Chemical Hygiene Plan - Queensborough Community College ...

Chemical Hygiene Plan - Queensborough Community College ... Chemical Hygiene Plan - Queensborough Community College ...

05.06.2014 Views

flammability. One chemical/ biological storage room under the supervision of a qualified person is essential for each school. The storage room should have adequate security. Safety facilities must include the following: • Fire extinguishers of the approved type, including sand and soda positioned near an escape route • Spill control and cleanup materials • Master control shutoff valves for gas, water, and electricity • Approved eye/face wash • Shower • Smoke detector • Forced ventilation from floor to ceiling with exhaust above roof level • Lip edged shelving secured to wall with top shelf below eye level • Safety cabinets for specific groups of compatible substances • A communication system to the main office or emergency center 6.6 Flammable Storage in Refrigerators/Freezers Flammable liquids must be stored only in specially designed flammable storage refrigerators/freezers or explosion-proof refrigerators/freezers, as per NFPA 45 and article 501 in NFPA 70. Do not store flammable liquids in standard (non-flammable rated) refrigerators/freezers. Standard refrigerators are not electrically designed to store flammable liquids. If flammable liquids are stored in a standard refrigerator, the buildup of flammable vapors can ignite when the refrigerator’s compressor or light turns on, resulting in a fire or an explosion. Properly rated flammable liquid storage refrigerators/freezers have protected internal electrical components and are designed for the storage of flammable liquids. Explosion-proof refrigerators/freezers have both the internal and external electrical components properly protected and are designed for the storage of flammable liquids. Refrigerators and freezers rated for the storage of flammable materials will be clearly identified as such by the manufacturer. For additional information, please refer to ANSI/UL 1203-1994 entitled, “Explosion-Proof and Dust-Ignition-Proof Electrical Equipment for Use in Hazardous (Classified) Locations.” For most laboratory applications, a flammable storage refrigerator/freezer is acceptable. However, some operations may require an explosion-proof refrigerator/freezer. If a laboratory cannot purchase a flammable storage refrigerator for the laboratory’s own use, departments and laboratory groups on each floor are strongly encouraged to consider purchasing a communal flammable storage refrigerator for the proper and safe storage of flammable liquids. 6.7 Flammable Storage Cabinets The requirements for use of flammable storage cabinets are determined by the classification of the flammable liquids, the quantities kept on hand, the building construction (fire wall ratings), and the floor of the building the flammables are being stored on. As a general rule of thumb, if you have more than 10 gallons of flammable liquids, including materials in use, then you should store the flammable liquids in a properly rated flammable liquid storage cabinet. All flammable 35

liquids not in use should be kept in the flammable liquid storage cabinet. For stand-alone flammable cabinets (as opposed to cabinets underneath fume hoods), there are vent holes on each side of the cabinet (called bung holes) that must have the metal bungs screwed into place for the cabinet to maintain its fire rating. Venting of flammable cabinets is NOT required, however, if a flammable cabinet is vented, it must be vented properly according to the manufacturer’s specifications and NFPA 30. Typically, proper flammable cabinet ventilation requires that air be supplied to the cabinet and the air be taken away via non-combustible pipes. If you are planning on venting your flammable storage cabinet, please contact your EHSO for more information. Be sure to follow local fire codes when storing flammable chemicals in separate cabinets. Storage Suggestions. 1. Avoid floor chemical storage (even temporarily) 2. No top shelf chemical storage 3. No chemicals stored above eye level 4. Shelf assemblies are to be firmly secured to walls. Avoid island shelf assemblies 5. Provide anti roll lips on all shelves 6. Ideally, shelving assemblies would be of metal construction 7. Avoid , adjustable shelf supports, and clips; fixed shelves and supports are better suited 8. Store acids in a dedicated acid cabinet. · store nitric acid in that same cabinet only if isolated from other acids · store both inorganic and some organic acids in the acid cabinet 9. Store flammables in a dedicated flammables cabinet 10. Store severe poisons in a dedicated poisons cabinet. Special attention must be paid to the following chemicals due to their potential instability. Inorganic Nitrates, nitrites, azides Perchloric Acid Peroxide Phosphorus Phosphorus Pentoxide Organic Ethers Azides Dioxane Tetrahydrofuran 2-Propanol Numerous texts listed in Appendix Q can be referred to assist in determining the best arrangement. One straightforward solution is described in Chapter 4: 'Incompatible Chemicals in the Storeroom: Identification and segregation," from Safe Storage of Laboratory, by Pipitone. Particular attention must be paid to isolating flammables, air reactives, peroxidizables, and toxic chemicals. Storage of specific hazard classes of chemicals is discussed in more detail below. 6.8 Specifications for Chemical Stockrooms Stockrooms are areas in facilities in which relatively large quantities of chemicals are stored for laboratory use. General Specifications for All Stockrooms 36

flammability. One chemical/ biological storage room under the supervision of a qualified person<br />

is essential for each school. The storage room should have adequate security. Safety facilities<br />

must include the following:<br />

• Fire extinguishers of the approved type, including sand and soda positioned near an<br />

escape route<br />

• Spill control and cleanup materials<br />

• Master control shutoff valves for gas, water, and electricity<br />

• Approved eye/face wash<br />

• Shower<br />

• Smoke detector<br />

• Forced ventilation from floor to ceiling with exhaust above roof level<br />

• Lip edged shelving secured to wall with top shelf below eye level<br />

• Safety cabinets for specific groups of compatible substances<br />

• A communication system to the main office or emergency center<br />

6.6 Flammable Storage in Refrigerators/Freezers<br />

Flammable liquids must be stored only in specially designed flammable storage<br />

refrigerators/freezers or explosion-proof refrigerators/freezers, as per NFPA 45 and article 501 in<br />

NFPA 70. Do not store flammable liquids in standard (non-flammable rated)<br />

refrigerators/freezers. Standard refrigerators are not electrically designed to store flammable<br />

liquids. If flammable liquids are stored in a standard refrigerator, the buildup of flammable<br />

vapors can ignite when the refrigerator’s compressor or light turns on, resulting in a fire or an<br />

explosion.<br />

Properly rated flammable liquid storage refrigerators/freezers have protected internal electrical<br />

components and are designed for the storage of flammable liquids. Explosion-proof<br />

refrigerators/freezers have both the internal and external electrical components properly<br />

protected and are designed for the storage of flammable liquids. Refrigerators and freezers rated<br />

for the storage of flammable materials will be clearly identified as such by the manufacturer. For<br />

additional information, please refer to ANSI/UL 1203-1994 entitled, “Explosion-Proof and<br />

Dust-Ignition-Proof Electrical Equipment for Use in Hazardous (Classified) Locations.”<br />

For most laboratory applications, a flammable storage refrigerator/freezer is acceptable.<br />

However, some operations may require an explosion-proof refrigerator/freezer. If a laboratory<br />

cannot purchase a flammable storage refrigerator for the laboratory’s own use, departments and<br />

laboratory groups on each floor are strongly encouraged to consider purchasing a communal<br />

flammable storage refrigerator for the proper and safe storage of flammable liquids.<br />

6.7 Flammable Storage Cabinets<br />

The requirements for use of flammable storage cabinets are determined by the classification of<br />

the flammable liquids, the quantities kept on hand, the building construction (fire wall ratings),<br />

and the floor of the building the flammables are being stored on. As a general rule of thumb, if<br />

you have more than 10 gallons of flammable liquids, including materials in use, then you should<br />

store the flammable liquids in a properly rated flammable liquid storage cabinet. All flammable<br />

35

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