Chemical Hygiene Plan - Queensborough Community College ...

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** Increased to 200 gals if not an educational or instructional lab as per FC 2706.6 *** Educational & instructional labs to comply with Class D requirements only Class I = Flash pt < 100 F; Class II = Flash pt 100 F – 140F; Class III = Flash pt > 140F Note: QCC instructional labs comply only with Class “D” requirements. Research labs follow Class “B” rules. Other materials: As per FC 2706.6 Maximum quantity in 1-hr fire rated lab Maximum quantity in 2-hr fire rated lab Water-Reactive Material Pyrophoric Material Highly Toxic Material Toxic Material Corrosive Material Flammable Solids Oxidizers/Org Peroxides 2.5 lbs 5 lbs 0.5 lb 1 lbs 5 lbs 5 lb 250 lbs 250 lbs 250 gals 250 gals 10 lbs 15 lbs 40 lbs* 50 lbs* Unstable reactive material 6 lbs** 12 lbs** *maximum 2 lbs of Class 3 oxidizers & 1 lb of Class I organic peroxides **maximum 1 lb of Class 3 unstable reactive material **Except for chemical research laboratories, no permit shall be required for laboratories storing or using less than 32 ounces, flammable liquids or VFOS. 0.5 pound oxidizing materials and/or 0. 15 cubic feet water container capacity of flammable gases. For example, a laboratory unit with a fire rating of 1 hour that has no sprinkler system must not store more than · 15 gallons of flammable liquids; · 3 pounds of flammable solids; · 20 pounds of oxidizing material · 2 pounds of unstable or reactive chemicals. The National Fire Protection Association's (NFPA) Code 45 (Fire Protection for Laboratories Using Chemicals goes further in describing maximum permissible quantities of flammable and combustible materials outside of approved liquid storage rooms. They recommend limits per lab unit as well as per 100 square feet of laboratory unit in sprinklered and unsprinklered units. Instructional laboratories specifically are allowed only half of the quantity of non instructional laboratories. For example, the maximum quantity of Class I flammables in unsprinklered instructional laboratories including quantities in storage cabinets and safety cans is 10 gallons per 100 square feet of laboratory unit. Research labs would be allowed 20 gallons including quantities in storage cabinets and safety cans. Laboratory Supervisors should inventory chemicals in laboratories monthly to ensure that the above described limits are not exceeded. Any problems must be directed to the departmental chairperson, the college EHS Officer, the Chemical Hygiene Officer, or other designated individual. 33
6.4 Transporting Chemicals When transporting chemicals between laboratories within the same building or contiguous buildings, it is recommended the following guidelines be adhered to for protection of people and the environment, and to minimize the potential for spills to occur: • Whenever transporting chemicals by hand, always use a secondary container such as a rubber acid carrying bucket, plastic bucket, or 5-gallon pail. If necessary, a small amount of packing material (shipping peanuts, vermiculite, or cardboard inserts) that is compatible with the chemical(s) should be used to prevent bottles from tipping over or breaking during transport. You should have proper PPE accessible in the event of a spill. • Wheeled carts with lipped surfaces (such as Rubbermaid carts) should be used whenever feasible. • Whenever possible, do not use passenger elevators when transporting chemicals; only freight elevators should be used. If it is necessary to use a passenger elevator, use should be restricted to low-use times such as early in the morning or late in the afternoon. If this is not possible, be sure to warn passengers or prohibit passengers from riding with you. • When transporting compressed gas cylinders, always use a proper gas cylinder hand truck with the cylinder strapped to the cart and keep the cap in place. NEVER roll or drag a compressed gas cylinder. • Avoid riding in elevators with cryogenic liquids or compressed gas cylinders. If you must, consider using a buddy system. Have one person send the properly secured dewars or cylinders on the elevator while the other person waits at the floor by the elevator doors where the dewars or cylinders will arrive. Please contact the EHS Office if chemicals are to be transported between laboratories in noncontiguous buildings. Please note: If chemicals are being transported off the main campus, be aware that there are specific procedures, training and other legal requirements that must be followed. For more information, refer to the Shipping Hazardous Materials section. 6.5 Segregation of Incompatible Chemicals Chemicals must not be arranged alphabetically or haphazardly in stockrooms or in laboratory work areas. It is acceptable to store powdered chemicals alphabetically if a hazard class system is used (e.g. corrosive, flammable, oxidizers, poisons, reproductive hazard. See the CHRIS compatibility system). Chemicals must be segregated to prevent mixing of incompatible chemical vapors or liquids in the event that containers break or leak. Numerous approaches can be taken to segregate chemicals in storage. Different approaches may be required depending on the type and amount of space available for storage and the environmental conditions of the spaces. Major considerations for criteria to segregate should include water compatibility and 34
Page 1 and 2: LABORATORY SAFETY AND CHEMICAL HYGI
Page 3 and 4: TABLE OF CONTENTS Purpose..........
Page 5 and 6: Visiting Scientists and Other Simil
Page 7 and 8: Cryogenic Safety...................
Page 9 and 10: PURPOSE OF THIS MANUAL The main pur
Page 11 and 12: The OSHA Laboratory Standard requir
Page 13 and 14: 12. Maintain records and make them
Page 15 and 16: 3. Keep the Department Chairperson,
Page 17 and 18: 6. Before an extremely hazardous su
Page 19 and 20: • Laboratories can use “price t
Page 21 and 22: shipment of improperly labeled prod
Page 23 and 24: • Do not smell or taste chemicals
Page 25 and 26: 5.3 Inhalation Inhalation of chemic
Page 27 and 28: Symptoms of skin exposure to chemic
Page 29 and 30: 5.10 Toxic Effects Toxic effects ar
Page 31 and 32: • All chemical containers MUST be
Page 33: · Peroxidizable materials (aldehyd
Page 37 and 38: liquids not in use should be kept i
Page 39 and 40: 7. An inside storage room meeting a
Page 41 and 42: VII. CHEMICAL HAZARDS Chemicals can
Page 43 and 44: • Metal Picrate Salts • 2,4-Din
Page 45 and 46: 7.5 Dangerous When Wet “Dangerous
Page 47 and 48: ways to remove them if discovered.
Page 49 and 50: 1(800) 222-1222. If possible, bring
Page 51 and 52: • Prior approval - Before anyone
Page 53 and 54: everyone in the laboratory is aware
Page 55 and 56: particularly hazardous substances
Page 57 and 58: 8.7 Reproductive Toxins The OSHA La
Page 59 and 60: 9.1 Chemical Fume Hoods Fume hoods
Page 61 and 62: inspected, and initials of the insp
Page 63 and 64: 9.4 Biological Safety Cabinet Certi
Page 65 and 66: • Plan and prepare for your work
Page 67 and 68: The topic of glove boxes can be con
Page 69 and 70: 10.1 Standard Operating Procedures
Page 71 and 72: paper, boxes, plastics, etc.) withi
Page 73 and 74: 10.6 Working Alone In Appendix A of
Page 75 and 76: • The nature of the experiment in
Page 77 and 78: Additionally, as with installation
Page 79 and 80: • Record keeping requirements •
Page 81 and 82: Prescription Safety Eyewear OSHA re
Page 83 and 84: different glove types. Different ma
Page 85 and 86:
• Natural Rubber Latex*** - Resis
Page 87 and 88:
The use of all types of respiratory
Page 89 and 90:
your College’s Emergency Procedur
Page 91 and 92:
• Check all pressure, temperature
Page 93 and 94:
If you have been trained and it is
Page 95 and 96:
4) Try to prevent spilled chemicals
Page 97 and 98:
their use. Colleges and departments
Page 99 and 100:
Once outside, notify emergency resp
Page 101 and 102:
5) Keep flushing for at least 15 mi
Page 103 and 104:
3. The New York City Rules and Regu
Page 105 and 106:
6. Selection of Hazardous Waste Con
Page 107 and 108:
XV. PESTICIDES A pesticide is defin
Page 109 and 110:
16.1 Institutional Biosafety Commit
Page 111 and 112:
the College’s IACUC must ensure t
Page 113 and 114:
• Materials derived from animals
Page 115 and 116:
the same regulations and laws; and
Page 117 and 118:
problems and compliance issues, and
Page 119 and 120:
from any given amperage, the table
Page 121 and 122:
extension cords, see the Consumer P
Page 123 and 124:
"reset" buttons. They are found on
Page 125 and 126:
properly replaced before use. Movin
Page 127 and 128:
22.4.1 Handling Compressed Gas Cyli
Page 129 and 130:
materials for connections; toxic an
Page 131 and 132:
Therefore, when counting an “equa
Page 133 and 134:
• If toxic, flammable, or otherwi
Page 135 and 136:
22.9 Centrifuges Some general safet
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significant thrust may be experienc
Page 139 and 140:
frozen to the underlying skin, cold
Page 141 and 142:
• Allow the system to cool and th
Page 143 and 144:
• Cover the tubing with cloth and
Page 145 and 146:
• Apparatus, equipment, or chemic
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• Seat height—be sure lab chair
Page 149 and 150:
someone else in your department or
Page 151 and 152:
23.3 Cylinders • Before moving to
Page 153 and 154:
EHS roles/responsibilities: • Pro
Page 155 and 156:
and that there are no dents or hole
Page 157 and 158:
• The contents of the Laboratory
Page 159 and 160:
Training Manuals and Booklets P.I.s
Page 161 and 162:
• Where airborne exposure monitor
Page 163 and 164:
than one year's employment must be
Page 165 and 166:
APPENDIX B: SITE MAP 164
Page 167 and 168:
APPENDIX D: OSHA TOXIC SUBSTANCES L
Page 169 and 170:
APPENDIX F: SAMPLE LAB INSPECTION F
Page 171 and 172:
APPENDIX G: CHEMICAL COMPATIBILITY
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peroxide, Nitric acid, Sodium perox
Page 175 and 176:
Sodium peroxide Sulfides Sulfuric a
Page 177 and 178:
APPENDIX I: FDNY REGULATIONS GOVERN
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41 and the total quantity, excludin
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Dimethyl sulfoxide 1 Natural rubber
Page 183 and 184:
Pump oil Butyl rubber Silane based
Page 185 and 186:
APPENDIX L: HOW TO UNDERSTAND MATER
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Percent Volatile by Volume: Describ
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Stability: Unstable indicates that
Page 191 and 192:
APPENDIX M: HAZARDS OF FUNCTIONAL G
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Examples: Butane Cyclohexene Cyclop
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• Azides of nonmetals, such as th
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• The routes of exposure are inha
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• Many of the common solvents can
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ORGANIC PEROXIDES • Compounds con
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• High doses may produce somnolen
Page 205 and 206:
APPENDIX O:LASER REGISTRATION FORM
Page 207 and 208:
APPENDIX Q : APPENDIX OF REFERENCE
Page 209 and 210:
Biological Effects and Exposure Cri
Page 211 and 212:
Dental X-Ray Protection, National C
Page 213 and 214:
Gibson, David E., Printmaking, Occu
Page 215 and 216:
Laboratory Decontamination and Carc
Page 217 and 218:
Natural Background Radiation In The
Page 219 and 220:
Public Radiation Exposure from Nucl
Page 221 and 222:
Materials, The School of the Art In
Page 223 and 224:
Video Display Terminals, Bell Labor
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