Chemical Hygiene Plan - Queensborough Community College ...

More documents

Recommendations

Info

SECTION II - HAZARDOUS INGREDIENTS OF MIXTURES Principal Hazardous component(s) % TVL (Units) This section describes the percent composition of the substance, listing chemicals present in the mixture. It lists Threshold Limit Values for the different chemicals that are present. Threshold Limit values (TLV's) are values for airborne toxic materials that are used as guides in the control of health hazards. They represent concentrations to which nearly all workers (workers without special sensitivities) can be exposed to for long periods of time without harmful effect. TLV's are usually expressed as parts per million (ppm), the parts of gas or vapor in each million parts of air. TLV's are also expressed as mg/m 3 , the milligrams of dust or vapor per cubic meter of air. SECTION III - PHYSICAL DATA Boiling Point ( o F) Specific Gravity (H 2 O=1) Vapor Pressure (mm Hg) Percent Volatile By Volume (%) Vapor Density (Air=1) Evaporation Rate (Butyl Acetate=1) Solubility in Water Appearance and Odor This section gives information about the physical characteristics of the chemical. This information can be very useful in determining how a chemical will behave in a spill situation and what appropriate steps should be taken. Vapor Pressure: Vapor pressure (VP) can be used as a measure of how volatile a substance is…how quickly it evaporates. VP is measured in units of millimeters of mercury (mm Hg). For comparison, the VP of water (at 20 o Centigrade) is 17.5 mm Hg. The VP of Vaseline (a nonvolatile substance) would be close to zero mm Hg, while the VP of diethyl ether (a very volatile substance) is 440 mm Hg. Vapor Density: Vapor density describes whether the vapor is lighter or heavier than air. The density of air is 1.0. A density greater than 1.0 indicates a heavier vapor, a density less than 1.0 indicates a lighter vapor. Vapors heavier than air (gasoline vapor for instance) can flow along just above the ground and can collect in depressions where they may pose a fire and explosion hazard. Specific Gravity: Specific gravity describes whether the liquid is lighter or heavier than water. Water has a specific gravity of 1.0. 185
Percent Volatile by Volume: Describes how much of the substance will evaporate. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point ( o F) Flammable Limits in Air (% by Lower Upper Vol.) Extinguisher Media Autoignition Temperature ( o F) Special Fire Fighting Procedures Explosion Hazards This section gives information, which is important for preventing and extinguishing fires and explosions. If a fire does occur, this information should be made available to fire fighters. Flash Point: Flash point is the lowest temperature at which a liquid gives off enough vapor to ignite when a source of ignition is present. A fire or explosion hazard may exist if the substance is at or above this temperature and used in the presence of spark or flame. Flammable Limits: In order to be flammable, a substance must be mixed with a certain amount of air (as in an automobile carburetor). A mixture that is too "lean" (not enough chemical) or too "rich" (not enough air) will not ignite. The Lower Explosive Limit (LEL) and the Upper Explosive Limit (UEL) define the range of concentration in which combustion can occur. The wider the range between the LEL and UEL, the more flammable the substance is. SECTION V - HEALTH HAZARD DATA Threshold Limit Value Effects of Overexposure Acute Overexposure Chronic Overexposure Emergency and First Aid Procedures Inhalation Eyes Skin Ingestion This section describes the potential health effects resulting from overexposure to the chemical and gives emergency and first aid procedures. The symptoms and effects listed 186
Page 1 and 2:
LABORATORY SAFETY AND CHEMICAL HYGI
Page 3 and 4:
TABLE OF CONTENTS Purpose..........
Page 5 and 6:
Visiting Scientists and Other Simil
Page 7 and 8:
Cryogenic Safety...................
Page 9 and 10:
PURPOSE OF THIS MANUAL The main pur
Page 11 and 12:
The OSHA Laboratory Standard requir
Page 13 and 14:
12. Maintain records and make them
Page 15 and 16:
3. Keep the Department Chairperson,
Page 17 and 18:
6. Before an extremely hazardous su
Page 19 and 20:
• Laboratories can use “price t
Page 21 and 22:
shipment of improperly labeled prod
Page 23 and 24:
• Do not smell or taste chemicals
Page 25 and 26:
5.3 Inhalation Inhalation of chemic
Page 27 and 28:
Symptoms of skin exposure to chemic
Page 29 and 30:
5.10 Toxic Effects Toxic effects ar
Page 31 and 32:
• All chemical containers MUST be
Page 33 and 34:
· Peroxidizable materials (aldehyd
Page 35 and 36:
6.4 Transporting Chemicals When tra
Page 37 and 38:
liquids not in use should be kept i
Page 39 and 40:
7. An inside storage room meeting a
Page 41 and 42:
VII. CHEMICAL HAZARDS Chemicals can
Page 43 and 44:
• Metal Picrate Salts • 2,4-Din
Page 45 and 46:
7.5 Dangerous When Wet “Dangerous
Page 47 and 48:
ways to remove them if discovered.
Page 49 and 50:
1(800) 222-1222. If possible, bring
Page 51 and 52:
• Prior approval - Before anyone
Page 53 and 54:
everyone in the laboratory is aware
Page 55 and 56:
particularly hazardous substances
Page 57 and 58:
8.7 Reproductive Toxins The OSHA La
Page 59 and 60:
9.1 Chemical Fume Hoods Fume hoods
Page 61 and 62:
inspected, and initials of the insp
Page 63 and 64:
9.4 Biological Safety Cabinet Certi
Page 65 and 66:
• Plan and prepare for your work
Page 67 and 68:
The topic of glove boxes can be con
Page 69 and 70:
10.1 Standard Operating Procedures
Page 71 and 72:
paper, boxes, plastics, etc.) withi
Page 73 and 74:
10.6 Working Alone In Appendix A of
Page 75 and 76:
• The nature of the experiment in
Page 77 and 78:
Additionally, as with installation
Page 79 and 80:
• Record keeping requirements •
Page 81 and 82:
Prescription Safety Eyewear OSHA re
Page 83 and 84:
different glove types. Different ma
Page 85 and 86:
• Natural Rubber Latex*** - Resis
Page 87 and 88:
The use of all types of respiratory
Page 89 and 90:
your College’s Emergency Procedur
Page 91 and 92:
• Check all pressure, temperature
Page 93 and 94:
If you have been trained and it is
Page 95 and 96:
4) Try to prevent spilled chemicals
Page 97 and 98:
their use. Colleges and departments
Page 99 and 100:
Once outside, notify emergency resp
Page 101 and 102:
5) Keep flushing for at least 15 mi
Page 103 and 104:
3. The New York City Rules and Regu
Page 105 and 106:
6. Selection of Hazardous Waste Con
Page 107 and 108:
XV. PESTICIDES A pesticide is defin
Page 109 and 110:
16.1 Institutional Biosafety Commit
Page 111 and 112:
the College’s IACUC must ensure t
Page 113 and 114:
• Materials derived from animals
Page 115 and 116:
the same regulations and laws; and
Page 117 and 118:
problems and compliance issues, and
Page 119 and 120:
from any given amperage, the table
Page 121 and 122:
extension cords, see the Consumer P
Page 123 and 124:
"reset" buttons. They are found on
Page 125 and 126:
properly replaced before use. Movin
Page 127 and 128:
22.4.1 Handling Compressed Gas Cyli
Page 129 and 130:
materials for connections; toxic an
Page 131 and 132:
Therefore, when counting an “equa
Page 133 and 134:
• If toxic, flammable, or otherwi
Page 135 and 136: 22.9 Centrifuges Some general safet
Page 137 and 138: significant thrust may be experienc
Page 139 and 140: frozen to the underlying skin, cold
Page 141 and 142: • Allow the system to cool and th
Page 143 and 144: • Cover the tubing with cloth and
Page 145 and 146: • Apparatus, equipment, or chemic
Page 147 and 148: • Seat height—be sure lab chair
Page 149 and 150: someone else in your department or
Page 151 and 152: 23.3 Cylinders • Before moving to
Page 153 and 154: EHS roles/responsibilities: • Pro
Page 155 and 156: and that there are no dents or hole
Page 157 and 158: • The contents of the Laboratory
Page 159 and 160: Training Manuals and Booklets P.I.s
Page 161 and 162: • Where airborne exposure monitor
Page 163 and 164: than one year's employment must be
Page 165 and 166: APPENDIX B: SITE MAP 164
Page 167 and 168: APPENDIX D: OSHA TOXIC SUBSTANCES L
Page 169 and 170: APPENDIX F: SAMPLE LAB INSPECTION F
Page 171 and 172: APPENDIX G: CHEMICAL COMPATIBILITY
Page 173 and 174: peroxide, Nitric acid, Sodium perox
Page 175 and 176: Sodium peroxide Sulfides Sulfuric a
Page 177 and 178: APPENDIX I: FDNY REGULATIONS GOVERN
Page 179 and 180: 41 and the total quantity, excludin
Page 181 and 182: Dimethyl sulfoxide 1 Natural rubber
Page 183 and 184: Pump oil Butyl rubber Silane based
Page 185: APPENDIX L: HOW TO UNDERSTAND MATER
Page 189 and 190: Stability: Unstable indicates that
Page 191 and 192: APPENDIX M: HAZARDS OF FUNCTIONAL G
Page 193 and 194: Examples: Butane Cyclohexene Cyclop
Page 195 and 196: • Azides of nonmetals, such as th
Page 197 and 198: • The routes of exposure are inha
Page 199 and 200: • Many of the common solvents can
Page 201 and 202: ORGANIC PEROXIDES • Compounds con
Page 203 and 204: • High doses may produce somnolen
Page 205 and 206: APPENDIX O:LASER REGISTRATION FORM
Page 207 and 208: APPENDIX Q : APPENDIX OF REFERENCE
Page 209 and 210: Biological Effects and Exposure Cri
Page 211 and 212: Dental X-Ray Protection, National C
Page 213 and 214: Gibson, David E., Printmaking, Occu
Page 215 and 216: Laboratory Decontamination and Carc
Page 217 and 218: Natural Background Radiation In The
Page 219 and 220: Public Radiation Exposure from Nucl
Page 221 and 222: Materials, The School of the Art In
Page 223 and 224: Video Display Terminals, Bell Labor
show all

Chemical Hygiene Plan - Queensborough Community College ...

Create successful ePaper yourself

Delete template?

Save as template?