Chemical Hygiene Plan - Queensborough Community College ...

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Ethyl ester (EMS) (Ethyl methanesulfonate) Monoethanolamine Nitrile Nickel chloride Nitrile Nitrile, double glove Nickel salts Nitrile Nitrile, double glove Nitric acid Nitrile (8 mil), double glove Heavy weight (.28-.33mm) Butyl rubber or Neoprene N-Methylethanolamine Nitrile (8 mil), double glove Viton, Neoprene, Butyl rubber Octane Nitrile Heavy weight Nitrile or Viton Organophosphorous compounds Nitrile (8 mil), double glove, or 15 mil or heavier Osmium salts Nitrile Osmium tetroxide Nitrile Nitrile, double glove Paraformaldehyde Nitrile Pentane Nitrile (8mil), double glove Heavy weight Neoprene, or Viton Perchloroethylene Nitrile (8 mil), double glove Nitrile (22mil or heavier) (tetrachloroethylene) Pesticides heavy weight, unlined Nitrile (8-20 mils), or glove specified by pesticide label. Petroleum ether Nitrile Heavy weight Nitrile or Viton Phenol Nitrile (8 mil), double glove Neoprene, Butyl rubber Phenol-Chloroform Nitrile (8 mil), double glove, or Viton mixtures 15 mil or heavier Phenylmethylsulfonyl Nitrile Nitrile, double glove fluoride (PMSF) Phosphonic acid Nitrile (4 mil), double glove, or 8 mil or heavier single Phosphoric acid Nitrile (4 mil), double glove, or 8 mil or heavier Picloram (4-amino-3,5,6- Nitrile trichloropicolinic acid) Polychlorinated Biphenyls Nitrile (8 mil) glove over a Neoprene (20 mil) (PCB’s) Neoprene glove Polyoxyethylene-sorbitaln-monolaurate Nitrile (Tween 20) Potassium ferricyanide Nitrile Potassium ferrocyanide Nitrile Potassium permanganate Nitrile Propanol Nitrile Propionic acid Nitrile Neoprene or Butyl rubber Propylene oxide heavier weight (17 mil or greater) Butyl rubber or Neoprene Norfoil Psoralen Nitrile Nitrile, double glove 181
Pump oil Butyl rubber Silane based silanization or derivatization Nitrile (8 mil), double glove, or 15 mil or heavier single compounds Silver nitrate Nitrile Nitrile, double glove Silver salts Nitrile Sodium dodecyl sulfate Nitrile (SDS) Sodium azide Nitrile, or double glove Spermidine Nitrile Sulfuric acid Nitrile (8 mil) Neoprene, Butyl rubber (20 mil or greater) Tetrahydrofuran (THF) Nitrile (8 mil), double glove, Norfoil or 15 mil or heavier 3,3’,5,5’-Tetramethylbenzidine Nitrile Nitrile, double glove (TMB) N,N,N’,N’-Tetramethylethylenediamine Nitrile Nitrile, double glove (TEMED) Timetin Nitrile Toluene Nitrile (8 mil), double glove, or 15 mil or heavier Viton, Polyvinyl acetate (PVA) Trichloroethylene Nitrile (8 mil), double glove Viton, Polyvinyl acetate (PVA) Trichloromethyl chloroformate Nitrile (8 mil) over Butyl rubber glove This material must be used in a glove box. (diphosgene) Triton-X100 Nitrile Uranium salts Nitrile Valeric acid Nitrile Nitrile, double gloves, or Neoprene or Butyl rubber Xylene Nitrile Polyvinyl acetate (PVA), Viton 1 If you are allergic to natural rubber products, you may double glove with 8 mil Nitrile gloves. 182
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LABORATORY SAFETY AND CHEMICAL HYGI
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TABLE OF CONTENTS Purpose..........
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Visiting Scientists and Other Simil
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Cryogenic Safety...................
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PURPOSE OF THIS MANUAL The main pur
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The OSHA Laboratory Standard requir
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12. Maintain records and make them
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3. Keep the Department Chairperson,
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6. Before an extremely hazardous su
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• Laboratories can use “price t
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shipment of improperly labeled prod
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• Do not smell or taste chemicals
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5.3 Inhalation Inhalation of chemic
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Symptoms of skin exposure to chemic
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5.10 Toxic Effects Toxic effects ar
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• All chemical containers MUST be
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· Peroxidizable materials (aldehyd
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6.4 Transporting Chemicals When tra
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liquids not in use should be kept i
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7. An inside storage room meeting a
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VII. CHEMICAL HAZARDS Chemicals can
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• Metal Picrate Salts • 2,4-Din
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7.5 Dangerous When Wet “Dangerous
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ways to remove them if discovered.
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1(800) 222-1222. If possible, bring
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• Prior approval - Before anyone
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everyone in the laboratory is aware
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particularly hazardous substances
Page 57 and 58:
8.7 Reproductive Toxins The OSHA La
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9.1 Chemical Fume Hoods Fume hoods
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inspected, and initials of the insp
Page 63 and 64:
9.4 Biological Safety Cabinet Certi
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• Plan and prepare for your work
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The topic of glove boxes can be con
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10.1 Standard Operating Procedures
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paper, boxes, plastics, etc.) withi
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10.6 Working Alone In Appendix A of
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• The nature of the experiment in
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Additionally, as with installation
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• Record keeping requirements •
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Prescription Safety Eyewear OSHA re
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different glove types. Different ma
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• Natural Rubber Latex*** - Resis
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The use of all types of respiratory
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your College’s Emergency Procedur
Page 91 and 92:
• Check all pressure, temperature
Page 93 and 94:
If you have been trained and it is
Page 95 and 96:
4) Try to prevent spilled chemicals
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their use. Colleges and departments
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Once outside, notify emergency resp
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5) Keep flushing for at least 15 mi
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3. The New York City Rules and Regu
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6. Selection of Hazardous Waste Con
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XV. PESTICIDES A pesticide is defin
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16.1 Institutional Biosafety Commit
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the College’s IACUC must ensure t
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• Materials derived from animals
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the same regulations and laws; and
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problems and compliance issues, and
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from any given amperage, the table
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extension cords, see the Consumer P
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"reset" buttons. They are found on
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properly replaced before use. Movin
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22.4.1 Handling Compressed Gas Cyli
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materials for connections; toxic an
Page 131 and 132: Therefore, when counting an “equa
Page 133 and 134: • If toxic, flammable, or otherwi
Page 135 and 136: 22.9 Centrifuges Some general safet
Page 137 and 138: significant thrust may be experienc
Page 139 and 140: frozen to the underlying skin, cold
Page 141 and 142: • Allow the system to cool and th
Page 143 and 144: • Cover the tubing with cloth and
Page 145 and 146: • Apparatus, equipment, or chemic
Page 147 and 148: • Seat height—be sure lab chair
Page 149 and 150: someone else in your department or
Page 151 and 152: 23.3 Cylinders • Before moving to
Page 153 and 154: EHS roles/responsibilities: • Pro
Page 155 and 156: and that there are no dents or hole
Page 157 and 158: • The contents of the Laboratory
Page 159 and 160: Training Manuals and Booklets P.I.s
Page 161 and 162: • Where airborne exposure monitor
Page 163 and 164: than one year's employment must be
Page 165 and 166: APPENDIX B: SITE MAP 164
Page 167 and 168: APPENDIX D: OSHA TOXIC SUBSTANCES L
Page 169 and 170: APPENDIX F: SAMPLE LAB INSPECTION F
Page 171 and 172: APPENDIX G: CHEMICAL COMPATIBILITY
Page 173 and 174: peroxide, Nitric acid, Sodium perox
Page 175 and 176: Sodium peroxide Sulfides Sulfuric a
Page 177 and 178: APPENDIX I: FDNY REGULATIONS GOVERN
Page 179 and 180: 41 and the total quantity, excludin
Page 181: Dimethyl sulfoxide 1 Natural rubber
Page 185 and 186: APPENDIX L: HOW TO UNDERSTAND MATER
Page 187 and 188: Percent Volatile by Volume: Describ
Page 189 and 190: Stability: Unstable indicates that
Page 191 and 192: APPENDIX M: HAZARDS OF FUNCTIONAL G
Page 193 and 194: Examples: Butane Cyclohexene Cyclop
Page 195 and 196: • Azides of nonmetals, such as th
Page 197 and 198: • The routes of exposure are inha
Page 199 and 200: • Many of the common solvents can
Page 201 and 202: ORGANIC PEROXIDES • Compounds con
Page 203 and 204: • High doses may produce somnolen
Page 205 and 206: APPENDIX O:LASER REGISTRATION FORM
Page 207 and 208: APPENDIX Q : APPENDIX OF REFERENCE
Page 209 and 210: Biological Effects and Exposure Cri
Page 211 and 212: Dental X-Ray Protection, National C
Page 213 and 214: Gibson, David E., Printmaking, Occu
Page 215 and 216: Laboratory Decontamination and Carc
Page 217 and 218: Natural Background Radiation In The
Page 219 and 220: Public Radiation Exposure from Nucl
Page 221 and 222: Materials, The School of the Art In
Page 223 and 224: Video Display Terminals, Bell Labor
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