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Chemical Hygiene Plan - Queensborough Community College ...

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generation of unknowns, allowing for the correct disposal of wastes, and facilitating emergency<br />

responses such as cleaning up spills and obtaining the proper medical treatment.<br />

New chemical containers have the proper labeling information on the chemical label. The<br />

OSHA Laboratory Standard requires that labels on all incoming containers must be maintained<br />

and not defaced. As part of laboratory good housekeeping and self-inspections, if any chemical<br />

labels appear to be falling off, then laboratory personnel should tape the label back on the<br />

container or relabel entirely. All personnel working in the laboratory must be fully trained on<br />

how to label chemicals. Training must occur when a new person begins working in the<br />

laboratory, when new chemicals are introduced, and at least once a year in any event.<br />

4.2 Non-Original Containers<br />

Non-original containers (secondary use containers) such as wash bottles, squirt bottles,<br />

temporary storage containers, beakers, flasks, bottles and vials, or any container that a chemical<br />

from an original container is transferred into, must be properly labeled. EPA and OSHA<br />

regulations require the listing of any hazards associated with that chemical and, whenever<br />

possible, writing out the full chemical name. In order to satisfy New York State and EPA<br />

regulations (6 NYCRR 372.2 (a) (2); 40 CFR 262.11) all chemical containers used for storing<br />

and handling chemicals must be labeled with enough information that when they do become a<br />

waste, a proper “waste determination” can be made. Since a chemical in use or storage can<br />

instantly become a waste through spillage, fire, or water damage, it is imperative that the<br />

information required to handle the waste properly be on the label. Laboratory personnel are<br />

encouraged to use commercially available pre-labeled containers (such as squirt bottles) for<br />

chemicals that are used frequently.<br />

The information required is not extensive or difficult to determine. If the material:<br />

1. Is flammable (flash point under 141 o F)<br />

2. Is an oxidizer<br />

3. Reacts with water or air<br />

4. Spontaneously combusts or polymerizes<br />

5. Has a pH less than 2 or greater than 12<br />

6. Is explosive<br />

7. Contains heavy metals<br />

then the container must indicate the hazard. Any organic solvent must also be listed.<br />

For small containers such as vials and Eppendorf tubes, laboratory personnel can group them by<br />

class into a larger vessel and simply label the outside of the vessel once. A brief description<br />

indicating all hazard characteristics should be included. While this type of system is available<br />

for laboratory personnel to use, using such a system for hazardous chemicals is not<br />

recommended. Such a system would be more appropriate for non-hazardous compounds such as<br />

agar and buffer solutions. Examples of similar systems can be found below:<br />

• Placing the vial or small container in a Ziploc bag or other type of overpack container<br />

(e.g., a beaker or plastic bottle) and labeling the overpack container with the chemical<br />

name and hazard characteristics.<br />

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