Chemical Hygiene Plan - Queensborough Community College ...

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APPENDIX C: PEROXIDIZABLE CHEMICALS LIST Class 1 (High Probability of Peroxide Formation) • <strong>Chemical</strong> Name • Isopropyl Ether • Divinyl Acetylene • Vinylidene Chloride • Potassium metal • Sodium amide • Recommended storage time or retest schedule • 3 months • 3 months • 3 months • 3 months • 3 months Class 2 (Moderate Probability of Peroxide Formation) Ethyl Ether Tetrahydrofuran Dioxane Acetal Methyl isobutyl ketone Ethylene glycol dimethy ether Vinyl ether Dicyclopentadiene Diacetylene Methyl acetylene 6 months 6 months 6 months 6 months 6 months 6 months 6 months 6 months 6 months 6 months Cumene 6 months Tetrahydronaphthalene 6 months Cyclohexene 6 months Methyl Cyclpentane 6 months 2 Propanol 6 months Iso butanol 6 months Class 3 (Hazard due to Peroxide Initiation of Polymerization) Styrene Butadiene Tetrafluroethylene Chlorotrifluroethylene Vinyl Acetylene Vinyl Acetate Vinyl Chloride Vinyl Pyridine Chlorobutadiene 12 months 12 months 12 months 12 months 12 months 12 months 12 months 12 months 12 monhs 165
APPENDIX D: OSHA TOXIC SUBSTANCES LIST (29CFR1910. SUBPART Z) Section Contaminant 1910.1000 Air contaminant 1910.1001 Asbestos 1910.1002 Coal tar pitch volatiles 1910.1003 13 carcinogens 1910.1004 Alpha naphtylamine 1910.1006 Methyl chloromethyl ether 1910.1007 3 dichlorobenzidine and salts 1910.1008 Bis chloromethyl ether 1910.1009 Beta naphtylamine 1910.1010 Benzidine 1910.1011 4 Amino diphenyl 1910.1012 Ethyleneimine 1910.1013 Beta Propiolactone 1910.1014 2 Acetylaminofluorene 1910.1015 4 Dimethylaminoazobenzene 1910.1016 N-Nitrosodimethylamine 1910.1017 Vinyl Chloride 1910.1018 Inorganic Arsenic 1910.1020 Access to employee exposure and medical records 1910.1025 Lead 1910.1027 Cadmium 1910.1028 Benzene 1910.1029 Coke oven emissions 1910.1030 Blood borne pathogens 1910.1043 Cotton dust 1910.1044 1,2 dibromo-3-chloropropane 1910.1045 Acrylonitrile 1910.1047 Ethylene Oxide 1910.1048 Formaldehyde 1910.1050 Methylenedianiline 1910.1051 1,3 Butadiene 1910.1052 Methylene Chloride 1910.1096 Ionizing Radiation 1910.1200 Hazard Communication 1910.1201 Retention of DOT markings, placards and labels 1910.1450 Occupational exposure to hazardous substances in laboratories 166
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LABORATORY SAFETY AND CHEMICAL HYGI
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TABLE OF CONTENTS Purpose..........
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Visiting Scientists and Other Simil
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Cryogenic Safety...................
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PURPOSE OF THIS MANUAL The main pur
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The OSHA Laboratory Standard requir
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12. Maintain records and make them
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3. Keep the Department Chairperson,
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6. Before an extremely hazardous su
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• Laboratories can use “price t
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shipment of improperly labeled prod
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• Do not smell or taste chemicals
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5.3 Inhalation Inhalation of chemic
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Symptoms of skin exposure to chemic
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5.10 Toxic Effects Toxic effects ar
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• All chemical containers MUST be
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· Peroxidizable materials (aldehyd
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6.4 Transporting Chemicals When tra
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liquids not in use should be kept i
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7. An inside storage room meeting a
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VII. CHEMICAL HAZARDS Chemicals can
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• Metal Picrate Salts • 2,4-Din
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7.5 Dangerous When Wet “Dangerous
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ways to remove them if discovered.
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1(800) 222-1222. If possible, bring
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• Prior approval - Before anyone
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everyone in the laboratory is aware
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particularly hazardous substances
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8.7 Reproductive Toxins The OSHA La
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9.1 Chemical Fume Hoods Fume hoods
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inspected, and initials of the insp
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9.4 Biological Safety Cabinet Certi
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• Plan and prepare for your work
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The topic of glove boxes can be con
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10.1 Standard Operating Procedures
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paper, boxes, plastics, etc.) withi
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10.6 Working Alone In Appendix A of
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• The nature of the experiment in
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Additionally, as with installation
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• Record keeping requirements •
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Prescription Safety Eyewear OSHA re
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different glove types. Different ma
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• Natural Rubber Latex*** - Resis
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The use of all types of respiratory
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your College’s Emergency Procedur
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• Check all pressure, temperature
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If you have been trained and it is
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4) Try to prevent spilled chemicals
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their use. Colleges and departments
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Once outside, notify emergency resp
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5) Keep flushing for at least 15 mi
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3. The New York City Rules and Regu
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6. Selection of Hazardous Waste Con
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XV. PESTICIDES A pesticide is defin
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16.1 Institutional Biosafety Commit
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the College’s IACUC must ensure t
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• Materials derived from animals
Page 115 and 116: the same regulations and laws; and
Page 117 and 118: problems and compliance issues, and
Page 119 and 120: from any given amperage, the table
Page 121 and 122: extension cords, see the Consumer P
Page 123 and 124: "reset" buttons. They are found on
Page 125 and 126: properly replaced before use. Movin
Page 127 and 128: 22.4.1 Handling Compressed Gas Cyli
Page 129 and 130: materials for connections; toxic an
Page 131 and 132: Therefore, when counting an “equa
Page 133 and 134: • If toxic, flammable, or otherwi
Page 135 and 136: 22.9 Centrifuges Some general safet
Page 137 and 138: significant thrust may be experienc
Page 139 and 140: frozen to the underlying skin, cold
Page 141 and 142: • Allow the system to cool and th
Page 143 and 144: • Cover the tubing with cloth and
Page 145 and 146: • Apparatus, equipment, or chemic
Page 147 and 148: • Seat height—be sure lab chair
Page 149 and 150: someone else in your department or
Page 151 and 152: 23.3 Cylinders • Before moving to
Page 153 and 154: EHS roles/responsibilities: • Pro
Page 155 and 156: and that there are no dents or hole
Page 157 and 158: • The contents of the Laboratory
Page 159 and 160: Training Manuals and Booklets P.I.s
Page 161 and 162: • Where airborne exposure monitor
Page 163 and 164: than one year's employment must be
Page 165: APPENDIX B: SITE MAP 164
Page 169 and 170: APPENDIX F: SAMPLE LAB INSPECTION F
Page 171 and 172: APPENDIX G: CHEMICAL COMPATIBILITY
Page 173 and 174: peroxide, Nitric acid, Sodium perox
Page 175 and 176: Sodium peroxide Sulfides Sulfuric a
Page 177 and 178: APPENDIX I: FDNY REGULATIONS GOVERN
Page 179 and 180: 41 and the total quantity, excludin
Page 181 and 182: Dimethyl sulfoxide 1 Natural rubber
Page 183 and 184: Pump oil Butyl rubber Silane based
Page 185 and 186: APPENDIX L: HOW TO UNDERSTAND MATER
Page 187 and 188: Percent Volatile by Volume: Describ
Page 189 and 190: Stability: Unstable indicates that
Page 191 and 192: APPENDIX M: HAZARDS OF FUNCTIONAL G
Page 193 and 194: Examples: Butane Cyclohexene Cyclop
Page 195 and 196: • Azides of nonmetals, such as th
Page 197 and 198: • The routes of exposure are inha
Page 199 and 200: • Many of the common solvents can
Page 201 and 202: ORGANIC PEROXIDES • Compounds con
Page 203 and 204: • High doses may produce somnolen
Page 205 and 206: APPENDIX O:LASER REGISTRATION FORM
Page 207 and 208: APPENDIX Q : APPENDIX OF REFERENCE
Page 209 and 210: Biological Effects and Exposure Cri
Page 211 and 212: Dental X-Ray Protection, National C
Page 213 and 214: Gibson, David E., Printmaking, Occu
Page 215 and 216: Laboratory Decontamination and Carc
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Natural Background Radiation In The
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Public Radiation Exposure from Nucl
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Materials, The School of the Art In
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Video Display Terminals, Bell Labor
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