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Polymers Product Guide - Polysciences, Inc.

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<strong>Polymers</strong> <strong>Product</strong> <strong>Guide</strong><br />

Acid-Functional <strong>Polymers</strong> and Salts<br />

Amides<br />

Amine-Functional <strong>Polymers</strong><br />

Biodegradable <strong>Polymers</strong><br />

Block Copolymers<br />

Conductive <strong>Polymers</strong><br />

Halogen-Containing <strong>Polymers</strong><br />

Liquid Crystal <strong>Polymers</strong><br />

Phenol-Functional <strong>Polymers</strong><br />

Phosphonic Acids<br />

Photoactive <strong>Polymers</strong><br />

Reactive <strong>Polymers</strong><br />

Water-Soluble <strong>Polymers</strong>


<strong>Polymers</strong> <strong>Product</strong> <strong>Guide</strong><br />

<strong>Polysciences</strong> stocks a wide portfolio of polymers. This variety provides the formulation scientist a useful set of tools to design compositions with markedly<br />

different performance. These polymers can also be used by the synthetic scientist as platforms on which to build yet more complex polymer systems.<br />

Polymer Selection <strong>Guide</strong> At-A-Glance<br />

Acid-functional <strong>Polymers</strong> and Salts 3<br />

• Carboxylic Acids<br />

• Sulfonic Acids<br />

• Phosphoric Acids<br />

Amides 4<br />

Amine-Functional <strong>Polymers</strong> 4<br />

Biodegradable <strong>Polymers</strong> 6<br />

Block Copolymers 7<br />

Conductive <strong>Polymers</strong> 7<br />

Halogen-Containing <strong>Polymers</strong> 8<br />

Liquid Crystals 8<br />

Phenol-Functional <strong>Polymers</strong> 8<br />

Phosphonic Acids 8<br />

Photoactive <strong>Polymers</strong> 8<br />

Reactive <strong>Polymers</strong> 9<br />

• Aldehyde and Ketone-Functional <strong>Polymers</strong><br />

• Carboxylic Acid Anhydride-Functional <strong>Polymers</strong><br />

• Carboxylic Acid Chloride-Functional <strong>Polymers</strong><br />

• Oxirane-Functional <strong>Polymers</strong><br />

• Hydroxyl-Functional <strong>Polymers</strong><br />

• Nitrile-Functional <strong>Polymers</strong><br />

Water Soluble <strong>Polymers</strong> 10<br />

2<br />

For technical questions, info@polysciences.com or (800) 523-2575 / (215) 343-6484


Acid-functional <strong>Polymers</strong> and Salts<br />

Acidic groups are often used to convey solubility to polymers in aqueous media. These versatile moieties can be converted to a wide range of alternative<br />

functional groups. Acid groups can be utilized as catalysts for chemical reactions. Additionally they are employed in polymers as the functional group which<br />

enables improved adhesion to a variety of substrates through hydrogen bonding or metal chelation.<br />

Carboxylic Acids<br />

<strong>Product</strong> Name Molecular Weight Form Catalog # Size<br />

Poly Acrylic Acid 2,000 63% aqueous<br />

5,000 50% aqueous<br />

50,000 25% aqueous<br />

345,000 25% aqueous<br />

450,000 powder<br />

1,000,000 powder<br />

4,000,000 powder<br />

Poly Acrylic Acid, 250,000 powder<br />

Ammonium Salt<br />

Poly Acrylic Acid, Sodium Salt 2,000 powder<br />

3,000 40% aqueous<br />

6,000 powder<br />

10,000 powder<br />

60,000 35% aqueous<br />

225,000 20% aqueous<br />

Poly Butadiene/Maleic Acid (50/50) 12,000 42% aqueous<br />

Poly Butyl Acrylate/Acrylic Acid (50/50) 20% latex/alcohol<br />

(50/50) powder<br />

Poly Ethyl Acrylate/Acrylic Acid (50/50) 20% in Ethanol<br />

(50/50) powder<br />

Poly Ethylene/Acrylic Acid (92/8)<br />

Poly Ethylene/Maleic Anhydride (50/50) 400,000<br />

Poly Maleic Acid 1,000 50% aqueous<br />

Poly Methacrylic Acid 1,000,000 powder<br />

Poly Methacrylic Acid 15,000 30% aqueous<br />

Ammonium Salt<br />

Poly Methacrylic Acid 15,000 30% aqueous<br />

Sodium Salt<br />

Poly Methyl Methacrylate/ (75/25) 1,200,000 powder<br />

Methacrylic Acid (80/20) powder<br />

(90/10) 100,000 powder<br />

(95/5) 500,000 powder<br />

Poly Styrene Sulfonic Acid/ (50/50) 15,000 25% aqueous<br />

Maleic Acid, Sodium Salt (75/25) 20,000 powder<br />

06513-250 250g<br />

06519-250 250g<br />

00627-250 250g<br />

03326-250 250g<br />

03312-100 100g<br />

06500-100 100g<br />

06501-100 100g<br />

03311-25 25g<br />

06568-250 250g<br />

18608-250 250g<br />

06567-250 250g<br />

18609-250 250g<br />

18611-250 250g<br />

18613-250 250g<br />

07787-500 500g<br />

19911-10 10g<br />

21058-5 5g<br />

19914-10 10g<br />

21056-5 5g<br />

06517-100 100g<br />

02308-50 50g<br />

09732-10 10g<br />

00578-10 10g<br />

00578-50 50g<br />

21169-25 25g<br />

21170-25 25g<br />

21170-100 100g<br />

08208-100 100g<br />

08221-100 100g<br />

08207-50 50g<br />

19629-100 100g<br />

11795-25 25g<br />

18407-25 25g<br />

Sulfonic Acids<br />

<strong>Product</strong> Name Molecular Weight Form Catalog # Size<br />

Poly(styrenesulfonic acid) 70,000 30% AQ<br />

Poly(styrenesulfonic acid), sodium salt 70,000 powder<br />

500,00 powder<br />

08770-250 250g<br />

08772-25 25g<br />

08773-25 25g<br />

Phosphoric Acids<br />

<strong>Product</strong> Name Molecular Weight Form Catalog # Size<br />

Poly(vinylphosphoric acid), sodium salt >200,000 powder 04391-5 5g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

3


Amides<br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyacrylamide 1,500 50% AQ water soluble polymer. High 23967-100 100g<br />

10,000 50% AQ molecular weight polymers 22581-250 250g<br />

700K - 1,000,000 10% AQ find application as flocculants. 19901-250 250g<br />

5,000,000- 6,000,000 powder<br />

02806-250 250g<br />

5,000,000 1% AQ<br />

21485-250 250g<br />

18,000,000 powder<br />

18522-100 100g<br />

Poly(acrylamide/acrylic acid) 90:10, Na Salt 50,000 powder acidic acrylamide polymer 04652-250 250g<br />

Poly(acrylamide/acrylic acid) 60:40, Na Salt 450,000 powder acidic acrylamide polymer 18545-250 250g<br />

Poly(acrylamide/acrylic acid) 30:70, Na Salt 2,000 powder acidic acrylamide polymer 02220-250 250g<br />

Polycaprolactam (Nylon 6) 5,000 powder widely used in fibers<br />

18180-250 250g<br />

50,000 powder<br />

18179-250 250g<br />

Poly etherimide 450,000 powder high softening point resin<br />

16845-100 100g<br />

Poly(2-ethyl-2-oxazoline) 2,000 powder neutral water soluble<br />

24066-50 50g<br />

5,000 powder can be hydrolyzed to linear 17808-100 100g<br />

50,000 powder polyethylenimine<br />

24882-100 100g<br />

450,000 powder<br />

17810-100 100g<br />

Poly(hexamethyleneadipamide) (Nylon 6/6) 2,000 powder used in fibers. mp 265 - 270ºC 06557-500 500g<br />

Poly methacrylamide 5,000 powder hydrophilic water soluble polymide 16144-10 10g<br />

Poly(N-isopropylacrylamide) 50,000 powder water soluble at RT. insoluble<br />

above 40ºC<br />

21458-10 10g<br />

Amine-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Chitin, practical<br />

acetylated amino glucose<br />

00210-50 50g<br />

Chitosan (poly d-glucosamine) 15,000 powder cationic polymer<br />

21661-50 50g<br />

Chitosan practical 100K - 300K powder<br />

00281-100 100g<br />

Poly(acrylamide/2-methacryloxy<br />

50,000 20% AQ cationic polymer<br />

21743-10 10g<br />

ethyltrimethylammonium bromide)<br />

Poly allylamine hydrochloride 60,000 powder pH of 1% aqueous 4.0<br />

18378-50 50g<br />

Poly 4-amino styrene >150,000 powder insol in org solvents and mineral acids 02823-1 1g<br />

Polyaniline Emeraldine form<br />

Acid doped<br />

Undoped<br />

Water soluble<br />

Poly 3-chloro-2-hydroxypropyl-2-<br />

methacryloxyethyldimethylammonium<br />

chloride<br />

Poly(diallyldimethylammonium<br />

chloride)<br />

Poly(2-dimethyaminoethyl<br />

methacrylate)<br />

Poly(ethylene glycol) alpha-2-<br />

aminoethyl, omega-methoxy<br />

15,000<br />

~15,000<br />

Poly(ethylene glycol) bis 2-aminoethyl 1,000<br />

10,000<br />

powder<br />

powder<br />

powder<br />

240,000 powder<br />

28% AQ<br />

50,000 20% in tBuOH<br />

conductivity 2-4 S/cm<br />

conductivity 10 -10 S/cm<br />

polyaniline polyaniline with propanesultone<br />

20% AQ can be cyclized to oxirane with mild base<br />

linear cationic quat ammonium<br />

cyclopolymer<br />

2,000 solid used for protein conjugation<br />

powder<br />

powder<br />

bifunctional PEG derivative that<br />

can be used to conjugate proteins and<br />

drugs for delivery<br />

21288-5<br />

24043-5<br />

23614-1<br />

5g<br />

5g<br />

1g<br />

21480-10 10g<br />

17338-10<br />

19898-250<br />

10g<br />

250g<br />

21510-10 10g<br />

24304-1 1g<br />

24285-1<br />

24303-1<br />

1g<br />

1g<br />

4<br />

For technical questions, info@polysciences.com or (800) 523-2575 / (215) 343-6484


Amine-Functional <strong>Polymers</strong> (continued)<br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyethylenimine, branched 600<br />

Polyethylenimine,<br />

branched, benzylated<br />

Polyethylenimine, branched,<br />

permethylated, permethobromide<br />

1,200<br />

1,800<br />

liquid<br />

liquid<br />

liquid<br />

10,000 liquid<br />

10,000 30% AQ<br />

70,000 30% AQ<br />

50K-100K<br />

30% AQ<br />

highly branched polyamine containing primary,<br />

secondary and tertiary amine groups<br />

adsorbed on SiO 2<br />

/ 40-200 mesh<br />

6,300 10% AQ High charge density<br />

quaternary salt<br />

Polyethylenimine, linear 25,000 powder all secondary amine polymers<br />

Polyethylenimine “Max” Nominal 4,000 solid easy to handle<br />

(Equ. to MW 2,500 in freebase form) hydrochloride salt form<br />

Nominal 40,000 solid<br />

(Equ. to MW 25,000 in freebase form)<br />

02371-100<br />

02371-500<br />

06088-100<br />

06088-500<br />

06089-100<br />

06089-500<br />

19850-100<br />

19850-500<br />

100g<br />

500g<br />

100g<br />

500g<br />

100g<br />

500g<br />

100g<br />

500g<br />

17938-100 100g<br />

00618-100<br />

00618-500<br />

06090-100<br />

06090-500<br />

100g<br />

500g<br />

100g<br />

500g<br />

17208-10 10g<br />

21903-10 10g<br />

23966-2 2g<br />

24885-2<br />

2g<br />

24765-2<br />

2g<br />

Poly(l-lysine hydrobromide)<br />

Poly(2-methacryloxyethyltrimethylammonium<br />

bromide)<br />

40K - 60K<br />

60K - 120K<br />

100K - 140K<br />

50,000<br />

200,000<br />

powder<br />

20% AQ<br />

powder<br />

20% AQ<br />

20% AQ<br />

cationic polymer for cell adhesion<br />

on surfaces<br />

cationic water soluble polymer<br />

Poly(N-methylvinylamine) 500,000 powder water soluble all secondary polyamine<br />

Poly vinylamine hydrochloride 25,000 powder water soluble all primary<br />

polyamine salt<br />

Poly(2-vinyl-1-methylpyridinium bromide) 50,000 20% AQ cationic polymer, 50% quaternized<br />

Poly(4-vinyl-1-methylpyridinium bromide) 50,000 20% AQ cationic polymer, 85% quaternized<br />

Poly(2-vinylpyridine) 40,000<br />

200K - 400K<br />

300K - 400K<br />

Poly(4-vinylpyridine) 50,000<br />

150K - 200K<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

water soluble at low pH<br />

water soluble at low pH<br />

water soluble at low pH<br />

water soluble at low pH<br />

water soluble at low pH<br />

Poly(4-vinylpyridine/ divinylbenzene) beads beads used as adsorbant or ion exchange resin<br />

Poly(2-vinylpyridine N-oxide) 300K - 400K powder water soluble cationic<br />

Poly(4-vinylpyridine N-oxide) 200,000 powder water soluble cationic<br />

Poly(N-vinylpyrrolidone) 2,500<br />

4,000 - 6,000<br />

10,000<br />

40,000<br />

40,000<br />

1,000,000<br />

Poly(N-vinylpyrrolidone/<br />

2-dimethylaminoethyl<br />

methacrylate),dimethyl<br />

sulfate quaternary (90:10)<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

water soluble polymer used as a thickner<br />

or protective colliod<br />

pharmaceutical grade<br />

100,000 20% aqueous water soluble quaternary salt<br />

18619-50<br />

09730-25<br />

09730-250<br />

21430-100<br />

21479-10<br />

21746-10<br />

50g<br />

25ml<br />

250ml<br />

100mg<br />

10g<br />

10g<br />

24038-5 5g<br />

23965-1<br />

23965-5<br />

1g<br />

5g<br />

21477-10 10g<br />

21478-10 10g<br />

21382-10<br />

19238-10<br />

17770-10<br />

00112-50<br />

22176-50<br />

10g<br />

10g<br />

10g<br />

50g<br />

50g<br />

06579-10 10g<br />

01564-10 10g<br />

23684-10 10g<br />

16693-250<br />

24737-250<br />

03315-250<br />

01051-250<br />

01052-250<br />

06067-250<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

16294-100 100g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

5


Biodegradable <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polycaprolactone 43,000 flakes hydroxyl end group. mp 55 - 65ºC<br />

19561-500 500g<br />

Polycaprolactone diol 1,250<br />

2,0000<br />

liquid<br />

liquid<br />

hydroxyl # 90mg /g of polymer<br />

hydroxyl # 56mg /g of polymer<br />

09706-500<br />

09694-500<br />

500g<br />

500g<br />

Poly [(-)3-hydroxybutyric acid] 500,000 powder mp 168 - 176ºC<br />

Poly(DL-lactic acid) 15,000<br />

20K - 30K<br />

330K - 600K<br />

Poly(L-lactic acid) 1,600 - 2,400<br />

40,000 - 70,000<br />

Poly(DL-lactide/glycolide)<br />

80K - 100K<br />

325K - 460K<br />

700,000<br />

90/10<br />

85/15<br />

80/20<br />

75/25<br />

70/30<br />

50/50<br />

50/50<br />

Poly(L-lactide/glycolide) 70/30<br />

70/30<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />


Poly(ethylene glycol)/Poly(lactic acid) Diblock & Triblock <strong>Polymers</strong><br />

Diblock <strong>Polymers</strong> (Numbers in parentheses refer to Mw of the segment)<br />

<strong>Product</strong> Name Form Comments Catalog # Size<br />

PEG(350)-b-PLA(300) liquid biodegradable<br />

24375-1 1g<br />

PEG(1000)-b-PLA(750) visc liquid diblock copolymers<br />

24378-1 1g<br />

PEG(1000)-b-PLA(5000)<br />

solid<br />

24381-1 1g<br />

PEG(5000)-b-PLA(1000)<br />

solid<br />

24386-1 1g<br />

PEG(5000)-b-PLA(5000)<br />

solid<br />

24389-1 1g<br />

PEG(5000)-b-PLA(10000)<br />

solid<br />

25018-1 1g<br />

PEG(10000)-b-PLA(5000)<br />

solid<br />

25017-1 1g<br />

Triblock <strong>Polymers</strong> (Numbers in parentheses refer to Mw of the segment)<br />

<strong>Product</strong> Name Form Comments Catalog # Size<br />

PCL(1000)-b-PEG(1000)-b-PCL(1000) visc liquid biodegradable<br />

24500-1 1g<br />

PLA(2000)-b-PEG(1000)-b-PLA(2000) solid triblock copolymers<br />

24501-1 1g<br />

PLA(5000)-b-PEG(1000)-b-PLA(5000)<br />

solid<br />

24502-1 1g<br />

PLA(1000)-b-PEG(4000)-b-PLA(1000)<br />

solid<br />

24503-1 1g<br />

PLA(1000)-b-PEG(10,000)-b-PLA(1000) solid<br />

24509-1 1g<br />

PLA(5000)-b-PEG(10,000)-b-PLA(5000) solid<br />

25026-1 1g<br />

PLA(10000)-b-PEG(10,000)-b-PLA(10000) solid triblock polymer<br />

25027-1 1g<br />

Block Copolymers<br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Poly(dimethylsiloxane-bethylene<br />

oxide), methyl<br />

terminated<br />

25:75<br />

20:80<br />

600<br />

3,000<br />

liquid<br />

liquid<br />

surfactant-like diblock copolymer<br />

surfactant-like diblock copolymer<br />

09780-100<br />

21870-100<br />

100g<br />

100g<br />

Poly(ethylene oxide-bpropylene<br />

oxide)<br />

1,100<br />

3,400<br />

2,900<br />

13,300<br />

8,750<br />

liquid<br />

liquid<br />

liquid<br />

waxy solid<br />

waxy solid<br />

ratio 0.15:1<br />

ratio 0.33:1<br />

ratio 0.8:1<br />

ratio 3.0:1<br />

ratio 5.0:1<br />

16273-100<br />

16274-100<br />

16275-100<br />

16276-100<br />

16277-100<br />

100g<br />

100g<br />

100g<br />

100g<br />

100g<br />

Conductive <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyaniline Emeraldine form<br />

Acid doped<br />

Undoped<br />

Water soluble<br />

Poly(3,4-ethylenedioxythiophene/poly<br />

styrenesulfonate), aqueous dispersion<br />

15,000<br />

~15,000<br />

powder<br />

powder<br />

powder<br />

liquid<br />

conductivity 2-4 S/cm<br />

conductivity 10 -10 S/cm<br />

polyaniline polyaniline with<br />

propanesultone<br />

conductive polymer<br />

Poly(3-methylthiophene) 500,000 powder conductive polymer<br />

Poly(3-octylthiophene) 100,000 powder<br />

Polypyrrole powder conductive polymer<br />

Poly(N-vinylcarbazole) 40,000 powder photoconductive polymer<br />

21288-5<br />

24043-5<br />

23614-1<br />

5g<br />

5g<br />

1g<br />

24215-100 100g<br />

21826-1 1g<br />

22052-1 1g<br />

21304-5 5g<br />

02428-50 50g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

7


Halogen-Containing <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Fluorinated Ethylene Propylene<br />

flakes hydroxyl end group. mp 55 - 65ºC 24778-100 100g<br />

Copolymer (10-35 MFI)<br />

Fluorinated Ethylene Propylene<br />

flakes hydroxyl end group. mp 55 - 65ºC 24779-100 100g<br />

Copolymer (35-70 MFI)<br />

Poly(4-bromostyrene) flakes hydroxyl end group. mp 55 - 65ºC 07030-1 1g<br />

21480-10 10g<br />

Poly(3-chloro-2-hydroxypropyl-<br />

2-methacryloxyethyldimethylammonium<br />

chloride)<br />

powder<br />

powder<br />

powder<br />

i.v. 0.15 - 0.30<br />

i.v. 0.35 - 0.45<br />

i.v. 2.00 - 2.80<br />

Poly(4-chlorostyrene) 250,000 flakes hydroxyl end group. mp 55 - 65ºC<br />

Poly(chlorotrifluoroethylene) 500 - 600 flakes hydroxyl end group. mp 55 - 65ºC<br />

Poly(4-iodostyrene/styrene/-<br />

divinylbenzene)<br />

58/40/2


Reactive <strong>Polymers</strong><br />

Aldehyde and Ketone-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyacrolein 200K - 2,000,000 powder due to intermolecular acetals,<br />

acts as if heavily crosslinked<br />

Poly(vinylmethyl ketone) powder reactive carbonyl<br />

04287-10 10g<br />

04320-10 10g<br />

Carboxylic Acid Anhydride-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Poly(butadiene/maleic anhydride)<br />

1:1 molar<br />

10,000 - 15,000 25% in acetone can be reacted at anhydride<br />

or backbone olefin<br />

Poly(ethylene/maleic anhydride) 1:1 molar 400,000 powder reacts with alcohols or amines<br />

Poly(maleic anhydride) ca 5,000 powder reacts with alcohols or amines<br />

Poly(octadecene/maleic anhydride) 1:1 molar 30K- 50K powder reacts with alcohols or amines,<br />

hydrophobic<br />

07788-500 500g<br />

02308-50 50g<br />

02348-5 5g<br />

05152-100 100g<br />

Carboxylic Acid Chloride-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Poly(acryloyl chloride) 10,000 25% in dioxane reacts with alcohols or amines<br />

Poly(methacryloyl chloride) 25% in dioxane reacts with alcohols or amines<br />

04293-10 10g<br />

04315-10 10g<br />

Oxirane-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Poly(glycidyl methacrylate) 25,000 10% in MEK reacts with carboxyls,<br />

hydroxyls or amines<br />

06524-5 5g<br />

Hydroxyl-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Poly(1-glycerol methacrylate) waxy solid hydrophilic, water soluble<br />

Poly(2-hydroxyethyl methacrylate) 200,000<br />

powder<br />

water swellable<br />

200,000<br />

12% in Ethanol<br />

Poly(vinyl alcohol) 6,000<br />

25,000<br />

25,000<br />

78,000<br />

78,000<br />

78,000<br />

108,000<br />

125,000<br />

133,000<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

80 mol % hydrolyzed<br />

88 mol % hydrolyzed<br />

98 mol % hydrolyzed<br />

88 mol % hydrolyzed<br />

98 mol % hydrolyzed<br />

99.7 mol % hydrolyzed<br />

99.7 mol % hydrolyzed<br />

88 mol % hydrolyzed<br />

99 mol % hydrolyzed<br />

16855-10 10g<br />

09689-25<br />

18894-100<br />

22225-500<br />

02975-500<br />

04397-500<br />

15132-500<br />

15130-500<br />

15129-500<br />

04324-500<br />

04398-500<br />

02815-500<br />

25g<br />

100g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

Nitrile-Functional <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyacrylonitrile 150,000 powder<br />

Poly(butadiene/acrylonitrile)<br />

carboxyl terminated<br />

Poly(Methacrylonitrile)<br />

(67:33) solid widely used nitrile rubber<br />

powder<br />

03914-100<br />

03914-500<br />

100g<br />

500g<br />

06561-500 500g<br />

04314-10 10g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

9


Water Soluble <strong>Polymers</strong><br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Cellulose, carboxymethyl ether, Na+ 80,000<br />

250,000<br />

700,000<br />

Cellulose, hydroxyethyl ether ~90,000<br />

720,000<br />

1,000,000<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

degree of substitution = 0.7<br />

degree of substitution = 0.7<br />

degree of substitution = 0.7<br />

06140-250<br />

06138-250<br />

06139-250<br />

05570-500<br />

05569-500<br />

05568-500<br />

Cellulose, methyl hydroxyethyl ether 2% soln. in H 2O cellulose derivative 21275-500 500g<br />

Chitosan (Poly d-glucosamine) 15,000 powder degree of deacetylation 84% 21161-50 50g<br />

Chitosan (practical) 200,000 powder amine 7-12% 00281-100 100g<br />

Dextran poly[(1,6)-alpha-d-glucose] 17,500<br />

150,000<br />

250,000<br />

5,000,000<br />

powder<br />

powder<br />

powder<br />

powder<br />

i.v. 0.10 - 0.14<br />

i.v. 0.343<br />

i.v. 0.4 - 0.5/37°C<br />

01341-100<br />

05056-100<br />

22500-100<br />

05059-100<br />

Dextran hydrogenated 5,000,000 powder i.v. 0.055 terminal alcohol 16653-100 100g<br />

Dextran sulfate, sodium salt 500,000 powder sulfur 19%, anionic dextran derivative 00407-100 100g<br />

Guar gum 1,200,000 powder natural water-soluble polysaccharide 21255-100 100g<br />

Poly(acrylamide) 1,500<br />

10,000<br />

850,000<br />

5,500,000<br />

5,000,000<br />

18,000,000<br />

Poly(acrylamide/acrylic acid) Na+ 90/10<br />

60/40<br />

30/70<br />

Poly(acrylamide/2- methacryloxyethyl<br />

trimethylammoniumbromide)<br />

200,000<br />

>10,000,000<br />

200,000<br />

Poly(acrylic acid) 2,000<br />

5,000<br />

345,000<br />

450,000<br />

1,000,000<br />

4,000,000<br />

50% AQ<br />

50% AQ<br />

10% AQ<br />

powder<br />

1% AQ<br />

powder<br />

powder<br />

powder<br />

powder<br />

nonionic water-soluble polymer;<br />

high Mw polymer used as flocculant<br />

23967-100<br />

22581-250<br />

19901-250<br />

02806-250<br />

21485-250<br />

18522-100<br />

anionic acrylamide polymer 04652-250<br />

18545-250<br />

02220-250<br />

250g<br />

250g<br />

250g<br />

500g<br />

500g<br />

500g<br />

100g<br />

100g<br />

100g<br />

100g<br />

100g<br />

250g<br />

250g<br />

250g<br />

250g<br />

100g<br />

250g<br />

250g<br />

250g<br />

80/20 50,000 20% AQ cationic acrylamide polymer 21743-10 10g<br />

63% AQ<br />

50% AQ<br />

25% AQ<br />

powder<br />

powder<br />

powder<br />

anionic water-soluble polymer; can<br />

be crosslinked covalently or ionically<br />

to form hydrogels<br />

06513-250<br />

06519-250<br />

03326-250<br />

03312-100<br />

06500-100<br />

06501-100<br />

Poly(acrylic acid) NH 4 + 250,000 powder 03311-25 25g<br />

Poly(acrylic acid) Na+ 2,000<br />

3,000<br />

6,000<br />

10,000<br />

60,000<br />

225,000<br />

Poly(Allyl Amine) 1,000<br />

15,000<br />

Poly(Diallyl Dimethyl Ammonium Chloride) 8,500<br />

40,000<br />

240,000<br />

Poly(Diallyl Methyl Amine Chloride) 5,000<br />

20,000<br />

powder<br />

40% AQ<br />

powder<br />

40% AQ<br />

35% AQ<br />

20% AQ<br />

15% solid in H 2O<br />

15% solid in H 2O<br />

28% solid in H 2O<br />

28% solid in H 2O<br />

powder<br />

25% solid in H 2O<br />

25% solid in H 2O<br />

water-soluble anionic polymer, low<br />

molecular weights used as pigment<br />

dispersants, high Mw’s used as<br />

flocculants<br />

water soluble cationic polymer<br />

water soluble cationic polymer<br />

supplied as hydrochloride salts<br />

supplied as hydrochloride salts<br />

linear cationic cyclic polymer<br />

supplied as hydrochloride salts<br />

supplied as hydrochloride salts<br />

06568-250<br />

18608-250<br />

06567-250<br />

18609-250<br />

18611-250<br />

18613-250<br />

24825-100<br />

24826-100<br />

24828-100<br />

24830-100<br />

17338-10<br />

24827-100<br />

24829-100<br />

Poly(allylamine hydrochloride) 60,000 powder polymeric primary amine 18378-50 50g<br />

Poly(butadiene/maleic anhydride) 1:1 molar 12,500 42% AQ anionic polymer capable of anhydride 07787-500 500g<br />

or backbone unsaturation reaction<br />

Poly(n-butyl acrylate/2-methacryloxytrimethylammonium<br />

80:20 20% AQ cationic polymer 21744-10 10g<br />

bromide<br />

Poly(3-chloro-2-hydroxypropyl-2-<br />

methacryloxyethyldimethylammonium<br />

chloride<br />

20% AQ chlorohydroxypropyl group can be<br />

cyclized to oxirane by mild alkali<br />

21480-10 10g<br />

250g<br />

250g<br />

250g<br />

100g<br />

100g<br />

100g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

100g<br />

100g<br />

100g<br />

100g<br />

10g<br />

100g<br />

100g<br />

10<br />

For technical questions, info@polysciences.com or (800) 523-2575 / (215) 343-6484


Water Soluble <strong>Polymers</strong> (continued)<br />

<strong>Product</strong> Name Molecular Weight Form Comments<br />

Poly(2-dimethylaminoethyl methacrylate 50,000 20% in BuOH 21510-10 10g<br />

Poly(ethyl acrylate/acrylic acid) 50:50 20% in EtOH 19914-10 10g<br />

Poly(ethylene glycol) 200<br />

300<br />

400<br />

600<br />

1,000<br />

1,450<br />

3,400<br />

7.500<br />

10,000<br />

20,000<br />

1,540<br />

3,400<br />

8,000<br />

Poly(ethylene glycol)-bisphenol<br />

A-diglycidyl ether adduct<br />

liquid<br />

liquid<br />

liquid<br />

liquid<br />

solid<br />

solid<br />

solid<br />

solid<br />

solid<br />

solid<br />

solid<br />

solid<br />

solid<br />

nonionic water soluble<br />

polymer<br />

pharmaceutical grade<br />

pharmaceutical grade<br />

pharmaceutical grade<br />

01112-250<br />

01110-250<br />

01109-250<br />

00684-250<br />

00682-250<br />

00679-250<br />

06102-250<br />

06103-250<br />

22567-250<br />

22568-250<br />

01102-100<br />

00678-100<br />

17243-100<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

100g<br />

100g<br />

100g<br />

18,500 solid 04686-250 250g<br />

Poly(ethylene glycol-200) adipate ca 546 liquid reaction product for one mole (adipic 21509-100 100g<br />

acid) and two moles (PEG 200)<br />

Poly(ethylene glycol) alpha-2-<br />

aminoethyl, omega-methoxy<br />

2,000 solid used for protein conjugation 24304-1 1g<br />

Poly(ethylene glycol) bis 2-aminoethyl 1,000<br />

10,000<br />

Poly(ethylene glycol) dimethyl ether 400<br />

1,000<br />

2,000<br />

Poly(ethylene glycol)monocarboxymethyl<br />

ether monomethyl ether<br />

Poly(ethylene glycol) monomethyl ether 350<br />

550<br />

750<br />

1,900<br />

5,000<br />

Poly(ethylene oxide) 100,000<br />

200,000<br />

300,000<br />

600,000<br />

1,000,000<br />

4,000,000<br />

5,000,000<br />

8,000,000<br />

Poly(ethylene oxideb-propylene<br />

oxide)<br />

0.15:1.0<br />

0.33:1.0<br />

0.8:1.0<br />

3.0:1.0<br />

5.0:1.0<br />

solid<br />

solid<br />

liquid<br />

liquid<br />

liquid<br />

used to conjugate proteins and drug<br />

substances for delivery<br />

used to complex metals and phase<br />

transfer agents<br />

750 solid carboxylic acid-terminated, coupled<br />

to molecules with carbodiimides<br />

1,100<br />

3,400<br />

1,900<br />

13,300<br />

8,750<br />

Polyethylenimine, branched 600<br />

1,200<br />

1,800<br />

10,000<br />

10,000<br />

70,000<br />

50K-100K<br />

liquid<br />

low mp solid<br />

solid<br />

solid<br />

solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

waxy solid<br />

liquid<br />

liquid<br />

liquid<br />

waxy solid<br />

waxy solid<br />

liquid<br />

liquid<br />

liquid<br />

liquid<br />

30% AQ<br />

30% AQ<br />

30% AQ<br />

24285-1<br />

24303-1<br />

17031-25<br />

17032-25<br />

17033-25<br />

hydroxyl group at one end 04200-500<br />

04457-500<br />

00626-500<br />

04242-500<br />

05986-500<br />

06104-500<br />

17503-500<br />

06105-500<br />

06106-500<br />

21295-500<br />

04030-500<br />

04031-500<br />

21296-500<br />

water-soluble or water-dispersible<br />

polymers with surfactant properties,<br />

chains are hydroxyl terminated<br />

highly branched, with high charge<br />

density, contain primary, secondary<br />

and tertiary amine groups, soluble<br />

in water at all Mw’s<br />

Catalog #<br />

1g<br />

1g<br />

25g<br />

25g<br />

25g<br />

21483-500 500g<br />

16273-100<br />

16274-100<br />

16275-100<br />

16276-100<br />

16277-100<br />

02371-100<br />

02371-500<br />

06088-100<br />

06088-500<br />

06089-100<br />

06089-500<br />

19850-100<br />

19850-500<br />

17938-100<br />

00618-100<br />

00618-500<br />

06090-100<br />

06090-500<br />

Size<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

100g<br />

100g<br />

100g<br />

100g<br />

100g<br />

100g<br />

500g<br />

100g<br />

500g<br />

100g<br />

500g<br />

100g<br />

500g<br />

100g<br />

100g<br />

500g<br />

100g<br />

500g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

11


Water Soluble <strong>Polymers</strong> (continued)<br />

<strong>Product</strong> Name Molecular Weight Form Comments Catalog # Size<br />

Polyethylenimine, branched,<br />

permethylated, permethobromide<br />

6,300 10% AQ high charge density, quaternary salt 21903-10 10g<br />

Polyethylenimine, linear 2,500<br />

25,000<br />

250,000<br />

powder<br />

powder<br />

powder<br />

all secondary amine polymers 24313-2<br />

23966-2<br />

24314-2<br />

2g<br />

2g<br />

2g<br />

Polyethylenimine “Max” Nominal 4,000 solid<br />

(Equ. to MW 2,500 in freebase form)<br />

Nominal 4,000 solid<br />

(Equ. to MW 25,000 in freebase form)<br />

easy to handle, hydrochloride<br />

salt form<br />

24885-2<br />

24765-2<br />

2g<br />

2g<br />

Poly(2-ethyl-2-oxazoline) 5,000<br />

50,000<br />

200,000<br />

500,000<br />

powder<br />

powder<br />

powder<br />

powder<br />

neutral polymer, can be hydrolyzed<br />

to linear polyethylenimine<br />

24066-50<br />

17808-100<br />

24882-100<br />

17810-100<br />

Poly(1-glycerol methacrylate) waxy solid hydrophilic, water-swellable polymer, 16855-10 10g<br />

probably cross-linked<br />

Poly(2-hydroxyethyl methacrylate/<br />

methacrylic acid)<br />

solid water soluble in presence of alkali 08725-10 10g<br />

Poly(l-lysine hydrobromide) 50,000<br />

90,000<br />

120,000<br />

powder<br />

0.1% AQ<br />

powder<br />

cationic polymer, used for promotion<br />

of cell adhesion to surfaces<br />

18619-50<br />

09730-25<br />

21430-100<br />

Poly(maleic acid) 1,000 50% AQ 09732-10 10g<br />

Poly(methacrylamide) 5,000 powder water soluble polymer 16144-10 10g<br />

Poly(methacrylic acid) 100,000 solid water soluble polymer 00578-10<br />

00578-50<br />

Poly(methacrylic acid) ammonium salt 15,000 30% AQ forms insoluble salts with polyamines 21169-25 25g<br />

Poly(methacrylic acid) sodium salt 15,000 30% AQ forms insoluble salts with polyamines 21170-25<br />

21170-100<br />

Poly(2-methacryloxyethyltrimethylammonium<br />

bromide)<br />

50,000<br />

200,000<br />

20% AQ<br />

20% AQ<br />

cationic (quaternary ammonium)<br />

cationic (quaternary ammonium)<br />

21479-10<br />

21746-10<br />

Poly(N-iso-propylacrylamide) 40,000 solid soluble at RT, insoluble above 40ºC 21458-10 10g<br />

Poly(oxyethylene), sorbitan monolaurate 1,230 liquid surfactant, Tween ® 20 06110-100 100g<br />

Poly(styrenesulfonic acid) 70,000 30% AQ ionic polymer in acid form 08770-250 250g<br />

Poly(styrenesulfonic acid), sodium salt 70,000<br />

500,000<br />

Poly(styrenesulfonic acid/ maleic acid),<br />

sodium salt<br />

1:1 molar<br />

3:1 molar<br />

15,000<br />

20,000<br />

powder<br />

powder<br />

25% AQ<br />

solid<br />

ionic polymer in salt form 08772-25<br />

08773-25<br />

can be used as a pigment dispersant 11795-25<br />

18407-25<br />

Poly(N-vinyl acetamide) ~4,060,000 powder moderately water soluble, stable 24808-50 50g<br />

Poly(N-methyl N-vinyl acetamide)<br />

powder may be converted to poly (N-methyl 24810-50 50g<br />

homopolymer<br />

vinyl amine) by hydrolysis<br />

Poly(N-vinyl acetamide-co-sodium acrylate) powder moderately water soluble, stable 24809-50 50g<br />

Poly(N-vinyl acetamide) homopolymer,<br />

Crosslinked<br />

powder moderately water soluble, stable 24807-50 50g<br />

Poly(vinyl alcohol) 6,000<br />

25,000<br />

25,000<br />

78,000<br />

78,000<br />

78,000<br />

108,000<br />

125,000<br />

133,000<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

88% hydrolyzed<br />

88% hydrolyzed<br />

98% hydrolyzed<br />

88% hydrolyzed<br />

98% hydrolyzed<br />

99.7% hydrolyzed<br />

99.7% hydrolyzed<br />

88% hydrolyzed<br />

99% hydrolyzed<br />

22225-500<br />

02975-500<br />

04397-500<br />

15132-500<br />

15130-500<br />

15129-500<br />

04324-500<br />

04398-500<br />

02815-500<br />

50g<br />

100g<br />

100g<br />

100g<br />

50g<br />

25g<br />

100g<br />

10g<br />

50g<br />

25g<br />

100g<br />

10g<br />

10g<br />

25g<br />

25g<br />

25g<br />

25g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

500g<br />

12<br />

For technical questions, info@polysciences.com or (800) 523-2575 / (215) 343-6484


Water Soluble <strong>Polymers</strong> (continued)<br />

<strong>Product</strong> Name Molecular Weight Form Comments<br />

Poly(vinyl alcohol), N-methyl-4(4’-formylstyryl)<br />

pyridinium methosulfate acetal<br />

45,000 13.3% AQ photocrosslinkable polymer, high<br />

dielectric constant, used in making<br />

silkscreen printing screens<br />

Poly(vinylamine) hydrochloride 25,000 powder all primary anime 23965-1<br />

23965-5<br />

Catalog # Size<br />

22570-75 75g<br />

Poly(2-vinyl-1-methylpyridinium bromide) 50,000 20% AQ degree of quaternization ~50% 21477-10 10g<br />

Poly(4-vinyl-1-methylpyridinium bromide) 50,000 20% AQ degree of quaternization ~85% 21478-10 10g<br />

Poly(vinylphosphoric acid), sodium salt 200,000 solid straight chain; 5% phosphorus 04391-5 5g<br />

Poly(vinylphosphonic acid), sodium salt 24,000 30% AQ polydispersity ~1.24 24297-10 10g<br />

Poly(2-vinylpyridine) 50,000<br />

300,000<br />

350,000<br />

Poly(4-vinylpyridine) 50,000<br />

300,000<br />

powder<br />

powder<br />

powder<br />

solid<br />

solid<br />

water-soluble at low pH,<br />

adhesive-promoting properties<br />

water-soluble at low pH<br />

water-soluble at low pH<br />

21382-10<br />

19238-10<br />

17770-10<br />

00112-50<br />

22176-50<br />

Poly(2-vinylpyridine, N-oxide) 150K-200K powder water-soluble cationic resin 01564-10 10g<br />

Poly(4-vinylpyridine, N-oxide) 200,000 powder water-soluble cationic resin 23684-10 10g<br />

Poly(N-vinylpyrrolidone) 2,500<br />

4,000-6,000<br />

10,000<br />

40,000<br />

40,000<br />

1,000,000<br />

Poly(N-vinylpyrrolidone/2-dimethylaminoethyl<br />

methacrylate)<br />

dimethylsufate<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

powder<br />

water-soluble polymer used as<br />

a thickener, protective colloid<br />

pharmaceutical grade<br />

16693-250<br />

24737-250<br />

03315-250<br />

01051-250<br />

01052-250<br />

06067-250<br />

90/10 100,000 20% AQ cationic quaternary salt 16294-100 100g<br />

Poly(vinylsulfonic acid), sodium salt 5,000 25% AQ anionic polymer 04392-100 100g<br />

1g<br />

5g<br />

10g<br />

10g<br />

10g<br />

50g<br />

50g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

250g<br />

For more information please call (800) 523-2575 / (215) 343-6484 or visit polysciences.com<br />

13


<strong>Polysciences</strong>, <strong>Inc</strong>.<br />

Chemistry Beyond the Ordinary<br />

Corporate Headquarters<br />

<strong>Polysciences</strong>, <strong>Inc</strong>.<br />

400 Valley Road<br />

Warrington, PA 18976<br />

(800) 523-2575 / (215) 343-6484<br />

Fax: (800) 343-3291 / (215) 343-0214<br />

email: info@polysciences.com<br />

www.polysciences.com<br />

European Headquarters<br />

<strong>Polysciences</strong> Europe GmbH<br />

Handelsstrasse 3<br />

D-69214 Eppelheim<br />

Germany<br />

(49) 6221-765767<br />

Fax: (49) 6221-764620<br />

email: info@polysciences.de<br />

We offer a complete line of Monomers & <strong>Polymers</strong> products,<br />

to learn more visit polysciences.com<br />

Copyright <strong>Polysciences</strong> <strong>Inc</strong>. 2011. All rights reserved. No artwork or photographic images within this or other related publications may be reproduced, stored in a retrieval<br />

system, transmitted in any form or any means, electronic, mechanical, photocopying, recording, or otherwise without permission from <strong>Polysciences</strong>, <strong>Inc</strong>.

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