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Figure 1. Then new NPL cavity pyroelectric detector.<br />

A total of 35 CPDs have been assembled and studied over<br />

the period from 1998 to 2003. The gain G(λ) [5] as a<br />

function of wavelength was measured for the majority of<br />

these CPDs. Figure 2 shows the spectral responsivity of a<br />

3 mm by 3 mm Pt-black-coated pyroelectric detector<br />

measured in the 0.8 µm to 25 µm wavelength range<br />

relative to both the CPD75 and pyroelectric detector 75 i.e.<br />

against the same pyroelectric detector, with and without a<br />

gold-coated reflective hemisphere. These plots are typical<br />

for the pyroelectric detectors with the very best quality<br />

gold-black coatings. Division of the two traces shown in<br />

Figure 2 gives the relative spectral responsivity of CPD75<br />

relative to pyroelectric detector 75. This ratio is also the<br />

gain G(λ) resulting from the addition of the reflective<br />

hemisphere onto the pyroelectric detector. The values of<br />

G(λ) as a function of wavelength for CPD75 are shown in<br />

Figure 3. Figure 3 shows that the gain is greater than unity<br />

for all wavelengths. This confirms that the gold-black<br />

coating deposited on pyroelectric detector 75 is not perfect<br />

and that the addition of the hemisphere redirects some of<br />

the radiation reflected by the gold-black coating back to<br />

the gold-black coating thus enhancing its effective<br />

absorbance and therefore its response. Moreover Figure 3<br />

shows that G(λ) increases monotonically with increasing<br />

wavelength. This indicates that the reflectance of the gold<br />

black coating gradually increases with wavelength<br />

(assuming the effective reflectance of the reflecting<br />

hemisphere is not a function of wavelength). This<br />

observation is in agreement with measurements of the<br />

reflectance of all good quality gold-black coatings [6].<br />

Relative response<br />

2<br />

1.9<br />

1.8<br />

1.7<br />

1.6<br />

1.5<br />

1.4<br />

T13/cp75<br />

T13/P75<br />

1.3<br />

0 5 10 15 20 25<br />

Wavelength/µm<br />

Figure 2: Spectral response of a 3 mm by 3 mm<br />

Pt-black-coated pyroelectric detector measured in the<br />

0.8 µm to 25 µm wavelength range relative to both CPD75<br />

and pyroelectric detector 75<br />

All parameters of the cavity pyroelectric detectors were<br />

fully evaluated and will be presented at the meeting. These<br />

include their relative and absolute spectral responsivities,<br />

spatial uniformity of response, linearity of response,<br />

temperature coefficient of response, temporal response,<br />

long term stability and noise characteristics.<br />

The presentation will also describe how the relative<br />

spectral responsivity of a cavity pyroelectric detector is<br />

estimated from the knowledge of its gain G(λ) as a<br />

function of wavelength. It will also deal with the<br />

uncertainty budget developed to estimate the uncertainty of<br />

the NPL infrared relative spectral responsivity scale.<br />

Gain<br />

1.045<br />

1.04<br />

1.035<br />

1.03<br />

1.025<br />

1.02<br />

1.015<br />

1.01<br />

1.005<br />

1<br />

0 5 10 15 20 25<br />

Wavelength/µm<br />

Figure 3: Gain in the 0.8 µm to 25 µm wavelength range<br />

measured when a reflective hemisphere was added to<br />

pyroelectric detector 75.<br />

Acknowledgements Special thanks must go to John Lehman of<br />

NIST Boulder for assembling all the pyroelectric detector<br />

modules used in the new NPL CPDs and for many useful<br />

discussions. The author also wishes to thank Nick Nelms of the<br />

Space Research Centre of the University of Leicester, UK and<br />

Mark Proulx of Laser Probe Inc.<br />

Reference<br />

1. G. W. Day, C. A. Hamilton and K. W. Pyatt,<br />

Applied Optics, 15, 1865-1868, 1976.<br />

2. D. H. Nettleton, T. R. Prior and T. H. Ward,<br />

“ Improved spectral responsivity scales at NPL, 400<br />

nm to 20 µm”, Metrologia, 30, 425-432, 1993.<br />

3. L. P. Boivin, “Current work at NRC of Canada on<br />

absolute radiometer based calibrations in the infrared”,<br />

in New developments and Applications in optical<br />

Radiometry, N. P. Fox and D. H. Nettleton (eds), 1989,<br />

81-88.<br />

4. J. Lehman, E. Theocharous, G. Eppeldauer, and C.<br />

Pannel, “Gold-black coatings for freestanding<br />

pyroelectric detectors” Measurement Science and<br />

Technology, 14, 916-922, 2003.<br />

5. E. Theocharous, “The establishment of the NPL<br />

infrared relative spectral responsivity scale using<br />

cavity pyroelectric detectors”, to be published.<br />

6. N. Nelms and J. Dawson, “Goldblack coating for<br />

thermal infrared detectors” Accepted for publication in<br />

Sensors and Actuators, January 2005.<br />

302

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