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Workshop book - Physikzentrum der RWTH Aachen - RWTH Aachen ...

Workshop book - Physikzentrum der RWTH Aachen - RWTH Aachen ...

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Posters Monday February 4<br />

Poster 15:<br />

Mechanism for Giant Thermopower in Negative-U Molecular Quantum Dots<br />

Theo Costi<br />

We investigate with the aid of numerical renormalization group techniques<br />

the thermoelectric properties of a molecular quantum dot described by the<br />

negative-U An<strong>der</strong>son model. We show that the charge Kondo effect provides<br />

a mechanism for enhanced thermoelectric power via a correlation-induced<br />

asymmetry in the spectral function close to the Fermi level. We show that<br />

this effect results in a dramatic enhancement of the Kondo-induced peak in<br />

the thermopower of negative-U systems with Seebeck coefficients exceeding<br />

50 µV/K over a wide range of gate voltages [1,2].<br />

[1] S. An<strong>der</strong>gassen, T. A. Costi and V. Zlatic, Phys. Rev. B 84, 241107 (R)<br />

(2011)<br />

[2] T. A. Costi and V. Zlatic, Phys. Rev. Lett. {bf 108}, 36402 (2012); in<br />

"New Materials for Thermoelectric Applications: Theory and Experiment",<br />

ed. V. Zlatic and A. C. Hewson, ISBN 978-94-007-4983-2 (Springer, Berlin,<br />

2012)<br />

Coauthors: S. An<strong>der</strong>gassen and V. Zlatic<br />

Poster 16:<br />

Boltzmann-type approach to thermal drag in spin-1/2-lad<strong>der</strong> systems coupled<br />

to phonons<br />

Christian Bartsch<br />

We quantitatively investigate the spin-phonon drag contributions to the<br />

thermal conductivity of a two-leg-spin-1/2-lad<strong>der</strong> coupled to lattice vibrations<br />

in a magnetoelastic way. By applying suitable transformations the<br />

system is mapped onto a weakly interacting quantum gas model of bosonic<br />

spin excitations (magnons) and phonons. We adequately construct a collision<br />

term of a linear(ized) Boltzmann equation from the un<strong>der</strong>lying quantum<br />

dynamics by means of a pertinent projection operator technique. From the<br />

Boltzmann equation we obtain concrete numerical values for the drag conductivity<br />

and relate it to the individual thermal conductivities of magnons and<br />

phonons for parameter ranges which are typical for certain material classes.<br />

68

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