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Thermoelectric Properties of Fe0.2Co3.8Sb12-xTex ... - Physics

Thermoelectric Properties of Fe0.2Co3.8Sb12-xTex ... - Physics

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Title <strong>of</strong> abstract: Transport properties and noise in hydrazine reduced graphene oxide.<br />

Authors: Anindita Sahoo (1), Ryugo Tero (2), Tran Viet Thu (2), Yuji Tanizawa (3), Hiroshi<br />

Okada (2,3), Adarsh Sandhu (2,3), Arindam Ghosh (1)<br />

Affiliation: (1) Department <strong>of</strong> <strong>Physics</strong>, Indian Institute <strong>of</strong> Science, Bangalore 560012, (2)<br />

Electronics Inspired Interdisciplinary Research Institute (EIIRIS), (3) Department <strong>of</strong><br />

Electrical and Electronic Engineering, Toyohashi University <strong>of</strong> Technology, 1-1<br />

Hibarigaoka, Tempaku, Toyohashi 441-8580, JAPAN<br />

Abstract:<br />

Chemically reduced graphene oxide (GO) has attracted immense interest for large scale<br />

production <strong>of</strong> graphene. This makes electrical properties, in particular resistivity and<br />

flicker noise, in these systems extremely important for variety <strong>of</strong> electronic applications.<br />

Here we present a study <strong>of</strong> electrical resistivity, bias stressing and flicker noise (or 1/f<br />

noise) in hydrazine-reduced graphene oxide films as a function <strong>of</strong> the extent <strong>of</strong> reduction.<br />

The electrical resistance measurement on individual monolayer flakes <strong>of</strong> reduced graphene<br />

oxide (RGO) showed that its resistance decreases by four orders <strong>of</strong> magnitude when<br />

GO is reduced by hydrazine. However, this decrease was associated with an increasing D-<br />

peak in the Raman spectroscopy in comparison to shorter hydrazine treatments indicating<br />

that hydrazine treatment introduces strong localized disorder in RGO, possibly<br />

through crystal defects and impurities. This was further confirmed with bias stressing<br />

and the measurement <strong>of</strong> 1/f noise (low frequency resistance fluctuation) on the RGO-<br />

FET which showed that the presence <strong>of</strong> mobile defects in RGO with shorter hydrazine<br />

treatment leads to a faster relaxation <strong>of</strong> source-drain current and higher value <strong>of</strong> noise<br />

amplitude. Our experiments indicate that the nature as well as the kinetics <strong>of</strong> defects<br />

depends on the extent <strong>of</strong> hydrazine treatment in chemically reduced GO films.

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