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M4-NUWC Overview Fontaine.pdf

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Microplasma Reforming of Acetylene for SOFC Aboard<br />

UUVs Student: E. Lennon, PI: R. Besser, Navy Mentor: A. A.<br />

Burke<br />

elennon@stevens.edu, rbesser@stevens.edu<br />

Non-Thermal Microplasma<br />

S&T OBJECTIVES<br />

Examples:<br />

•<br />

Microplasma chips fabricated by Besser’s group<br />

running with inert gases (nitrogen & neon) in batch<br />

mode.<br />

APPROAC<br />

•H<br />

•<br />

•<br />

Characterize VI behaviors of microplasmas to<br />

determine device efficiencies under various chip<br />

geometries & input settings.<br />

Design next generation flow-thru microplasma<br />

chips & fabricate at Cornell Nanotechnology<br />

Facility (CNF).<br />

Assess hydrogen generation from C2H2 microplasma chips in a closed-loop carbide fuel<br />

processing system via measurement of<br />

conversion, yield, selectivity, & process<br />

efficiencies (all potentially improved by high<br />

electron density in microplasma).<br />

•<br />

•<br />

Determine if microplasma reforming of acetylene<br />

(C2H2) is a viable fuel processing option for H2 delivery to UUV SOFC.<br />

Determine if viable, under what conditions<br />

microplasma reforming of acetylene (C2H2) performs best.<br />

Compare microplasma fuel reforming for UUVs<br />

to existing reforming technologies.<br />

Accomplishments Jun’08 – May‘09<br />

• Completed H2 O2 decomposition project &<br />

submitted manuscript to Journal of Power<br />

Sources.<br />

• Completed microplasma fuel processing lit review.<br />

• Reviewed VI data of inert gas microplasmas &<br />

analyzed characteristics for batch chips.<br />

• Integrating mass spec into current experimental<br />

Upcoming setup. Work Jun’09 – May’10<br />

• Complete microplasma flow-thru chip design .<br />

• Fabricate next generation microplasma flow-thru<br />

chips at CNF.<br />

• Run experiments of acetylene reforming with<br />

microplasma chips to quantify hydrogen

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