Paper Conservation: Decisions & Compromises
Paper Conservation: Decisions & Compromises Paper Conservation: Decisions & Compromises
The Migration of Hydroxy Propyl Cellulose During Consolidation of a Painted Wallpaper: A Case Study Using a Fluorescent - Labelled Consolidant Tilly Laaser | Karolina Soppa | Christoph Krekel Staatliche Akademie der Bildenden Künste Stuttgart, Germany; Hochschule der Künste Bern, Konservierung und Restaurierung, Bern, Switzerland Introduction This paper presents the evaluation of a consolidation method planned for a painted wallpaper in the Neues Museum Berlin in 2007. Five years before, the painted surface had been secured with facings applied with Klucel® (hydroxy propyl cellulose) solved in ethanol. A method for their removal and simultaneous consolidation of the weakly bound and partly flaking paint layer was proposed by the conservators in charge and evaluated by researchers at the State Academy of Art and Design Stuttgart with test objects. 1 The penetration behaviour of hydroxy propyl cellulose in the test wallpapers was visualised using fluorescent labelling. 2 Fig. 1: Fluorochromization reaction between hydroxy propyl cellulose and FITC ‘Isomer I’, forming a stable, fluorescing conjugate. Original wallpaper and conservation problem In 2008, the Neues Museum Berlin was restored and reopened for the public after it had been severely damaged in World War II. The ceiling wallpaper is part of the original interior fittings from the 1850s. Originally, maculature and paper supports had been attached to the ceilings of the Mythologischer Saal and afterwards been painted in situ with glue-bound distemper. 3 After having suffered different damages connected to the partly destroyed museum building, the 250 m 2 of wallpaper were treated by conservators in 2002. The painted surface was secured with facings applied with hydroxy propyl cellulose dissolved in ethanol and the partly detached wall paper removed from the ceilings and transferred to a storage in anticipation of further conservation treatment. At the beginning of the wall paper’s conservation in 2007 4 , it was not possible to remove these facings from parts of the paint surface without risking paint loss. Thus, a method comprising their removal and consolidation of the weakly bound and in parts flaking paint was proposed by the conservators and investigated on test objects specially designed for this study at the State Academy of Art and Design Stuttgart. Method and testing The fluorescent labelling of hydroxy propyl cellulose 5 with Fluorescein-5-isothiocyanate (FITC ‘Isomer I’) was executed before its application, thus guaranteeing a precise detection of the latter. During the fluorochromization reaction, FITC and hydroxy propyl cellulose formed a stable bond (see Fig. 1). Any free fluorochrome was removed in a subsequent dialysis. The non-fluorescing test wallpaper was produced by glueing together two layers of paper with wheat starch paste which were then painted with several layers of glue-bound ultramarine (see Fig. 2). 6 The test wallpapers were treated with a fluorescent-labelled hydroxy propyl cellulose (corresponding to the first conservation treatment in 2002): Facings consisting of Japanese tissue 7 were attached to the paint layer of the test objects with a ten per cent solution of the labelled cellulose ether in ethanol. Having allowed a sufficient period of drying, it was now tried to remove the papers and at the same time use the facings’ adhesive to consolidate the paint layer (corresponding to the current conservation treatment). The conservators in charge suggested that the hydroxy propyl cellulose should be treated ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013 88
sharp view of the cross sections and a clear detection of the fluorescing consolidant within the sample while weak auto fluorescences of the materials were eliminated. Fig. 2: Photos in visible light of thin sections (8 µm) of the original wallpaper (left) and the test wallpaper (right). Layers: 1 Paper support, lower layer; 2 wheat starch layer; 3 Paper support, upper layer; 4 paint layer. with ethanol and the dissolved consolidant be transported into the paint layer and between paint layer and paper support by means of low pressure, avoiding however the impregnation of the paper support. Application method and residence time of the solvent, as well as exposure to low pressure were varied (an overview of the conservation treatments can be seen in Table 1). After the consolidation method had been tested, samples were cut out, embedded in Technovit 2000 LC and cut with a microtome into 8 µm thick layers. The thin sections were examined with fluorescence microscopy using a filter set specially designed for FITC. The non-fluorescing test wallpaper appeared black while the labelled hydroxy propyl cellulose exhibited a bright green fluorescence. The thin sections allowed for a Results It was shown that different migration depths could be achieved by varying the application method of ethanol and by the time the test objects remained on the suction table (see Fig. 3). Best results were achieved when only applying the ethanol from the front and removing the test objects from low pressure as soon as the facing had been removed (treatments A and C). The consolidant accumulated between support and paint layer as well as within the weakly bound paint (visible in higher magnification). Exposing the sample to low pressure before the facing’s removal (2 min. in treatment C) had only little impact on the migration depth. Applying the ethanol also from the back (treatment B) resulted in the undesired effect of a slightly deeper penetration of the consolidant; however, the consolidant migrated mostly between paint layer and support as well as into the paint layer. Leaving the test object on the suction table after the removal of the facing (treatment D) lead to the complete penetration of the consolidant into the paper support while it was not any longer visible on or within the paint layer. This treatment was thus eliminated as an option. Based on these findings, it was possible to choose the appropriate parameters for the hydroxy propyl cellulose to migrate into the weakly bound paint and accumulate between paint layer and support without risking impregnation of the paper support. The application of fluorescent-labelled consolidant on test objects designed for the conserva- Test painting Ethanol application Removal of facing on suction table Left to dry on suction table A from the front (5 min swelling) immediately no B from the front and from the back (5 min swelling) immediately no C from the front (5 min swelling) after 2 min no D from the front (5 min swelling) after 2 min yes Table 1 Conservation Methods tested ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013 89
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sharp view of the cross sections and a clear detection<br />
of the fluorescing consolidant within the<br />
sample while weak auto fluorescences of the materials<br />
were eliminated.<br />
Fig. 2: Photos in visible light of thin sections (8 µm) of the original<br />
wallpaper (left) and the test wallpaper (right). Layers: 1 <strong>Paper</strong> support,<br />
lower layer; 2 wheat starch layer; 3 <strong>Paper</strong> support, upper layer;<br />
4 paint layer.<br />
with ethanol and the dissolved consolidant be<br />
transported into the paint layer and between<br />
paint layer and paper support by means of low<br />
pressure, avoiding however the impregnation of<br />
the paper support. Application method and residence<br />
time of the solvent, as well as exposure to<br />
low pressure were varied (an overview of the conservation<br />
treatments can be seen in Table 1).<br />
After the consolidation method had been tested,<br />
samples were cut out, embedded in Technovit<br />
2000 LC and cut with a microtome into 8 µm<br />
thick layers. The thin sections were examined<br />
with fluorescence microscopy using a filter set<br />
specially designed for FITC. The non-fluorescing<br />
test wallpaper appeared black while the labelled<br />
hydroxy propyl cellulose exhibited a bright green<br />
fluorescence. The thin sections allowed for a<br />
Results<br />
It was shown that different migration depths<br />
could be achieved by varying the application<br />
method of ethanol and by the time the test objects<br />
remained on the suction table (see Fig. 3).<br />
Best results were achieved when only applying<br />
the ethanol from the front and removing the test<br />
objects from low pressure as soon as the facing<br />
had been removed (treatments A and C). The consolidant<br />
accumulated between support and paint<br />
layer as well as within the weakly bound paint<br />
(visible in higher magnification). Exposing the<br />
sample to low pressure before the facing’s removal<br />
(2 min. in treatment C) had only little impact<br />
on the migration depth. Applying the ethanol<br />
also from the back (treatment B) resulted in the<br />
undesired effect of a slightly deeper penetration<br />
of the consolidant; however, the consolidant<br />
migrated mostly between paint layer and support<br />
as well as into the paint layer. Leaving the<br />
test object on the suction table after the removal<br />
of the facing (treatment D) lead to the complete<br />
penetration of the consolidant into the paper<br />
support while it was not any longer visible on or<br />
within the paint layer. This treatment was thus<br />
eliminated as an option.<br />
Based on these findings, it was possible to<br />
choose the appropriate parameters for the hydroxy<br />
propyl cellulose to migrate into the weakly<br />
bound paint and accumulate between paint layer<br />
and support without risking impregnation of the<br />
paper support.<br />
The application of fluorescent-labelled consolidant<br />
on test objects designed for the conserva-<br />
Test painting Ethanol application Removal of facing on suction table Left to dry on suction table<br />
A from the front (5 min swelling) immediately no<br />
B<br />
from the front and from the back<br />
(5 min swelling)<br />
immediately<br />
no<br />
C from the front (5 min swelling) after 2 min no<br />
D from the front (5 min swelling) after 2 min yes<br />
Table 1<br />
<strong>Conservation</strong> Methods tested<br />
ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013<br />
89