Paper Conservation: Decisions & Compromises
Paper Conservation: Decisions & Compromises Paper Conservation: Decisions & Compromises
Fig. 1: A woman with two children, Wilanow Palace Museum, photo by T. Rizov-Ciechanski time when the object was made and brought to Wilanow as well as its location within the palace turned out to be an incredibly difficult task. The object is a long panel with a representation of a nianhua type, bordered with an imitative nineteenth century hand-painted decoration depicting vases and a valance. In the centre of the composition is a lady clad in an outfit from the Ming era with two boys. This is a popular theme in Chinese New Year prints representing the wish to have many prominent sons. It was made in China, probably by using a hand-primed, woodcut technique of printing contour lines or, as Prof. Feng Jicai from the Feng Jicai Literature & Art Institute of Tianjin University in China has suggested, it was entirely painted. Its dimensions are 251x83 cm. In the Wilanow collection there is a similar separate object with dimensions of 158x64 cm. Such an attribution required to be supported by complementary technological and iconographic research. Stratigraphic studies were carried out in four different locations (Fig.1.IV-VII). The analysis showed that the number of layers ranges from four to nine, whereas the object’s thickness from 0.266 to 0.824 mm (1.034 mm with the canvas layer). An analysis of fibre composition showed that both the paper which constitutes the surface of the Chinese object and the first lining layer were made of paper mulberry (Broussonetia Papyrifera). It was probably xuan zhi (xuan paper). The second lining layer consists of paper mulberry, Edgeworthia gardineri, and rice straw. It was all stuck on 10 sheets of handmade paper made from flax fibres and connected by means of joining overlapping edges with starch paste. This paper is evenly covered with a yellow layer which has been identified as a mixture of glutin glue and litharge, where the painted layer was directly applied. The object was relined on canvas and mounted on the stretcher. Preliminary determination of binders was performed by microchemical methods. Starch was identified as a binder between subsequent layers of paper and the canvas with Lugol’s iodine test. The lack of stains after the application of Sudan Black B excluded the possibility of using oil binders or natural resins. Stains that appeared after using Ponceau S, which indicates the presence of proteins, might have been caused by starch penetrating the adjacent layers because of gravity and material porosity. Results obtained by using these methods, especially with regard to the layers where calcium carbonate or gypsum ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013 118
had been used, may be false-positive as these substances are good dye absorbents. Due to the limitations of the methods, it was necessary to perform further identification by using FTIR analysis. The first samples were obtained using swabs soaked in water, which allowed for selective isolation of substances which are the most water-soluble – plant gums, which also constitute the object’s top layer. It is probably the layer with which the object was coated in its entirety during conservation works in the 50s. The comparison of the obtained spectra with the spectra for substances in standard samples taken with a scalpel (Fig.1.I-III) provided a probable picture of animal glue content with a small addition of plant gums. In order to preliminarily establish the scope of work, non-destructive studies were carried out by using false-colour infrared photography. The difference between the infrared image (in the range of 500-900 nm) and a part of the visible spectrum indicated the presence of specific pigments (Fig.1.12-18). Prussian blue, ferrite and organic yellow as well as cinnabar were identified. Further studies were recommended, that were based on reflected-light microscope observation, water smears viewed in transmitted light, microcrystalline and drop reactions to test the presence of selected inorganic ions as well as analysis of the elemental composition of samples performed using the scanning electron microscope. Raman spectroscopy also proved useful. Eleven pigments were identified (Fig.1.1-11), three of which will be described in more detail. Blue pigment showed up as very small particle groupings in cloudy, greenish blue areas. The pigment was base-sensitive and it vanished after adding a base solution. Ferric ions were present in the obtained solution. This means that Prussian blue had been used. Prussian blue was identified both in the Chinese image and European border (Fig.1.11). This pigment was obtained in 1704. After 1750 it was brought to China by the East India Company. After 1825 it was produced in Canton. Red pigment showed high resistance to acid and base reagents. No solubility was observed. A very distinctive microscopic view revealed large, angular and intense red grains. Characteristic parallel striations were observed among the red grains of natural cinnabar. Cinnabar was identified in the border and the image’s part depicting the boy’s attire (Fig.1.5). It is a natural pigment Fig. 2: A woman under a blossoming tree, Wilanow Palace Museum, photo by T. Rizov-Ciechanski obtained by grinding the mineral and it was used in the ancient China as early as in the sixth and fifth century BC. It is called zhu sha. Rich cinnabar deposits are located in southern Chinese provinces. The method of manufacturing its artificial form, that is dry-process vermilion – yin zhu, was also developed in China at the beginning of our era. Microscopic observation of whites from the woman’s face suggested that there might be two white pigments. Apart from very large, angular and colourless grains, very small, non-characteristic particles were observed as transmitting a very small amount of light (Fig.1.6.a). The reaction with diluted hydrochloric acid revealed partial solubility. Some gas was released but a substantial part of the sample was left intact. SEM- EDS analysis (Fig.1.6.b) revealed mostly calcium, carbon and oxygen, thus evidencing the presence ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013 119
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Fig. 1: A woman with two children, Wilanow Palace Museum, photo by T. Rizov-Ciechanski<br />
time when the object was made and brought to<br />
Wilanow as well as its location within the palace<br />
turned out to be an incredibly difficult task.<br />
The object is a long panel with a representation<br />
of a nianhua type, bordered with an imitative<br />
nineteenth century hand-painted decoration<br />
depicting vases and a valance. In the centre of<br />
the composition is a lady clad in an outfit from<br />
the Ming era with two boys. This is a popular<br />
theme in Chinese New Year prints representing the<br />
wish to have many prominent sons. It was made<br />
in China, probably by using a hand-primed,<br />
woodcut technique of printing contour lines or,<br />
as Prof. Feng Jicai from the Feng Jicai Literature<br />
& Art Institute of Tianjin University in China has<br />
suggested, it was entirely painted. Its dimensions<br />
are 251x83 cm. In the Wilanow collection there<br />
is a similar separate object with dimensions of<br />
158x64 cm. Such an attribution required to be<br />
supported by complementary technological and<br />
iconographic research.<br />
Stratigraphic studies were carried out in four<br />
different locations (Fig.1.IV-VII). The analysis<br />
showed that the number of layers ranges from<br />
four to nine, whereas the object’s thickness<br />
from 0.266 to 0.824 mm (1.034 mm with the<br />
canvas layer). An analysis of fibre composition<br />
showed that both the paper which constitutes<br />
the surface of the Chinese object and the first<br />
lining layer were made of paper mulberry (Broussonetia<br />
Papyrifera). It was probably xuan zhi (xuan<br />
paper). The second lining layer consists of paper<br />
mulberry, Edgeworthia gardineri, and rice straw.<br />
It was all stuck on 10 sheets of handmade paper<br />
made from flax fibres and connected by means of<br />
joining overlapping edges with starch paste. This<br />
paper is evenly covered with a yellow layer which<br />
has been identified as a mixture of glutin glue<br />
and litharge, where the painted layer was directly<br />
applied. The object was relined on canvas and<br />
mounted on the stretcher.<br />
Preliminary determination of binders was performed<br />
by microchemical methods. Starch was<br />
identified as a binder between subsequent layers<br />
of paper and the canvas with Lugol’s iodine test.<br />
The lack of stains after the application of Sudan<br />
Black B excluded the possibility of using oil binders<br />
or natural resins. Stains that appeared after<br />
using Ponceau S, which indicates the presence<br />
of proteins, might have been caused by starch<br />
penetrating the adjacent layers because of gravity<br />
and material porosity. Results obtained by<br />
using these methods, especially with regard to<br />
the layers where calcium carbonate or gypsum<br />
ICOM-CC Graphic Documents Working Group Interim Meeting | Vienna 17 – 19 April 2013<br />
118