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Surface Modification of Cellulose Acetate with Cutinase and ...

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Subchapter 3.1<br />

Wool is a complex natural fibre being mainly composed <strong>of</strong> proteins (97%) <strong>and</strong> lipids<br />

(1%). 82% <strong>of</strong> total protein content <strong>of</strong> wool is keratinous proteins, which are<br />

characterized by a high concentration <strong>of</strong> cystine. Approximately 17% <strong>of</strong> wool is<br />

composed <strong>of</strong> proteins which have been termed non keratinous, because <strong>of</strong> their<br />

relatively low cystine content (Feughelman, 1997 Rippon, 1992).<br />

Figure 1. Cross-section diagram <strong>of</strong> a merino wool fibre showing the structure at<br />

progressive magnification (Feughelman, 1997).<br />

Wool fibres have approximately the form <strong>of</strong> elliptical cylinders, <strong>with</strong> average diameters<br />

ranging from 15 μm to 50 μm <strong>and</strong> lengths depending <strong>of</strong> the rate <strong>of</strong> growth <strong>and</strong> the<br />

shearing regimes, as previous mentioned (Makinson, 1979). The wool fibre consists <strong>of</strong><br />

two major morphological parts: cuticle <strong>and</strong> cortex. The cuticle (also referred as scale<br />

layer <strong>of</strong> wool) is composed <strong>of</strong> laminar <strong>and</strong> rectangular structures which form a sheath <strong>of</strong><br />

overlapping scales enveloping the cortex (Speakman, 1985; Naik <strong>and</strong> Speakman, 1993).<br />

It is normally one cell thick <strong>and</strong> usually constitutes about 10% by weight <strong>of</strong> the total<br />

fiber. The cuticle is subdivided into three layers: exocuticle (which is subdivided into<br />

two main layers, A <strong>and</strong> B that differ mainly in the cystine content), endocuticle, <strong>and</strong> an<br />

outermost membrane called the epicuticle (Figure 2).<br />

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