Nuclear Production of Hydrogen, Fourth Information Exchange ...

Nuclear Production of Hydrogen, Fourth Information Exchange ... Nuclear Production of Hydrogen, Fourth Information Exchange ...

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STATUS OF THE KOREAN NUCLEAR HYDROGEN PRODUCTION PROJECT Introduction The effect of rapid climate change in Korea is more than twice than the world average. The increment in the temperature is 0.015°C per year and that of sea level is 0.1 to 0.2 cm per year. Moreover, energy consumption is the ninth rank in the world to support its heavy trade depending economy growth. About 97% of primary energy fuel is imported from foreign countries. The heavy reliance on the imported fuel degrades the energy security of Korea. To mitigate climate change as well as to enhance energy security, the Korean government has developed a master plan for the hydrogen economy in 2005 (MOCIE, 2005). The main components of the plan are to develop until 2020, to demonstrate until 2030, and to commercialise the required technologies for using, producing, storing and supplying the hydrogen fuel to public. The plan includes production hydrogen using a Generation IV nuclear reactor system with proven safety and environment friendliness. Recently the Korean Atomic Energy Committee has approved the nuclear hydrogen production development and demonstration plan as shown in Figure 1. The final goal of the plan is to commercialise the production of nuclear hydrogen technology before 2030. An extensive research and development programme for the production of hydrogen using nuclear power has been underway since 2004 in Korea. During the first three years, a technological area was identified for the economic and efficient production of hydrogen using a VHTR. A pre-conceptual design of the commercial nuclear hydrogen production plant was also performed. As a result, the key technology area in the core design, the hydrogen production process, the coupling between reactor and chemical side, and the coated fuel was identified. During last three years, research activities have been focused on the key technology areas to resolve the technical challenges in the efficient nuclear hydrogen production. The results of first phase research increase the confidence and mitigate the risk on the nuclear hydrogen technology. From 2009, the government decided to support further key technology development on an enlarged scale in correspondence with the Generation IV International Forum. The second phase of key technology development will further reduce the technical and economical risk in the nuclear hydrogen project. The government is also considering the construction of the Nuclear Hydrogen Development and Demonstration (NHDD) plant and will start funding for a conceptual design activity from 2010. Massive hydrogen production using VHTR is necessary to support growing demand of hydrogen as a fuel as well as a chemical feedstock. Figure 1: Nuclear hydrogen development plan 60 NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010

STATUS OF THE KOREAN NUCLEAR HYDROGEN PRODUCTION PROJECT Candidate NHDD system Considering economic production of hydrogen, the reaction temperature of a water-splitting process should be above 850°C. To achieve this temperature at the chemical reactor, the nuclear reactor should produce a heat of around 950°C. The NHDD reactor design aims at a 950°C outlet temperature as the technology development target. To enhance safety and to reduce technical risk, the NHDD reactor adopted a forged vessel with the conventional LWR pressure vessel material (Chang, 2007). The power capacity is set as 200 MW thermal to stay within the current vessel manufacturing capability in Korean industries. Table 1: NHDD system parameters Parameter PMR200 PBR200 Thermal power (MWth) 200 200 Equivalent active core inner/outer radius (cm) 50/140 80/147 Thickness of outer reflector (cm) 100 90 Effective core height (cm) 555 873 Average power density (W/cc) 6.69 4.79 Primary helium inlet/outlet temperature (°C) 490/950 490/950 Primary helium pressure (MPa) 7.0/6.95 7.0/6.87 Primary helium flow rate (kg/s) 82 83.2 RCCS inlet/outlet temperature (°C) 43/217 43/169 Peak fuel temperature (°C) 1 165 1 156 NHDD, which is proposed as a mid-term project, adopted a cooled vessel concept. The vessel material will be SA508/533 steel in which there are many experiences on forging, welding, etc. Analyses on the additional heat loss during normal operation and the peak temperature during accident confirm that the cooled vessel concept is applicable (Kim, M-H., 2008) until full manufacturing capability is developed for the high chromium steel vessel. Two types of core, a prismatic block (PMR) and a pebble bed (PBR), are studied for NHDD reactor. Each reactor type has pro and cons for hydrogen production. Currently, the more important issue is to resolve the technical challenges in supplying the high temperature heat to chemical reactor efficiently and safely. Since frequent maintenance such as catalyst replacement of a chemical plant is expected, the hydrogen production plant of NHDD consists of five trains. A multi-train approach may enhance plant availability as well as the possibility of testing various hydrogen production processes in an industrial environment before selecting adequate commercial process. A conceptual design of NHDD system is expected to be started in 2010 for three years. Design tools Many design tools were developed for the gas reactor analysis as well as for the hydrogen production assessment. A neutron diffusion solver is practical to handle the large number of cases including the sensitivity calculations for reactivity coefficient at several depletion steps. Computer tools for the reactor physics analysis are developed to support PMR and PBR design. To handle the double heterogeneity of coated particle, a special method named “reactivity equivalence physical transformation” (RPT) was introduced (Kim, 2005). A Monte Carlo code MCNP is adopted as a standard code in the design procedure in the RPT-based analysis methodology as shown in Figure 2. The idea of RPT was extended to pebble geometry as well. The RPT method applied for PMR and PBR results reasonably accurate prediction capability (Noh, 2008). Many computer codes are required for design and safety analysis of a VHTR system as displayed in Figure 2. HyPEP is a computer code to do scoping analysis of the VHTR, PCS and hydrogen plant coupled system. HyPEP can be used to set operating parameters of the nuclear hydrogen production system. The probabilistic safety analysis is done by PSA-AIMS. The detailed thermo-fluid analysis is performed by the thermo-fluid code MARS-GCR combined with the reactor physics code MASTER-GCR. A system analysis code GAMMA (No, 2007) is developed to handle air/moisture ingress situation. GAMMA solves an integrated system of equations for the chemical reactions and the conventional NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 61

STATUS OF THE KOREAN NUCLEAR HYDROGEN PRODUCTION PROJECT<br />

Candidate NHDD system<br />

Considering economic production <strong>of</strong> hydrogen, the reaction temperature <strong>of</strong> a water-splitting process<br />

should be above 850°C. To achieve this temperature at the chemical reactor, the nuclear reactor<br />

should produce a heat <strong>of</strong> around 950°C. The NHDD reactor design aims at a 950°C outlet temperature<br />

as the technology development target. To enhance safety and to reduce technical risk, the NHDD<br />

reactor adopted a forged vessel with the conventional LWR pressure vessel material (Chang, 2007).<br />

The power capacity is set as 200 MW thermal to stay within the current vessel manufacturing capability<br />

in Korean industries.<br />

Table 1: NHDD system parameters<br />

Parameter PMR200 PBR200<br />

Thermal power (MWth) 200 200<br />

Equivalent active core inner/outer radius (cm) 50/140 80/147<br />

Thickness <strong>of</strong> outer reflector (cm) 100 90<br />

Effective core height (cm) 555 873<br />

Average power density (W/cc) 6.69 4.79<br />

Primary helium inlet/outlet temperature (°C) 490/950 490/950<br />

Primary helium pressure (MPa) 7.0/6.95 7.0/6.87<br />

Primary helium flow rate (kg/s) 82 83.2<br />

RCCS inlet/outlet temperature (°C) 43/217 43/169<br />

Peak fuel temperature (°C) 1 165 1 156<br />

NHDD, which is proposed as a mid-term project, adopted a cooled vessel concept. The vessel<br />

material will be SA508/533 steel in which there are many experiences on forging, welding, etc. Analyses<br />

on the additional heat loss during normal operation and the peak temperature during accident confirm<br />

that the cooled vessel concept is applicable (Kim, M-H., 2008) until full manufacturing capability is<br />

developed for the high chromium steel vessel.<br />

Two types <strong>of</strong> core, a prismatic block (PMR) and a pebble bed (PBR), are studied for NHDD reactor.<br />

Each reactor type has pro and cons for hydrogen production. Currently, the more important issue is to<br />

resolve the technical challenges in supplying the high temperature heat to chemical reactor efficiently<br />

and safely. Since frequent maintenance such as catalyst replacement <strong>of</strong> a chemical plant is expected,<br />

the hydrogen production plant <strong>of</strong> NHDD consists <strong>of</strong> five trains. A multi-train approach may enhance<br />

plant availability as well as the possibility <strong>of</strong> testing various hydrogen production processes in an<br />

industrial environment before selecting adequate commercial process.<br />

A conceptual design <strong>of</strong> NHDD system is expected to be started in 2010 for three years.<br />

Design tools<br />

Many design tools were developed for the gas reactor analysis as well as for the hydrogen production<br />

assessment. A neutron diffusion solver is practical to handle the large number <strong>of</strong> cases including the<br />

sensitivity calculations for reactivity coefficient at several depletion steps. Computer tools for the reactor<br />

physics analysis are developed to support PMR and PBR design. To handle the double heterogeneity <strong>of</strong><br />

coated particle, a special method named “reactivity equivalence physical transformation” (RPT) was<br />

introduced (Kim, 2005). A Monte Carlo code MCNP is adopted as a standard code in the design<br />

procedure in the RPT-based analysis methodology as shown in Figure 2. The idea <strong>of</strong> RPT was extended<br />

to pebble geometry as well. The RPT method applied for PMR and PBR results reasonably accurate<br />

prediction capability (Noh, 2008).<br />

Many computer codes are required for design and safety analysis <strong>of</strong> a VHTR system as displayed<br />

in Figure 2. HyPEP is a computer code to do scoping analysis <strong>of</strong> the VHTR, PCS and hydrogen plant<br />

coupled system. HyPEP can be used to set operating parameters <strong>of</strong> the nuclear hydrogen production<br />

system. The probabilistic safety analysis is done by PSA-AIMS. The detailed thermo-fluid analysis is<br />

performed by the thermo-fluid code MARS-GCR combined with the reactor physics code MASTER-GCR.<br />

A system analysis code GAMMA (No, 2007) is developed to handle air/moisture ingress situation.<br />

GAMMA solves an integrated system <strong>of</strong> equations for the chemical reactions and the conventional<br />

NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 61

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