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Nuclear Production of Hydrogen, Fourth Information Exchange ...

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HEAT PUMP CYCLE BY HYDROGEN-ABSORBING ALLOYS TO ASSIST HTGR IN PRODUCING HYDROGEN<br />

Conclusions<br />

A chemical heat pump system was proposed to enhance the heat utilisation <strong>of</strong> HTGR. The overall heat<br />

pump cycle was explained on the pressure-reciprocal temperature relation. A heat pump packed<br />

with two hydrogen-absorbing alloys can be designed for its operation during three heat sources<br />

corresponding to the three decomposition reactions comprised in the S-I cycle. A Zr(V 1-X Fe X ) 2 alloy<br />

was tested for a high-temperature heat pump system to assist energy conversion <strong>of</strong> HTGR. A small<br />

mock-up test using ZrV 1.9 Fe 0.1 particles proved to be able to heat up the temperature <strong>of</strong> the heat pump<br />

at least ΔT = 100°C at the initial temperature <strong>of</strong> T 0 = 600°C. Fast hydrogen desorption from the alloy was<br />

also proved experimentally.<br />

Acknowledgements<br />

This research was performed under the Centre <strong>of</strong> Excellence (COE) programme supported by the<br />

Ministry <strong>of</strong> Education, Culture, Sports, Science and Technology. The programme is entitled “A Challenge<br />

<strong>of</strong> Reliable <strong>Hydrogen</strong>-related Technology”. Our research group belongs to the <strong>Hydrogen</strong> Technology<br />

Research Centre <strong>of</strong> Kyushu University: www.mech.kyushu-u.ac.jp/h2/english/. We would like to express<br />

our gratitude to all the students who belong to our laboratory.<br />

References<br />

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Science Forum, 31, 1-18.<br />

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Tube Bed Packed with ZrV 1.9 Fe 0.1 Particles”, Journal <strong>of</strong> Alloys and Compounds, 375, 305-312.<br />

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414 NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010

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