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Nuclear Production of Hydrogen, Fourth Information Exchange ...

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USE OF PSA FOR DESIGN OF EMERGENCY MITIGATION SYSTEMS IN A HYDROGEN PRODUCTION PLANT<br />

In the particular case <strong>of</strong> Section II <strong>of</strong> the SI process <strong>of</strong> General Atomics, an adequate system <strong>of</strong><br />

isolation, a system for neutralisation and a second electrical power back-up will maintain the frequency<br />

<strong>of</strong> toxic cloud formation, resulting from leakage <strong>of</strong> sulphuric acid, below 1E-09 per year, which is only<br />

16% <strong>of</strong> the frequency calculated for a system whose design is based only on process engineering.<br />

It should be noted that in areas where there is not a reliable supply <strong>of</strong> electricity, the reliability <strong>of</strong><br />

back-up electrical generators is one <strong>of</strong> the elements that have more influence on the overall safety <strong>of</strong><br />

a mitigation system.<br />

Acknowledgements<br />

Special thanks to the National Council for Science and Technology (Conacyt), as well as to<br />

Ms. Jenny Medina and Alejandro and Fernando Mendoza for their valuable contribution to this work.<br />

References<br />

AICHE/CCPS (1989), Guidelines for Process Equipment Reliability Data.<br />

Associated Press (2008), “The New York Times”, Page A39, 12 October, New York, USA.<br />

Bari, R.A., et al. (1985), Probabilistic Safety Analysis Procedures Guide, NUREG/CR-2815 [BNL-NUREG-51559],<br />

Brookhaven National Laboratory, Upton, NY, August.<br />

Brown, L.C., et al. (2003), Alternative Flowsheet for the Sulfur Iodine Thermochemical <strong>Hydrogen</strong> Cycle, Report<br />

GAA24266, General Atomics, USA.<br />

Fullwood, Ralph R. (2000), Probabilistic Safety Assessment in the Chemical and <strong>Nuclear</strong> Industries,<br />

Butterworth Heinemann, New York, USA.<br />

Greenberg, Harris R., Joseph J. Cramer (1991), Risk Assessment and Risk Management for the Chemical<br />

Process Industry, Van Nostrand Reinhold, New York, USA.<br />

Kasahara, Seiji, et al. (2007), “Flowsheet Study <strong>of</strong> the Thermochemical Water-splitting Iodine-Sulfur<br />

Process for Effective <strong>Hydrogen</strong> <strong>Production</strong>”, International Journal <strong>of</strong> <strong>Hydrogen</strong> Energy, 32, pp. 489-496.<br />

McAdams, R.L. (2006), Material Safety Data Sheets, Report ACC #37575, USA.<br />

Mendoza, Alexander (2009), Aspectos Técnicos, Económicos y Ambientales de la Producción de Hidrógeno por<br />

Método SI con un Reactor <strong>Nuclear</strong> de Alta Temperatura, Master’s Thesis in progress, UNAM, Mexico.<br />

Norman, John H., Thomas S. Roener, et al. (1978), Process for <strong>Hydrogen</strong> <strong>Production</strong> from Water, US Patent<br />

4,127,644, General Atomics, USA.<br />

Smith, C.L. (2005), Systems Analysis Programs for Hands-on Integrated Reliability Evaluations (SAPHIRE)<br />

v. 6.77, Idaho National Laboratory, Idaho Falls, ID.<br />

406 NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010

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