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Nuclear Production of Hydrogen, Fourth Information Exchange ...

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POSSIBILITY OF ACTIVE CARBON RECYCLE ENERGY SYSTEM<br />

Figure 2: Concept <strong>of</strong> ACRES<br />

C x H y O z + O 2<br />

E<br />

W<br />

Material<br />

CO 2 + H 2 O<br />

CO 2 reduction/oxidation<br />

Carbon dioxide system<br />

have quite a high affinity with common manufacturing industries. If the carbon recycle system can be<br />

established thermally and kinetically, it is expected that the system would be easily integrated into<br />

conventional industries. A natural carbon recycle energy system has already existed in plant life in<br />

nature, and is an ideal recycle system. However, the potential amount <strong>of</strong> biomass is not sufficient for<br />

a modern society. Specifically, it is less than 10% <strong>of</strong> all energy demand in Japan. The natural recycle<br />

system thus cannot sustain energy demand in Japan (Kameyama, 2005). Therefore, an artificial active<br />

carbon recycle system was proposed as ACRES in this study. The feasibility <strong>of</strong> ACRES was discussed<br />

from enthalpy balances in this paper.<br />

Structure <strong>of</strong> ACRES<br />

The structure <strong>of</strong> ACRES shown in Figure 3 consists <strong>of</strong> three elemental processes <strong>of</strong> hydrocarbon usage,<br />

CO 2 recovery and separation, and hydrocarbon regeneration. In the usage process, the hydrocarbon can<br />

be used for both heat source and material. CO 2 generated from hydrocarbon consumption is recovered<br />

by physical and chemical sorptions. Sorbed CO 2 in a sorption material is separated thermally from<br />

material by a heat input. This process produces highly concentrated CO 2 . The recovered CO 2 is<br />

regenerated into hydrocarbon in the regeneration process. The regeneration process is endothermic<br />

and requires energy input. In ACRES, the total energy input at recovery and separation (E S ), and<br />

regeneration (E R ) should be larger than the energy output at the usage process (E U ).<br />

E S + E R > E U (1)<br />

ACRES is energy consumption process, then, a discussion <strong>of</strong> the energy balance <strong>of</strong> the system is<br />

required for the feasibility evaluation <strong>of</strong> the system.<br />

Figure 3: The three elemental processes in ACRES<br />

Recovery and<br />

separation<br />

Recov./Sep. energy<br />

Effluent CO 2<br />

Usage<br />

Separated CO 2<br />

Regen. energy<br />

Materials<br />

Energy<br />

Regeneration<br />

Hydro carbon<br />

Input E > output E<br />

Carbon flow<br />

NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 347

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