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Nuclear Production of Hydrogen, Fourth Information Exchange ...

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NUCLEAR H 2 PRODUCTION – A UTILITY PERSPECTIVE<br />

the DOE’s NGNP project that focuses on extending HTGR technology for commercial deployment as a<br />

passively safe, process heat producer that can be co-located with an energy end-user facility. Although a<br />

variety <strong>of</strong> water-splitting processes have been evaluated for coupling to an advanced HTGR, the leading<br />

candidates currently under consideration include the sulphur-iodine (SI) process, the hybrid sulphur<br />

(HyS) process, and the high-temperature steam electrolysis (HTSE) process. One additional hydrogen<br />

production option using an advanced technology that has received consideration is the coupling <strong>of</strong><br />

the HTGR heat source with a steam methane reforming (SMR) facility. While the preliminary economic<br />

projections for this SMR coupled option are somewhat appealing, there several attendant disadvantages<br />

remain. They include consumption <strong>of</strong> a premium fossil fuel (natural gas), cost fluctuations associated<br />

with natural gas price volatility, and carbon emissions associated with the reformation process.<br />

Assessing the economic viability <strong>of</strong> hydrogen production using advanced technologies will<br />

require a variety <strong>of</strong> considerations including evaluation <strong>of</strong> capital or investments costs, operating and<br />

maintenance costs, technical risks, safety, operability and reliability. Since these advanced technologies<br />

are still in the developmental stage, there is large uncertainty in cost projections and as a consequence<br />

no definitive judgment can be made regarding commercial viability. As the developmental efforts on<br />

HTGR and the advanced water-splitting technologies progress, however, better certainty in assessing<br />

commercial viability will evolve. We also believe, however, that other considerations such as volatility<br />

in fossil fuel pricing, the security <strong>of</strong> energy supply and the possible enactment <strong>of</strong> carbon emissions<br />

legislation might well become influential in making the business case for these technologies.<br />

Market outlook<br />

Based on our participation in nuclear production <strong>of</strong> hydrogen studies, it appears that the best market<br />

potential for nuclear production <strong>of</strong> hydrogen in the foreseeable future will involve the HTGR<br />

technology coupled with either one <strong>of</strong> the advanced thermochemical water-splitting processes or<br />

coupling an HTGR to an SMR facility. Over the past several years, Entergy along with NGNP project<br />

personnel have conducted an outreach programme in the industrial sector to assess the potential<br />

market for these advanced technologies. As a result <strong>of</strong> this outreach effort, a large potential market<br />

for these technologies beyond the traditional nuclear energy applications <strong>of</strong> electric power generation<br />

has become more apparent. The distinct characteristics and capabilities <strong>of</strong> HTGR technology appear to<br />

be well suited for industrial application where there is a demand for high temperature process heat.<br />

These potential applications include:<br />

• “upstream” petroleum recovery operations such as enhanced oil recovery, tar sands production<br />

and oil shale recovery;<br />

• “downstream” petrochemical/refinery operations;<br />

• fertiliser production operations;<br />

• industrial chemical facility operations;<br />

• coal-to-liquids (CTL) and coal-to-gas (CTG) conversion processes (inclusive <strong>of</strong> H 2 production).<br />

We believe that these applications represent a large potential market and should provide the<br />

incentive necessary to pursue development <strong>of</strong> these advanced technologies to the point where more<br />

definitive judgments regarding their commercial viability can be made. Several independent studies<br />

have been conducted and conservatively estimate the size <strong>of</strong> these potential markets to be well over<br />

600 modules (assuming ~500 MWth per reactor module). Several specific market areas are described in<br />

the following subsections to better characterise the potential application and markets for the<br />

advanced HTGR and hydrogen production technologies.<br />

Tar sands<br />

The Canadian tar sands deposits in Alberta are the second largest oil reserves in the world after those<br />

<strong>of</strong> Saudi Arabia. It is estimated that the total recoverable reserves are approximately equivalent to<br />

200 billion barrels <strong>of</strong> oil, an order <strong>of</strong> magnitude larger than the oil reserves <strong>of</strong> the United States. Tar<br />

sands are mixtures <strong>of</strong> bitumen (a heavy, viscous oil), sand, water and clay. The bitumen is a solid at<br />

room temperature. With surface mining operations, the mixture is heated in large tanks until the<br />

sand and clay settle and the oil floats on the hot water to the top <strong>of</strong> the tank. There are also in situ oil<br />

NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 293

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