Nuclear Production of Hydrogen, Fourth Information Exchange ...

Nuclear Production of Hydrogen, Fourth Information Exchange ... Nuclear Production of Hydrogen, Fourth Information Exchange ...

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NUCLEAR HYDROGEN USING HIGH TEMPERATURE ELECTROLYSIS AND LIGHT WATER REACTORS FOR PEAK ELECTRICITY PRODUCTION • Response time. When a reactor is kept operating at high power output and the plant electricity is used for operating an electrolysis system, the electricity can be switched in a fraction of a second from the electrolysis plant to the electrical grid. The fast response times enables this system to be used to regulate the electrical grid (see section entitled Economics). Oxy-hydrogen steam turbine The storage of oxygen and hydrogen at pressure provides a second method of peak electricity production: the oxy-hydrogen steam turbine (Figure 2). Hydrogen, oxygen, and water are fed directly to a burner to produce high pressure, very high temperature steam. Because the combustion temperature of a pure hydrogen-oxygen flame is far beyond that of current materials of construction, water is added to lower the peak temperatures. The technology is that of a low-performance rocket engine. The resultant steam is fed directly to a very high temperature turbine that drives an electric generator. Through the use of advancing gas turbine technology with actively cooled blades, it is expected that peak steam temperatures at the inlet of the first turbines can approach 1 500°C. The projected heat-to-electricity efficiency for advanced turbines approaches ~70%, starting with compress oxygen and hydrogen from the storage facilities. The technology is based on ongoing development of an advanced natural gas electric plant that uses oxygen rather than air (Anderson, 2004) Combustors with outputs of ~20 MW(t) are being tested. With a feed of natural gas and oxygen, a mixture of steam and carbon dioxide is created. After it passes through the turbine to the condenser, the steam is condensed and the carbon dioxide is available for: i) injection into oil fields to increase the recovery of oil and/or ii) sequestration. The higher heat-to-electricity efficiency and the production of a clean carbon dioxide gas stream for long-term sequestration of the carbon dioxide greenhouse gases has created strong incentives to develop oxy-fuel combustors for burning of fossil fuels. Figure 2: Oxygen-hydrogen-water steam cycle 06-016 Hydrogen Steam Turbine Oxygen Burner Steam 1500º C Generator Water Cooling Water In Out Pump Condenser The capital costs (Forsberg, 2009b) for the oxy-hydrogen steam turbine system are significantly less than those for any existing methods to convert fossil fuels to electricity. The low capital-cost peak-power production technology is the natural-gas-fired combined-cycle plant with a high temperature gas turbine producing electricity and the hot gas turbine exhaust being sent to a steam boiler with the steam used to produce additional electricity. As is the case for traditional combined cycle plants, the turbine remains in the oxy-hydrogen steam cycle but the need to compress air as an oxidiser is eliminated, as well as the massive gas flow of nitrogen (80% of air) through the system. Equally important, the expensive high-surface-area boiler in the combined-cycle plant is also eliminated. These changes simultaneously increase efficiency (55 to 70%) and lower the capital costs. The low capital costs relative to any other method of peak electricity production allow the peak power system to be sized independently of the reactor or hydrogen production system. 160 NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010

NUCLEAR HYDROGEN USING HIGH TEMPERATURE ELECTROLYSIS AND LIGHT WATER REACTORS FOR PEAK ELECTRICITY PRODUCTION Combined peak power system The high temperature electolyser/fuel cell and oxy-hydrogen steam cycle are complementary technologies. The high temperature electrolyser as a peak-power fuel cell is the economic peak power option up to the capacity of the electrolyser/fuel cells required for hydrogen production. The same equipment is used for both hydrogen and electricity production. For added peak power capacity, the oxy-hydrogen steam turbine is expected to have significantly lower capital costs but it cannot generate hydrogen from electricity. It may become a critical technology for an electrical grid with significant renewable electricity production and the need for very large quantities of back-up power when local weather conditions shut down wind or solar systems. Economics While there are large unknowns about the cost of high temperature electrolysis systems, an economic assessment can be made of the peak electricity market underlying the potential system economics. The distinguishing characteristic of this system is that the electricity is sold to meet the needs of three premium markets (US DOE, 2007b), in which the value and price of electricity are far above the price of base-load electricity. These three markets (Table 1) determine the technical requirements and economic viability of the concept. Table 1: United States premium power-grid electrical markets (DOE, 2007b) Technology parameter Capital cost ($/kW) Total market potential (GW) Regulation Reserve power for grid stability and reliability 700 300-1 000 30-40 70-100 Load shifting and load levelling 300 (load levelling) 400-1 000 (peak shaving and load shifting) 650 (renewables) 80 (cost sensitive, excludes seasonal shifting) System power level Up to 200 MW 10 MW to 1 GW 1 MW to 1 GW Discharge time at rated power Capacity (storage time) Seconds 0.2 to 2 h 1 to 8 h Seconds ~ 2 weeks Hours to days (months for seasonal shifts) Lifetime (years) 20 40 7–10 Regulation Electric consumers turn equipment on and off with switches that operate in a fraction of a second. Electric generators can vary the power output over a period of minutes. If the demand and generation do not match, the system frequency and voltage change. If the changes are too great, both customer and utility equipment is damaged. Ultimately, the system fails, with a resultant blackout. The electrical system works because the electric grid averages demand over many customers so that the generators do not experience rapid changes in power demand. As a consequence, the larger electrical grids are more stable, have higher quality electricity (proper voltage and frequency), and are more reliable than smaller electrical grids. However, the stability of many electrical grids is decreasing because of changes in technology such as the increased use of electronics. With traditional electrical loads, such as incandescent light bulbs, if the line voltage drops (i.e. because of insufficient power generation), both the electrical current and the power demand drop. This decreased demand provides time for the electrical generators to speed up or slow down as required to match power production with power demand. With many electronic devices, as the voltage drops, the device demands more current and the power demand goes up. The system provides less time for electrical generators to respond to the demand. The system becomes more prone to failure, and the quality of electricity decreases. NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 161

NUCLEAR HYDROGEN USING HIGH TEMPERATURE ELECTROLYSIS AND LIGHT WATER REACTORS FOR PEAK ELECTRICITY PRODUCTION<br />

Combined peak power system<br />

The high temperature electolyser/fuel cell and oxy-hydrogen steam cycle are complementary<br />

technologies. The high temperature electrolyser as a peak-power fuel cell is the economic peak power<br />

option up to the capacity <strong>of</strong> the electrolyser/fuel cells required for hydrogen production. The same<br />

equipment is used for both hydrogen and electricity production. For added peak power capacity, the<br />

oxy-hydrogen steam turbine is expected to have significantly lower capital costs but it cannot generate<br />

hydrogen from electricity. It may become a critical technology for an electrical grid with significant<br />

renewable electricity production and the need for very large quantities <strong>of</strong> back-up power when local<br />

weather conditions shut down wind or solar systems.<br />

Economics<br />

While there are large unknowns about the cost <strong>of</strong> high temperature electrolysis systems, an economic<br />

assessment can be made <strong>of</strong> the peak electricity market underlying the potential system economics.<br />

The distinguishing characteristic <strong>of</strong> this system is that the electricity is sold to meet the needs <strong>of</strong><br />

three premium markets (US DOE, 2007b), in which the value and price <strong>of</strong> electricity are far above the<br />

price <strong>of</strong> base-load electricity. These three markets (Table 1) determine the technical requirements and<br />

economic viability <strong>of</strong> the concept.<br />

Table 1: United States premium power-grid electrical markets (DOE, 2007b)<br />

Technology parameter<br />

Capital cost<br />

($/kW)<br />

Total market potential<br />

(GW)<br />

Regulation<br />

Reserve power for grid<br />

stability and reliability<br />

700 300-1 000<br />

30-40 70-100<br />

Load shifting and load levelling<br />

300 (load levelling)<br />

400-1 000 (peak shaving and load shifting)<br />

650 (renewables)<br />

80<br />

(cost sensitive, excludes seasonal shifting)<br />

System power level Up to 200 MW 10 MW to 1 GW 1 MW to 1 GW<br />

Discharge time<br />

at rated power<br />

Capacity<br />

(storage time)<br />

Seconds 0.2 to 2 h 1 to 8 h<br />

Seconds<br />

~ 2 weeks<br />

Hours to days<br />

(months for seasonal shifts)<br />

Lifetime (years) 20 40 7–10<br />

Regulation<br />

Electric consumers turn equipment on and <strong>of</strong>f with switches that operate in a fraction <strong>of</strong> a second.<br />

Electric generators can vary the power output over a period <strong>of</strong> minutes. If the demand and generation<br />

do not match, the system frequency and voltage change. If the changes are too great, both customer<br />

and utility equipment is damaged. Ultimately, the system fails, with a resultant blackout. The electrical<br />

system works because the electric grid averages demand over many customers so that the generators<br />

do not experience rapid changes in power demand. As a consequence, the larger electrical grids are<br />

more stable, have higher quality electricity (proper voltage and frequency), and are more reliable than<br />

smaller electrical grids.<br />

However, the stability <strong>of</strong> many electrical grids is decreasing because <strong>of</strong> changes in technology<br />

such as the increased use <strong>of</strong> electronics. With traditional electrical loads, such as incandescent light<br />

bulbs, if the line voltage drops (i.e. because <strong>of</strong> insufficient power generation), both the electrical current<br />

and the power demand drop. This decreased demand provides time for the electrical generators to<br />

speed up or slow down as required to match power production with power demand. With many<br />

electronic devices, as the voltage drops, the device demands more current and the power demand<br />

goes up. The system provides less time for electrical generators to respond to the demand. The<br />

system becomes more prone to failure, and the quality <strong>of</strong> electricity decreases.<br />

NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 161

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