Nuclear Production of Hydrogen, Fourth Information Exchange ...

Nuclear Production of Hydrogen, Fourth Information Exchange ... Nuclear Production of Hydrogen, Fourth Information Exchange ...

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TABLE OF CONTENTS S. Fukada, N. Hayashi Heat pump cycle by hydrogen-absorbing alloys to assist high-temperature gas-cooled reactor in producing hydrogen ........................................................................... 407 R. Vilim Heat exchanger temperature response for duty-cycle transients in the NGNP/HTE ................................................................................................................................. 417 R. Vilim Alternate VHTR/HTE interface for mitigating tritium transport and structure creep ......................................................................................................................... 433 Poster session contributions ....................................................................................................................... 445 A. Doucek, L. Janik, J. Misak Activities of Nuclear Research Institute Rez in the area of hydrogen technologies ............................................................................................................................. 447 C. Forsberg, J. Collins, L. Dole, J. Ferrada, M.J. Haire, R. Hunt, J.L. Ladd-Lively, B. Lewis, R. Wymer A uranium thermochemical cycle for hydrogen production ............................................. 453 Annex 1 Meeting organisation .................................................................................................................... 457 Annex 2 List of participants ........................................................................................................................ 459 8 NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010

EXECUTIVE SUMMARY Executive summary Session 1: Programme overviews Chairs: Yoshiyuki Nemoto (OECD/NEA), Carl Sink (US DOE) Programme overviews from USA, France, Japan, Korea, Russia and Canada were presented in Session 1. As less than 30% of the thermal energy from a nuclear power plant is used to generate electricity, nuclear production of hydrogen should be developed to utilise the remaining energy. This would especially be appropriate for some of the next generation high-temperature nuclear plants. It was suggested that an economic and efficient use of thermal energy from a nuclear power plant would be to utilise the surplus energy for hydrogen production during periods in which electricity consumption is relatively low. Outlines of research and development programmes for several nuclear hydrogen production technologies, such as high-temperature steam electrolysis (HTE), and sulphur-iodine (S-I) and hybrid sulphur (HyS) thermochemical processes were introduced. The panel discussion, which followed the presentations, discussed the criteria for choosing the best hydrogen production system and suggested that the selection would be judged mainly on economic criteria. Detailed information about the economic analysis and considerations was presented in Session 5. Potential future hydrogen applications were discussed. As a huge amount of CO 2 is emitted from the transport sector, it would greatly reduce CO 2 emissions and prevent global warming if, for example, hybrid automobiles could be fuelled by electricity from nuclear power plants, oil fuels made from biomass and hydrogen produced by nuclear power plants. Other issues discussed by the panel related to gasoline upgrading and iron production using hydrogen. It was generally acknowledged that a sustainable energy production is required in the future. From this point of view, the nuclear fuel cycle has to be further developed. Fast breeder reactor (FBR) technology seems to be a good candidate for nuclear hydrogen production. However, other new reactor concepts, such as high-temperature gas-cooled reactors (HTGR) and supercritical water-cooled reactors (SCWR) have some advantages for hydrogen production, and further analysis is therefore required. Session 2: High-temperature electrolysis Chairs: Yoshiyuki Inagaki (JAEA), J. Stephen Herring (INL) Seven papers were presented during Session 2. Dr. James O’Brien of the Idaho National Laboratory began with a summary of the status of research on high-temperature electrolysis at the INL. He included a discussion of the systems’ analysis results, comparing the efficiency of hydrogen production using air, steam or nothing as the sweep gas for the oxygen. He also compared the hydrogen production efficiency using low-temperature electrolysis, high-temperature electrolysis and the S-I process for a range of reactor outlet temperatures from 400-1 000°C. The HTE efficiencies were between 40-60% for temperatures above 600°C. Dr. O’Brien then reviewed the recent results from the INL Integrated Laboratory Scale (ILS) experiment. This experiment, using three modules of 240 cells each, initially produced 5.6 Nm 3 /hr at a power of 18 kW. Over the course of the 1 080-hour experiment the H 2 production dropped to about 0.8 Nm 3 /hr due to the increase in cell resistance. Dr. Julie Mougin of the CEA Grenoble Laboratory described research on a low-weight stack and on materials for better efficiency and durability. The central experiment in answering both questions is NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 9

EXECUTIVE SUMMARY<br />

Executive summary<br />

Session 1: Programme overviews<br />

Chairs: Yoshiyuki Nemoto (OECD/NEA), Carl Sink (US DOE)<br />

Programme overviews from USA, France, Japan, Korea, Russia and Canada were presented in<br />

Session 1.<br />

As less than 30% <strong>of</strong> the thermal energy from a nuclear power plant is used to generate electricity,<br />

nuclear production <strong>of</strong> hydrogen should be developed to utilise the remaining energy. This would<br />

especially be appropriate for some <strong>of</strong> the next generation high-temperature nuclear plants. It was<br />

suggested that an economic and efficient use <strong>of</strong> thermal energy from a nuclear power plant would be<br />

to utilise the surplus energy for hydrogen production during periods in which electricity consumption<br />

is relatively low.<br />

Outlines <strong>of</strong> research and development programmes for several nuclear hydrogen production<br />

technologies, such as high-temperature steam electrolysis (HTE), and sulphur-iodine (S-I) and hybrid<br />

sulphur (HyS) thermochemical processes were introduced. The panel discussion, which followed the<br />

presentations, discussed the criteria for choosing the best hydrogen production system and suggested<br />

that the selection would be judged mainly on economic criteria. Detailed information about the<br />

economic analysis and considerations was presented in Session 5.<br />

Potential future hydrogen applications were discussed. As a huge amount <strong>of</strong> CO 2 is emitted from<br />

the transport sector, it would greatly reduce CO 2 emissions and prevent global warming if, for example,<br />

hybrid automobiles could be fuelled by electricity from nuclear power plants, oil fuels made from<br />

biomass and hydrogen produced by nuclear power plants. Other issues discussed by the panel related<br />

to gasoline upgrading and iron production using hydrogen.<br />

It was generally acknowledged that a sustainable energy production is required in the future.<br />

From this point <strong>of</strong> view, the nuclear fuel cycle has to be further developed. Fast breeder reactor (FBR)<br />

technology seems to be a good candidate for nuclear hydrogen production. However, other new reactor<br />

concepts, such as high-temperature gas-cooled reactors (HTGR) and supercritical water-cooled reactors<br />

(SCWR) have some advantages for hydrogen production, and further analysis is therefore required.<br />

Session 2: High-temperature electrolysis<br />

Chairs: Yoshiyuki Inagaki (JAEA), J. Stephen Herring (INL)<br />

Seven papers were presented during Session 2. Dr. James O’Brien <strong>of</strong> the Idaho National Laboratory<br />

began with a summary <strong>of</strong> the status <strong>of</strong> research on high-temperature electrolysis at the INL. He included<br />

a discussion <strong>of</strong> the systems’ analysis results, comparing the efficiency <strong>of</strong> hydrogen production using<br />

air, steam or nothing as the sweep gas for the oxygen. He also compared the hydrogen production<br />

efficiency using low-temperature electrolysis, high-temperature electrolysis and the S-I process for a<br />

range <strong>of</strong> reactor outlet temperatures from 400-1 000°C. The HTE efficiencies were between 40-60% for<br />

temperatures above 600°C. Dr. O’Brien then reviewed the recent results from the INL Integrated<br />

Laboratory Scale (ILS) experiment. This experiment, using three modules <strong>of</strong> 240 cells each, initially<br />

produced 5.6 Nm 3 /hr at a power <strong>of</strong> 18 kW. Over the course <strong>of</strong> the 1 080-hour experiment the H 2<br />

production dropped to about 0.8 Nm 3 /hr due to the increase in cell resistance.<br />

Dr. Julie Mougin <strong>of</strong> the CEA Grenoble Laboratory described research on a low-weight stack and on<br />

materials for better efficiency and durability. The central experiment in answering both questions is<br />

NUCLEAR PRODUCTION OF HYDROGEN – © OECD/NEA 2010 9

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