30.04.2014 Views

Membrane Bioreactors Short Course Abstracts - National Water ...

Membrane Bioreactors Short Course Abstracts - National Water ...

Membrane Bioreactors Short Course Abstracts - National Water ...

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

Published by the<br />

<strong>National</strong> <strong>Water</strong> Research Institute<br />

NWRI-2006-02<br />

10500 Ellis Avenue • P.O. Box 20865<br />

Fountain Valley, California 92728-0865 USA<br />

(714) 378-3278 • Fax: (714) 378-3375<br />

www.NWRI-USA.org


Conference Planning Committee<br />

Chair:<br />

✦ SAMER S. ADHAM, Ph.D., MWH<br />

✦ SIMON J. JUDD, Ph.D., Cranfield University<br />

✦ GINA MELIN, <strong>National</strong> <strong>Water</strong> Research Institute<br />

✦ JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute<br />

✦ TAMMY RUSSO, <strong>National</strong> <strong>Water</strong> Research Institute<br />

Sponsors<br />

The Conference Planning Committee is indebted to the following organizations and<br />

corporations whose support has helped make this conference a success.<br />

✦ NATIONAL WATER RESEARCH INSTITUTE<br />

✦ MWH<br />

✦ CRANFIELD UNIVERSITY<br />

✦ USFILTER<br />

✦ ZENON ENVIRONMENTAL CORPORATION<br />

✦ ORANGE COUNTY WATER DISTRICT<br />

✦ CORONA DEPARTMENT OF WATER AND POWER<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

iii


Foreword<br />

ICROFILTRATION IV is the fourth in a series of conferences sponsored by the <strong>National</strong><br />

M<strong>Water</strong> Research Institute (NWRI) devoted to low-pressure membrane (microfiltration<br />

and ultrafiltration) applications to water and wastewater treatment.<br />

Since the first NWRI-sponsored Microfiltration Conference in 1994, the technology has<br />

advanced and become a popular alternative to conventional treatment. MICROFILTRATION IV<br />

provides an update on the status of the technology and a focus on critical issues faced by<br />

end-users, such as new applications, regulatory perspectives, operational experiences, and<br />

fouling control.<br />

A special feature of MICROFILTRATION IV is a one-day short course on membrane bioreactors<br />

(MBRs), a promising technology that uses microfiltration to enhance the wastewater and<br />

reclaimed water treatment processes. The short course provides information on the state-of-the-art<br />

in MBRs and focuses on topics such as MBR design, procurement issues, and costs.<br />

The extended abstracts presented in this document were the contributions of conference speakers.<br />

The opinions expressed within the abstracts are those of individual authors and do not<br />

necessarily reflect those of the sponsors.<br />

NWRI gratefully acknowledges the efforts of all those involved with the planning, organizing,<br />

and sponsoring the conference, including MWH, Cranfield University, USFilter, Zenon<br />

Environmental Corporation, the Corona Department of <strong>Water</strong> and Power, and Orange County<br />

<strong>Water</strong> District. NWRI also extends special thanks to the conference moderators and speakers,<br />

whose expertise provided invaluable insight into the status and needs of membrane technology.<br />

NWRI would also like to extend sincere thanks to Gina Melin, Editor, and Tim Hogan,<br />

Graphic Designer, for their efforts in bringing this document to press and ensuring that the<br />

quality of each and every abstract reached their fullest potential.<br />

Lastly, this conference would not have been possible without the vision of Ronald B. Linsky,<br />

Executive Director of NWRI until his passing in August 2005. Ron will be fondly<br />

remembered for his energy, enthusiasm, and dedication to NWRI and the water community.<br />

Jeffrey J. Mosher<br />

Acting Executive Director<br />

<strong>National</strong> <strong>Water</strong> Research Institute<br />

Fountain Valley, California<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

v


Program and Contents<br />

WEDNESDAY, MARCH 22, 2006<br />

7:00 am - 9:00 am Registration Foyer of California Ballroom<br />

Session 1: Introduction<br />

California Ballroom<br />

Moderated by JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />

8:30 am - 8:45 am Welcome<br />

JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />

8:45 am - 9:15 am <strong>Membrane</strong> <strong>Bioreactors</strong> and ............................. 1<br />

the Future of Wastewater Treatment<br />

R. RHODES TRUSSELL, Ph.D., P.E., DEE,<br />

Trussell Technologies, Inc., California<br />

9:15 am - 9:45 am Biological Process Principles ............................ 3<br />

GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />

University of California, Davis, California<br />

9:45 am - 10:00 am Break<br />

Session 2: Fundamentals and Applications<br />

Moderated by SAMER S. ADHAM, Ph.D., MWH, California<br />

10:00 am - 10:45 am <strong>Membrane</strong> Bioreactor Process Fundamentals .............. 5<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

10:45 am - 11:05 am Commercially Available <strong>Membrane</strong> Bioreactor Systems ...... 11<br />

JAMES F. DECAROLIS, MWH, California<br />

11:05 am - 11:25 am Evaluation of Conventional Activated Sludge .............. 19<br />

Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />

R. SHANE TRUSSELL, Ph.D., P.E.,<br />

Trussell Technologies, Inc., California<br />

11:25 am - 11:45 am <strong>Membrane</strong> Bioreactor Global Knowledgebase .............. 25<br />

GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE,<br />

CH2M HILL, Colorado<br />

11:45 am - 12:15 pm Panel Discussion<br />

12:15 pm - 1:30 pm Lunch The Atrium<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

vii


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Moderated by GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />

University of California, Davis, California<br />

1:30 pm - 2:00 pm Design, Procurement, and Costs of. ...................... 29<br />

<strong>Membrane</strong> Bioreactor Systems<br />

STEPHEN M. LACY, P.E., DEE, MWH, Nevada<br />

2:00 pm - 2:20 pm Retrofit of an Existing .................................. 33<br />

Conventional Wastewater Treatment Plant with<br />

Zenon <strong>Membrane</strong> Bioreactor Technology<br />

DAVE N. COMMONS,<br />

City of Redlands Municipal Utilities Department, California<br />

2:20 pm - 2:40 pm Retrofit of an Existing .................................. 37<br />

Conventional Wastewater Treatment Plant<br />

with USFilter <strong>Membrane</strong> Bioreactor Technology<br />

JOHN HATCHER, Oconee County Utility Department, Georgia<br />

2:40 pm - 3:20 pm <strong>Membrane</strong> Bioreactor Applications: A Global Perspective .... 39<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

3:20 pm - 3:45 pm Panel Discussion<br />

3:45 pm - 4:00 pm Break<br />

Session 4: Innovative Applications and Future Outlook of the Technology<br />

Moderated by R. RHODES TRUSSELL, Ph.D., P.E., DEE<br />

Trussell Technologies, Inc., California<br />

4:00 pm - 4:30 pm <strong>Membrane</strong> Aeration, Biofilms, ........................... 43<br />

and <strong>Membrane</strong> <strong>Bioreactors</strong><br />

MICHAEL J. SEMMENS, Ph.D., P.E.,<br />

University of Minnesota, Minnesota<br />

4:30 pm - 4:50 pm Future Outlook on <strong>Membrane</strong> Bioreactor Technology ....... 45<br />

SIMON J. JUDD, Ph.D., Cranfield University, England<br />

4:50 pm - 5:15 pm Panel Discussion<br />

5:15 pm <strong>Short</strong> <strong>Course</strong> on <strong>Membrane</strong> <strong>Bioreactors</strong> Adjourns<br />

viii


THURSDAY, MARCH 23, 2006 ~ FIELD TRIPS<br />

8:30 am - 11:30 am Field Trips<br />

Those who are attending field trips must turn in field trip passes prior to bus departure. Please check in<br />

at the Foyer of the California Ball Room at least 30 minutes prior to departure.<br />

Field Trip Option A:<br />

MICROFILTRATION AT THE ORANGE COUNTY WATER DISTRICT<br />

The Groundwater Replenishment System Phase One plant is a 5-million gallon per day (mgd)<br />

advanced water treatment facility that contains three major processes: microfiltration, reverse<br />

osmosis, and advanced oxidation. The microfiltration<br />

process consists of a 6-mgd USFilter<br />

CMF-S submersible system. This process is a<br />

smaller-scale version of the 86-mgd microfiltration<br />

facility currently under construction at<br />

the same site. Driving time from the hotel to<br />

the Orange County <strong>Water</strong> District in<br />

Fountain Valley, California, is approximately<br />

20 minutes.<br />

Field Trip Option B:<br />

MEMBRANE BIOREACTOR AT THE CORONA DEPARTMENT OF WATER AND POWER<br />

Wastewater Treatment Plant 3 at the Corona Department of <strong>Water</strong> and Power was<br />

commissioned in 2001 to treat 1.1-mgd raw wastewater to Title 22 standards for recycling<br />

purposes. Currently, about 0.4 mgd of recycled water is<br />

produced, which is used to irrigate a nearby golf course<br />

and will soon irrigate surrounding schools and parks.<br />

The foundation for Plant 3 is the ZenoGem Process, a<br />

technology designed by Zenon that consists of a<br />

suspended growth biological reactor integrated with a<br />

microfiltration membrane system. Driving time from<br />

the hotel to the Corona Department of <strong>Water</strong> and Power<br />

in Corona, California, is approximately 35 minutes.<br />

Photos courtesy of the Orange County <strong>Water</strong> District,<br />

and the Corona Department of <strong>Water</strong> and Power<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

ix


<strong>Abstracts</strong><br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

xi


xii


Session 1: Introduction<br />

<strong>Membrane</strong> <strong>Bioreactors</strong> and<br />

the Future of Wastewater Treatment<br />

R. RHODES TRUSSELL, PH.D., P.E., DEE<br />

Trussell Technologies, Inc.<br />

Pasadena, California<br />

Adecade ago, membrane bioreactors (MBRs) weren’t even on our radar screen. Today,<br />

MBRs are the process of choice for small-scale reuse projects with demands for high<br />

water quality. Projects are popping up everywhere. Soon, MBRs will change the way we think<br />

about treatment for reuse, opening a new era of decentralized treatment. In the very longterm,<br />

just as membrane filtration will replace granular media filtration, MBRs will replace<br />

conventional biological processes that depend on gravity sedimentation or granular media<br />

filtration for solids separation.<br />

What is the appeal of the MBR? What are some of the limits of the process? How is our<br />

thinking about MBRs changing, and how will it change in the future? What problems must<br />

we solve for MBRs to reach their full potential? What can MBRs do to help us meet future<br />

regulations?<br />

The most obvious appeal of the MBR is that it produces an excellent effluent quality. The<br />

compactness of the MBR is another important element in its appeal. Finally, the MBR has<br />

great potential for automation. Important to both the design engineer and operator, the MBR<br />

eliminates the need for good sludge settleability as a central requirement. Effluent quality is<br />

less sensitive to operations, and precise control of the sludge residence time (SRT)/mixed<br />

liquor suspended solids (MLSS)/food to microorganisms (F:M) ratio is not as important.<br />

Finally, the MBR puts much greater distance between reclamation and the risk of microbial<br />

disease. Pathogens are not just reduced by a highly selective chemical or photochemical<br />

reaction, they are rejected by size exclusion. The MBR also makes longer SRTs feasible in a<br />

compact space, resulting in less biomass to waste, the removal of a broader variety of resistant<br />

compounds, and a more biostable effluent with a lower oxidant demand. Finally, the MBR<br />

produces an effluent that is immediately suitable for reverse osmosis treatment, should that be<br />

a requirement.<br />

In today’s world, there are two kinds of issues that we face in making decision about the<br />

deployment of MBRs:<br />

Type I Issues — Issues that must be resolved to improve reliability, cost, and/or<br />

performance.<br />

Type II Issues — Issues that are inherent to the process and must be understood by<br />

designers and operators of successful MBR projects.<br />

Correspondence should be addressed to:<br />

R. Rhodes Trussell, Ph.D., P.E., DEE<br />

President<br />

Trussell Technologies, Inc.<br />

232 North Lake Avenue, Suite 300<br />

Pasadena, CA 91101-1862 USA<br />

Phone: (626) 486-0560 • Email: rhodes.trussell@trusselltech.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

1


Examples of Type I issues are: (a) understanding the upper limits of the MLSS that the<br />

process can handle and how the reactor configuration affects this, (b) understanding the lower<br />

limits of SRT and hydraulic residence time (HRT), (c) the optimization of air scouring and<br />

energy consumption, (d) membrane cleaning, (e) design and operational practices that will<br />

extend membrane life, and (f) designing and operating the MBR process to optimize sludge<br />

filterability.<br />

Examples of Type II issues are the design and operation requirements imposed by the impact<br />

that fouling can have on hydraulic performance, by MBR’s limited ability to handle peaking,<br />

and on MBRs by reduced oxygen transfer at high MLSS.<br />

To date, most MBR installations have been small enough that it has basically been possible to<br />

ignore the biology. This will not do in the future. The future belongs to those who take full<br />

advantage of all that we have learned about the behavior of this complex biological system and<br />

integrate it with the unique capabilities and limitations of MBRs. Some examples of problems<br />

that must be addressed include:<br />

• The management of organisms associated with foaming.<br />

• The management of the biological system to produce a sludge that is easily<br />

filtered and dewatered.<br />

• The full integration of what we know about nutrient removal with the MBR<br />

process.<br />

In the meantime, there are places where MBR is attractive today, even for the conservative<br />

engineer. MBR is most appealing when its small footprint, ease of automation, and excellent<br />

effluent quality are all requirements. It is also most appealing when flow peaking can be<br />

easily addressed. Reuse projects that scalp the flow from nearby sewers are one of the more<br />

obvious examples. Moreover, MBR has the potential to rearrange our thinking about reuse.<br />

There are limits to the idea of pumping treated wastewater up into and throughout a<br />

community in purple pipe. MBR creates the potential for decentralized reuse systems with<br />

treatment systems located closer to the point of application and smaller, less-intrusive purple<br />

infrastructure.<br />

R. RHODES TRUSSELL, Ph.D., P.E., DEE, is recognized worldwide as an authority<br />

in methods and criteria for water quality and in the development of advanced<br />

processes for treating water or wastewater to achieve the highest standards. A Civil<br />

and Corrosion Engineer with 35 years of experience, he has worked on the process<br />

design for dozens of treatment plants ranging in size from 1 to 900 million gallons per<br />

day in capacity. At present, he is President of Trussell Technologies, Inc., an<br />

environmental engineering firm that focuses on the quality and treatment of water<br />

and wastewater. He is also active on numerous boards and committees, such as<br />

serving as Chair of the <strong>Water</strong> Science and Technology Board for the <strong>National</strong> Academies. Just recently,<br />

he retired from the U.S. Environmental Protection Agency’s Science Advisory Board after 17 years of<br />

service. Trussell received a B.S. in Civil Engineering and both an M.S. and Ph.D. in Sanitary<br />

Engineering from the University of California, Berkeley.<br />

2


Session 1: Introduction<br />

Biological Process Principles<br />

GEORGE TCHOBANOGLOUS, PH.D., P.E.<br />

University of California, Davis<br />

Davis, California<br />

With proper analysis and environmental control, almost all wastewaters containing<br />

biodegradable constituents can be treated biologically. Therefore, it is essential that the<br />

environmental engineer understand the characteristics of each biological process to ensure<br />

that the proper environment is produced and controlled effectively. The overall objectives of<br />

the biological treatment of domestic wastewater are to:<br />

• Transform (i.e., oxidize) dissolved and particulate biodegradable constituents into<br />

acceptable end-products.<br />

• Capture and incorporate suspended and nonsettleable colloidal solids into a biological<br />

floc or biofilm.<br />

• Transform or remove nutrients, such as nitrogen and phosphorus.<br />

• More recently, to remove specific trace constituents and compounds.<br />

For industrial wastewater, the objective is to remove or reduce the concentration of organic<br />

and inorganic compounds. Because some of the constituents and compounds found in<br />

industrial wastewater are toxic to microorganisms, pretreatment may be required before<br />

industrial wastewater can be discharged to a municipal collection system. For agricultural<br />

irrigation runoff, the objective is to remove nutrients (specifically nitrogen and phosphorus),<br />

pesticides, and trace constituents that are capable of affecting the aquatic environment.<br />

The principal biological processes used for wastewater treatment can be divided into three<br />

main categories: suspended growth, attached growth (or biofilm), and combined suspended and<br />

attached growth processes. The successful design and operation of the biological processes<br />

requires an understanding of the:<br />

• Types of microorganisms involved.<br />

• Specific reactions that they perform.<br />

• Environmental factors that affect their performance.<br />

• Nutritional needs of microorganisms.<br />

• Microorganism reaction kinetics.<br />

These subjects are reviewed in light of process developments that have occurred over the past<br />

century.<br />

Correspondence should be addressed to:<br />

George Tchobanoglous, Ph.D., P.E.<br />

Professor Emeritus of Civil and Environmental Engineering<br />

University of California, Davis<br />

662 Diego Place<br />

Davis, CA 95616 USA<br />

Phone: (530) 756-5747 • Email: gtchobanoglous@ucdavis.edu<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

3


4<br />

For over 35 years, wastewater expert GEORGE TCHOBANOGLOUS, PH.D., P.E.,<br />

has taught courses on water and wastewater treatment and solid waste management<br />

at the University of California, Davis, where he is Professor Emeritus in the Department<br />

of Civil and Environmental Engineering. He has authored or coauthored over<br />

350 publications, including 13 textbooks and five engineering reference books.<br />

Tchobanoglous has been past President of the Association of Environmental<br />

Engineering and Science Professors and currently serves as a national and international<br />

consultant to both government agencies and private concerns. Among his<br />

honors, he received the Athalie Richardson Irvine Clarke Prize from the <strong>National</strong> <strong>Water</strong> Research<br />

Institute in 2003 and was inducted to the <strong>National</strong> Academy of Engineers in 2004. In 2005, he<br />

received an Honorary Doctor of Engineering degree from the Colorado School of Mines.<br />

Tchobanoglous received a B.S. in Civil Engineering from the University of the Pacific, an M.S. in<br />

Sanitary Engineering from the University of California, Berkeley, and a Ph.D. in Environmental<br />

Engineering from Stanford University.


Session 2: Fundamentals and Applications<br />

<strong>Membrane</strong> Bioreactor Process Fundamentals<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Introduction<br />

The use of microfiltration (MF) or ultrafiltration (UF) membranes in biological wastewater<br />

treatment has been well documented and extensively reviewed. <strong>Membrane</strong> filtration<br />

produces a high-quality, clarified, and disinfected permeate product. It also permits absolute<br />

control of solids retention time (SRT) and, thus, correspondingly, control of the mixed liquor<br />

suspended solids (MLSS) concentration. This both reduces the required reactor size and<br />

promotes the development of specific nitrifying bacteria, thereby enhancing ammonia removal,<br />

as well as producing less sludge.<br />

However, as with almost all other membrane processes, the production rate of membrane<br />

bioreactors (MBRs) is ultimately limited by membrane fouling. Fouling arises from the<br />

accumulation of solute, colloidal, and particulate species on or within the membrane, leading<br />

to a deterioration in membrane permeability. This phenomenon has led to the development<br />

of the low-fouling submerged configuration, first introduced 15 years ago, as opposed to<br />

sidestream systems, wherein the membrane is immersed in the bioreactor rather than fitted<br />

external to it (Figure 1). Submerged systems tend to allow greater hydraulic efficiencies,<br />

reflected in greater permeabilities, due to their operation at substantially lower fluxes than<br />

sidestream systems (Table 1), since fouling tends to increase with increasing flux.<br />

Out<br />

(membrane fouling)<br />

Feed<br />

(Screens)<br />

Bioreactor<br />

(Activity + Nature)<br />

Air<br />

(Energy)<br />

Sludge Waste<br />

(Quantity and Quality)<br />

Figure 1.<br />

Elements of a membrane bioreactor.<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

5


Table 1. Summary of <strong>Membrane</strong> Bioreactor Process Conditions for Sewage Treatment<br />

Mitsubushi<br />

Orelis or<br />

Parameter Kubota Rayon Zenon Wehrle<br />

<strong>Membrane</strong> Geometry FS HF HF MT<br />

Process Configuration Submerged Submerged Submerged Side-stream<br />

Mean Air Velocity (m/s) 0.05 0.03 0.1 –<br />

Mean Liquid Velocity (m/s) 0.5* – – 1-3<br />

TMP (bar) 0.05-0.15 0.1-0.5 0.1-0.5 2-5<br />

Flux (LMH) ~25 ~15 ~25 70-100<br />

FS = Flat sheet. HF = Hollow fiber. MT = Multitube. LMH = Liters per cubic meter per hour.<br />

TMP= Transmembrane pressure. m/s = Meters per second. *As quoted by supplier.<br />

Fouling<br />

Fouling is a particularly acute problem in the case of MBRs, since the membrane is challenged<br />

with highly contaminated liquors having total solids concentrations of 20 grams per liter (g/L) or<br />

more arising from concentrated biomass. A second limitation, clogging – which refers to the<br />

filling of the membrane interstices with solids – is generally of less significance, but must still<br />

be suppressed for successful operation. There are a number of elements of a submerged MBR<br />

system (see Figure 1), all contributing to varying degrees of fouling and clogging, and their<br />

interrelationship is complex (Figure 2).<br />

In considering fouling and its causes and implications, the various elements of the system<br />

(see Figure 1) can be discussed in turn. Firstly, there are the feed characteristics. Various<br />

biochemical transformations in the bioreactor convert the organic matter in the feed into largely<br />

EPS<br />

• Free<br />

• Bound<br />

Feed Characteristics<br />

Biomass Characteristics<br />

Floc Characteristics<br />

• Size<br />

• Structure<br />

Bulk Characteristics<br />

• Viscosity/Rheology<br />

• Hydrophobicity<br />

Operation<br />

Retention Time<br />

• Hydraulic<br />

• Solids<br />

Hydraulics<br />

• Flux<br />

• TMP<br />

Reversible<br />

Fouling<br />

Irreversible<br />

Clogging<br />

<strong>Membrane</strong><br />

Channels<br />

Aerator<br />

Ports<br />

Cleaning<br />

• Physical<br />

• Chemical<br />

<strong>Membrane</strong> Module Characteristics<br />

Pore<br />

• Size<br />

• Shape<br />

Surface Characteristics<br />

• Porosity<br />

• Charge/Hydrophobicity<br />

Configuration<br />

• Geometry<br />

• Dimensions<br />

Aeration<br />

• Design (Port Size)<br />

• Mean Flow Rate<br />

• Pulse Rate<br />

Figure 2. Inter-relationships between membrane bioreactor parameters and fouling.<br />

6


mineralized products, principally carbon dioxide and nitrate. In doing so, a variety of materials<br />

are released from the biomass in the reactor, which are collectively referred to as extracellular<br />

polymeric substances (EPS) and which contain a number of components that can foul the<br />

membrane to various extents. The relative and overall concentrations of the various components<br />

are determined both by feed characteristics and operational facets of the system and, in<br />

particular, by microbial speciation. Other foulants originate directly from unbiodegraded<br />

components of the feedwater, particularly for feeds of low biodegrability.<br />

Secondly, there is the actual process design and configuration of the MBR process, which in<br />

turn affects the key operator parameter values chosen. Submerged MBRs operate at lower<br />

fluxes and, as a result, lower transmembrane pressure (TMP) values (and so permeabilities)<br />

than the sidestream configuration. Therefore, they are inherently higher in energy efficiency,<br />

manifested as the specific energy demand in kilowatt-hour per cubic meter (kWh/m 3 )<br />

permeate product. The configuration of the membrane module — principally, the membrane<br />

element geometry (planar or cylindrical), material physical properties (pore size, tortuosity,<br />

hydrophobicity, and surface porosity), and chemistry (polymeric or ceramic) — can also<br />

influence fouling. Although there are now a number of proprietary MBR technologies in the<br />

marketplace, the majority of them are based either on a flat sheet (FS) membrane<br />

configuration or on hollow fibers (HF).<br />

Thirdly, the operation of the MBR can profoundly impact fouling. There are two components<br />

of MBR operation: the membrane and the bioreactor. The bioreactor component (as with a<br />

conventional activated sludge process) is controlled by the relative values of the retention of<br />

solids and liquid (i.e., the solids [SRT] and hydraulic [HRT] retention times). Increasing the<br />

SRT and decreasing the HRT leads to higher levels of suspended solids (usually referred to as<br />

mixed liquor suspended solids [MLSS]) in the bioreactor, which increases the risk of clogging<br />

in both the membrane interstices and aerator ports. However, the impact of retention times<br />

on fouling is normally not significant in sewage treatment provided the MLSS is kept within a<br />

range of values in which fouling and foaming are suppressed (which tends to prevail at low<br />

MLSS values of around 4 to 6 g/L) and clogging is avoided by operating below a threshold<br />

MLSS value (which depends largely upon the membrane configuration). The main<br />

determinants for fouling control, however, relate directly to the membrane itself.<br />

Fouling Control<br />

In submerged MBRs, generally only three strategies are available for limiting fouling with<br />

regards to operation: reducing the flux, increasing aeration, or employing physical or chemical<br />

cleaning. Coarse bubble aeration produces scouring action at the surface of the membrane,<br />

which limits the build-up of foulant material. Lowering the flux reduces the rate at which<br />

foulants arrive at the membrane. However, both these modifications have cost implications,<br />

since a reduced flux implies a greater membrane area requirement and energy demand<br />

increases roughly linearly with increasing air flow rate. Cleaning demands downtime, and<br />

more rigorous cleaning using chemicals exerts chemical demand and produces chemical waste.<br />

A good operation of submerged MBR systems is based on obtaining the appropriate balance<br />

between operational flux, aeration, and cleaning. It follows that good MBR design is associated<br />

with maximizing the impact of aeration (in terms of reducing fouling) and facilitating<br />

cleaning with minimal downtime and chemicals consumption, as well as providing a high<br />

membrane area at low cost so as to permit a low flux.<br />

The constraints imposed by the challenging environment in which the membranes operate<br />

have meant that the municipal wastewater treatment MBR market is dominated by just two<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

7


designs: the HF membrane-based product (Zenon) and the FS (Kubota). Much debate exists<br />

as to the relative merits offered by these two designs. The flat plate configuration tends to run<br />

at slightly higher permeabilities (flux per unit TMP) and is simpler in operation. On the other<br />

hand, unlike the HF, it cannot be backflushed. Both systems appear to maintain reasonable<br />

fluxes by applying relaxation – intermittent physical cleaning attained simply by closing the<br />

permeate valve and allowing air to scour the membrane surface. Both Kubota and Zenon have<br />

also recently developed design modifications for increasing efficiency. In the case of Kubota,<br />

this is achieved by stacking the membrane modules (already employed by Mitsubishi Rayon in<br />

its MBRs based on its Sterapore HF membrane). Zenon has introduced intermittent aeration,<br />

which effectively halves the specific energy demand associated with aeration, the main<br />

operating cost component.<br />

Technologies<br />

There are an increasing number of commercial MBR technologies, many of which are listed in<br />

Tables 2 and 3. It appears that almost all immersed MBRs are either rectangular FS or HF,<br />

and that most sidestream MBR technologies are multi-tubes (MT). The exceptions to these<br />

general observations appear to be:<br />

a. The Orelis Pleaide FS membrane used for sidestream treatment.<br />

b. The Polymem and Ultraflo sidestream HF systems.<br />

c. The hexagonal/octagonal rotating immersed Huber FS membrane.<br />

d) The Millenniumpore MT membrane, which has been used as an immersed module,<br />

as well as for air-lift sidestream.<br />

Table 2. Commercial Technologies<br />

Process Configuration<br />

Immersed<br />

Sidestream<br />

FS Colloide Novasep-Orelis<br />

Brightwater<br />

Huber*<br />

ITRI NWF<br />

Kubota<br />

Microdyn Nadir<br />

Toray<br />

<strong>Membrane</strong><br />

Configuration<br />

HF Asahi-kasie Polymem<br />

Han-S Environmental<br />

Ultraflo<br />

ITT<br />

Koch/Puron<br />

Kolon<br />

Mitsubishi Rayon<br />

Motimo<br />

Siemens/USF-Memcor<br />

Zenon<br />

MT Millenniumpore Berghof**<br />

Millenniumpore<br />

Norit-Xflow**<br />

*Rotating membrane.<br />

**MT membrane products used by process suppliers such as Aquabio, Dynatec, Triqua, and Wehrle.<br />

8


Table 3. Commercial <strong>Membrane</strong> Product Specifications<br />

<strong>Membrane</strong> Pore Specific Propietary Name,<br />

Supplier (Configuration, Size Surface <strong>Membrane</strong>,<br />

Material) (µm) Area (m -1 ) or Module<br />

Berghof MT, PES 0.08 110 HyPerm-AE<br />

or PVDF 0.12 Hyperflux<br />

Brightwater FS, PES 0.08 110 Membright<br />

Toray FS, PVDF 0.08 130 Toray<br />

Kubota FS, PE 0.4 150 Kubota<br />

Colloide FS, PES 0.04 160 Sub Snake<br />

Huber FS, PES 0.038 160 VRM<br />

Millenniumpore MT, PES 0.1 180 Millenniumpore<br />

Koch HF, PES 0.05 260 Puron<br />

Zenon HF, PVDF 0.04 300 ZW500C-D<br />

Norit-Stork MT, PVDF 0.038 320 F4385<br />

290 F5385<br />

Mitsubishi Rayon HF, PE 0.4 425 SUR<br />

HF, PVDF 0.4 333 SADF<br />

USF-Memcor HF, PVDF 0.04 600-700 B10R, B30R<br />

Asahi-kasie HF, PVDF 0.1 710 Microza<br />

Polymem HF, PS 0.08 800 WW120<br />

Motimo HF, PVDF 0.1-0.2 1100 Flat Plat<br />

Moreover, almost all HF MBR membrane products currently on the market are verticallymounted<br />

and polyvinylidene difluoride (PVDF)-based, the exceptions being the Koch-Puron<br />

membrane (which is polyethersulphone [PES]), the Polymem polysulfone (PS) membrane,<br />

and the Mitsubishi Rayon SUR module (which is polyethylene [PE] material and also<br />

horizontally oriented). All HF products are in the coarse UF/tight MF region of selectivity,<br />

having pore sizes predominantly between 0.03 and 0.4 micrometers (µm), and all such<br />

vertically-mounted systems are between 0.7 and 2.5 millimeters (mm) in external diameter.<br />

Distinctions in HF MBR systems can be found mainly in the use of membrane reinforcement<br />

(essential for those HF elements designed to provide significant lateral movement) and,<br />

perhaps most crucially, the air-to-membrane contact.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

9


10<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.


Session 2: Fundamentals and Applications<br />

Commercially Available<br />

<strong>Membrane</strong> Bioreactor Systems<br />

JAMES F. DECAROLIS<br />

MWH<br />

San Diego, California<br />

ZAKIR HIRANI<br />

MWH<br />

San Diego, California<br />

SAMER S. ADHAM, PH.D.<br />

MWH<br />

Pasadena, California<br />

NEIL TRAN, P.E.<br />

City of San Diego<br />

San Diego, California<br />

STEVE LAGOS<br />

City of San Diego<br />

San Diego, California<br />

Introduction<br />

The following paper provides a detailed description of four commercially available<br />

membrane bioreactor (MBR) systems currently established in the municipal wastewater<br />

treatment/water reclamation market in the United States. These systems are supplied by<br />

Zenon Environmental, Inc., USFilter, Ionics/Mitsubishi Rayon Corporation, and Enviroquip, Inc./<br />

Kubota Corporation. Each of these suppliers has full-scale MBRs currently operating in the<br />

United States, and their systems are approved by the California Department of Health<br />

Services (CDHS) to meet Title 22 water recycling criteria. Details of each system are based<br />

on knowledge gained during hands-on pilot testing performed by the project team along with<br />

information provided by the manufacturers. The paper will also describe four newly developed<br />

MBR systems currently entering the United States market. These suppliers include Koch<br />

<strong>Membrane</strong> Systems (KMS), Kruger, Parkson Corporation, and Huber, Inc. The project team<br />

is currently evaluating the ability of these new technologies to meet Title 22 recycling criteria<br />

under grant funding provided by the United States Department of Interior, Bureau of<br />

Correspondence should be addressed to:<br />

James F. DeCarolis<br />

MWH Americas, Inc.<br />

Aqua 2030 Research Center<br />

North City <strong>Water</strong> Reclamation Plant<br />

4949 Eastgate Mall<br />

San Diego, CA 92121 USA<br />

Phone: (858) 824-6067 • Email: jdecarolis@sandiego.gov<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

11


Reclamation. Lastly, the paper discusses MBR pilot-testing considerations based on nearly a<br />

decade of MBR research performed by the project team at the Aqua 2030 Research Center<br />

located in San Diego, California.<br />

Commercially Available <strong>Membrane</strong> Bioreactor Systems<br />

(Established in the United States)<br />

Zenon <strong>Membrane</strong> Bioreactor System<br />

The Zenon MBR system uses polyvinylidene fluoride (PVDF) ultrafiltration (UF) reinforced<br />

hollow fiber membranes (nominal pore size = 0.04 micron [µm]). Individual membrane<br />

elements are configured into membrane cassettes that are typically submerged directly into a<br />

designated membrane tank in direct contact with mixed liquor suspended solids (MLSS). The<br />

commercial designation of the membrane module currently used in the Zenon MBR system is<br />

ZW 500d, which has superseded previous generation modules offered by Zenon, including the<br />

ZW 500a and ZW 500c. Benefits of the<br />

ZW 500d configuration over its predecessors<br />

include a higher membrane packing density<br />

and lower air scouring requirements (Benedek<br />

and Cote, 2003). A photograph of a ZW 500d<br />

cassette is provided in Figure 1. Each cassette<br />

used in full-scale applications is typically<br />

designed to contain up to 48 individual<br />

membrane elements. Coarse bubble air is<br />

introduced from the bottom of the cassette to<br />

scour the surface of the membranes. This<br />

prevents solids from accumulating on the<br />

membrane surface, which could result in<br />

increased transmembrane pressure (TMP). A<br />

unique feature of the Zenon MBR system is<br />

the intermittent application of membrane air<br />

scour, which reduces energy consumption<br />

Figure 1. Photograph of Zenon 500d membrane<br />

cassette (Zenon, 2005).<br />

USFilter <strong>Membrane</strong> Bioreactor System<br />

The USFilter MBR system utilizes microfiltration (MF) hollow fiber PVDF membranes<br />

(nominal pore size of 0.08 µm) that are submerged in a separate membrane tank. The<br />

commercial designation of the original membranes used in USFilter’s MBR systems is B10R.<br />

Though still used in MBR package plants (


A unique feature of the USFilter MBR system is that it incorporates MemJet technology,<br />

which includes the injection of both air and mixed liquor at the bottom of the membrane<br />

modules. This operation causes the membranes to be scoured and fluidized and prevents<br />

particulate matter from accumulating on the membrane surface.<br />

Ionics/Mitsubishi Rayon <strong>Membrane</strong> Bioreactor System<br />

The Ionics/Mitsubishi Rayon MBR system uses<br />

polyethylene MF hollow fiber membranes (nominal<br />

pore size of 0.4 µm) that are submerged directly<br />

in an aeration basin. The commercial designation<br />

for the membranes is Sterapore HF. Though<br />

classified as MF, the membranes are characterized<br />

with a tight pore size distribution (absolute pore<br />

size= 0.5 µm). As shown in Figure 3, each<br />

membrane cassette contains individual hollow<br />

fibers membranes configured horizontally to make<br />

up an element. Each membrane cassette contains<br />

50 of the 1-square meter (m 2 ) Mitsubishi<br />

Sterapore HF MF membranes, for a total<br />

membrane area of 100 m 2 (1,076 ft 2 ). Air is<br />

supplied at the bottom of the tank for scour and Figure 3. Mitsubishi Sterapore HF membrane<br />

cassette.<br />

biological process. During filtration, vacuum<br />

pressure is applied, causing water to permeate through the membrane from the top and bottom.<br />

Kubota <strong>Membrane</strong> Bioreactor System<br />

The Kubota MBR system contains flat sheet, chlorinated polyethylene MF membranes (nominal<br />

pore = 0.4 µm) that are submerged directly in an aeration basin. The commercial designation<br />

of the flat sheet membrane cartridge is Type 510. Each cartridge is 1 m (H) x 0.49 m (W) x<br />

6 millimeters (mm) thick, and contains a membrane surface area of 0.8 m 2 . A photograph of<br />

the Type 510 membrane cartridge is provided in<br />

Figure 4. Each cartridge contains a support<br />

plate, spacer, permeate nozzle, and membrane<br />

layer on each side. Recently (2005), Kubota<br />

introduced a Type 515 membrane cartridge<br />

primarily for applications of 2 mgd or greater.<br />

The Type 515 cartridges are larger in dimension<br />

than Type 510 cartridges, resulting in increased<br />

membrane area per cassette. The Type 510<br />

cassette contains up to 150 individual cartridges<br />

(spaced 7 mm apart) and is equipped with a<br />

permeate manifold. During filtration, permeate<br />

water flows out of the cartridges through the<br />

permeate nozzle and into collection tubes that<br />

Figure 4. Kubota Type 510 membrane cassette.<br />

feed into the permeate manifold. A unique<br />

feature of the Kubota MBR system is that can be designed as a single or double deck (DD)<br />

configuration. The DD systems contain both upper and lower membrane cassettes. The<br />

lower cassettes are equipped with a coarse air bubble diffuser and provide structural support<br />

to the upper casts. This DD configuration offers several benefits (van der Roest et al, 2002),<br />

including the reduction of 1) the membrane footprint, 2) the biological volume consumed by<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

13


the membrane system, and 3) air consumption used for membrane cleaning. The DD also<br />

yields a more controllable biological process and reduces the possibility of short circuiting.<br />

Newly Developed <strong>Membrane</strong> Bioreactor Systems<br />

Koch <strong>Membrane</strong> Systems <strong>Membrane</strong> Bioreactor System<br />

The KMS membrane bioreactor uses PURON ® hollow fiber UF membranes (nominal pore<br />

size = 0.05 µm) that are made of polyethersulfone (PES) and casted onto a braided support.<br />

The hollow fiber membranes are configured in bundles to form membrane modules and are<br />

submerged in a designated membrane tank. A unique feature of the KMS MBR is that each<br />

membrane is sealed at the top and potted only at the lower end. This design allows the nonpotted<br />

ends to move freely in the MLSS, which eliminates the possibility of clogging. An air<br />

nozzle is located in the center of each bundle to provide membrane air scour. A standard<br />

module contains nine membrane bundles for a total membrane area of 30 m 2 . The PURON<br />

hollow fiber module is shown in Figure 5.<br />

Figure 5. PURON membrane module (Koch <strong>Membrane</strong> Systems, 2005).<br />

Huber <strong>Membrane</strong> Bioreactor System<br />

The Huber MBR system uses flat sheet UF membranes (nominal pore size= 0.038 µm)<br />

submerged in a designated membrane tank. A unique feature of the Huber MBR system is<br />

that the membranes are supported on a Vacuum Rotation <strong>Membrane</strong> (VRM ® ) unit, which<br />

consists of individual rotating VRM plate membranes installed around a stationary hollow<br />

shaft. Two centrally arranged air tubes<br />

introduce scouring air into the interspaces<br />

between the plates. Permeate<br />

is drawn from the each plate via<br />

permeate tubes that collect permeate<br />

to a common pipe. These horizontal<br />

pipes meet at a center manifold, from<br />

which the permeate exits the system.<br />

The constant rotation (1.8 revolutions<br />

per minute [RPM]) of the VRM unit<br />

allows the membrane plates to be air<br />

scoured alternatively by just two<br />

centrally placed air tubes, thereby Figure 6. Huber VRM unit (plan view).<br />

14


educing the scouring air requirements. Energy efficiency is maintained by using only a<br />

2−horsepower motor for the rotation of the VRM.<br />

The VRM membranes are configured in plates (3-m 2 filter surface area per plate) that contain<br />

permeate channels, spacers, and permeate discharge nozzles. A VRM module is comprised of<br />

four such plates; modules (when arranged circularly) form a membrane element. Huber MBR<br />

membrane elements are offered in two sizes: VRM 20 (containing six modules) and VRM 30<br />

(containing eight modules). Standard VRM 20 systems are designed with a minimum of 10<br />

and maximum of 50 elements, while standard VRM 30 systems are designed with a minimum<br />

of 20 and maximum of 60 elements. A photograph of a VRM 20 unit mounted on the VRM<br />

drive is provided in Figure 6.<br />

Kruger <strong>Membrane</strong> Bioreactor System<br />

Kruger MBR system uses flat-sheet PVDF UF<br />

membranes (nominal pore size of 0.08 µm)<br />

submerged in a designated membrane tank.<br />

<strong>Membrane</strong>s are supported on a polyolefin nonwoven<br />

material and Acrylonitrile Butadiene<br />

Styrene (ABS) plate. Each module contains<br />

100 flat-sheet membrane elements, with a total<br />

membrane area of 1,500 ft 2 . A photograph of the<br />

flat sheet module is provided in Figure 7. A<br />

unique feature of the Kruger MBR system is that<br />

the membrane is characterized with a tight pore<br />

size distribution (0.03 µm), allowing the fluid to<br />

Figure 7. Flat sheet module (Kruger, 2005).<br />

be equally distributed along the membrane surface<br />

during filtration (Kruger, 2005). It also allows the cleaning chemicals to be evenly distributed<br />

during maintenance cleaning, making cleaning more effective.<br />

Parkson Dynalift <strong>Membrane</strong> Bioreactor System<br />

The Parkson Dynalift MBR contains X-Flow ® PVDF tubular<br />

UF membranes with a nominal pore size of 0.03 µm. A unique<br />

feature of the Parkson MBR system is that the membranes are<br />

configured in modules and are external to the biological process.<br />

These tubular membranes provide a wide-channel, non-clogging<br />

design and, according to the manufacturer, can be operated at<br />

high MLSS levels of up to 15,000 milligrams per liter (mg/L).<br />

To eliminate high pumping energies, membranes are placed in a<br />

vertical orientation and MLSS is kept suspended inside the<br />

module using air-lift assisted cross-flow pumping. A photograph<br />

of the X-Flow membranes is provided in Figure 8.<br />

Aqua 2030 <strong>Membrane</strong> Bioreactor Research Program<br />

Figure 8. Parkson Corporation’s<br />

X-Flow membrane<br />

(Parkson, 2005)<br />

For nearly a decade, MWH and the City of San Diego in California have been researching<br />

MBR technology and its application for water reuse at the Aqua 2030 Research Center.<br />

The majority of this research was made possible under funding provided by the United States<br />

Department of Interior, Bureau of Reclamation, and was conducted in multiple phases from<br />

1997 to the present. Phase I (Adham and Gagliardo, 1998) included an extensive literature<br />

search on MBR technology and identified major MBR suppliers in the field. In addition, the<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

15


project team implemented a worldwide survey of full-scale MBR applications for domestic<br />

wastewater treatment and developed rough cost estimates for the technology. Information<br />

gathered during the survey included operational characteristics such as capacity, MLSS<br />

concentrations, food-to-microorganism ratio, permeate flux, solids retention time (SRT), and<br />

hydraulic retention time (HRT), along with performance in terms of particulate, organic,<br />

nutrient, and microbial contaminant removal.<br />

Phase II testing (Adham et al., 2000) included the operation and evaluation of two pilot-scale<br />

MBRs (Zenon and Mitsubishi) over a 1-year period. The purpose of testing was to evaluate<br />

the performance of these systems during the treatment of municipal wastewater and to<br />

establish baseline operating conditions. Towards the end of the pilot-testing period, the<br />

project team worked with CDHS to establish criteria for MBR systems to gain Title 22<br />

approval. Based on these criteria, further testing of the Zenon and Mitsubishi systems was<br />

done in 2001 under funding provided by the <strong>National</strong> <strong>Water</strong> Research Institute (Adham et al.,<br />

2001a and 2001b). Results from this testing, along with those acquired during the<br />

1-year operating period, were submitted to CDHS in September 2001. <strong>Short</strong>ly after, the two<br />

systems were granted conditional approval to meet Title 22 water recycling criteria.<br />

In June 2002, the project team embarked on Phase III (Adham and DeCarolis, 2004), which<br />

included the evaluation of four MBR pilot units (USFilter Corporation/Jet Tech Products Group;<br />

Zenon Environmental, Inc.; Ionics/Mitsubishi Rayon Corporation; and Enviroquip Inc./<br />

Kubota Corporation). Pilot testing of these systems was conducted over a 16-month period on<br />

raw and advanced primary effluent to evaluate MBR performance and to determine the<br />

suitability of MBR effluent as a feed to reverse osmosis units. Data generated during this<br />

study demonstrated the ability of the Kubota and USFilter MBR systems to meet Title 22<br />

<strong>Water</strong> Recycling Criteria, and both were granted approval in 2002/2003 (California<br />

Department of Health Services, 2005). In addition, it was shown that MBR systems could<br />

successfully operate on advanced primary treated wastewater containing coagulant and<br />

polymer residual.<br />

Recently, the project team has begun Phase IV (U.S. Department of Interior, Bureau of<br />

Reclamation, 2005) of the MBR program. The purpose of this ongoing project is to evaluate<br />

four newly developed MBR systems entering the municipal wastewater market in the United<br />

States. These include systems from Koch <strong>Membrane</strong> Systems (Wilmington, Massachusetts),<br />

Parkson Corporation (Fort Lauderdale, Florida), Huber Technology, Inc. (Huntersville, North<br />

Carolina), and Kruger (Cary, North Carolina). Each of these systems has been designed with<br />

innovative features aimed to optimize operational performance and efficiency. As part of<br />

testing, each system will be evaluated to meet Title 22 requirements, which (upon approval)<br />

would double the number of approved systems available to the water reclamation industry.<br />

Based on the research program described above, the project team has identified several<br />

important factors to consider when pilot testing MBR systems for water reuse applications.<br />

These include:<br />

• <strong>Water</strong> Quality Goals (total nitrogen, phosphorus, establish a water quality sampling plan).<br />

• Selecting a Supplier(s) (system configuration, customer support, suppliers experience,<br />

capacity of full-scale potential plant, pilot rental fee).<br />

• Pilot Site (access to raw wastewater [20- to 40 gallons per minute]), access to sewer to<br />

dispose of waste, potable water supply for cleaning, adequate power supply available).<br />

16


• MBR Operating Conditions (flux, HRT, SRT, membrane cleaning frequency [maintenance<br />

and recovery cleans], backwash/relax frequency, recirculation rate for denitrification).<br />

• Special Considerations (pretreatment, operator requirements, duration of testing, post<br />

treatment requirements, operation and maintenance requirements, biological tank mixing<br />

requirements, redundancy and location of feed pumps, wasting, foaming control).<br />

Additional information regarding these considerations will be provided during the conference<br />

presentation.<br />

References<br />

Adham, S., and P. Gagliardo (1998). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Repurification – Phase I. Desalination<br />

Research and Development Program Report No. 34, Project No. 1425-97-FC-81-30006J, United States<br />

Department of Interior, Bureau of Reclamation.<br />

Adham, S., R. Mirlo R. and P. Gagliardo (2000). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Reclamation – Phase II.<br />

Desalination Research and Development Program Report No. 60; Project No. 98-FC-81-0031, United<br />

States Department of Interior, Bureau of Reclamation.<br />

Adham, S., D. Askenaizer, R. Trussell, and P. Gagliardo (2001a). Assessing the Ability of the Zenon Zenogem<br />

<strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong> Research<br />

Institute.<br />

Adham, S., D. Askenaizer, R. Trussell, P. and Gagliardo (2001b). Assessing the Ability of the Zenon Mitsubishi<br />

Sterapore <strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong><br />

Research Institute.<br />

Adham, S., and J. DeCarolis (2004). Optimization of Various MBR Systems for <strong>Water</strong> Reclamation – Phase III.<br />

Final Report Project No. 01-FC-81-0736, Bureau of Reclamation.<br />

Benedek, A., and P. Cote (2003). “Long-Term Experience with Hollow Fiber <strong>Membrane</strong> <strong>Bioreactors</strong>.”<br />

Proceedings, International Desalination Association Conference.<br />

California Department of Health Services (2005). Treatment Technology Report for Recycled <strong>Water</strong>. Department<br />

of Health Services, State of California Division of Drinking <strong>Water</strong> and Environmental Management.<br />

Koch <strong>Membrane</strong> Systems (2005). Technical literature on the KMS <strong>Membrane</strong> Bioreactor.<br />

Kruger (2005). Technical literature on the BIOSEP FS MBR Process.<br />

Parkson Corporation (2005). Website: http://www.parkson.com/Content.aspx?ntopicid=196.<br />

U.S. Department of Interior, Bureau of Reclamation (2005). Project agreement number 05 FC 81157,<br />

October.<br />

USFilter-Memcor (2005). Technical information and correspondence provided by Wenjun Liu, Director of<br />

Bioprocess Technology.<br />

van der Roest, H.F., D.P. Lawrence, and A.G.N. van Bentem, (2002) <strong>Membrane</strong> <strong>Bioreactors</strong> for Municipal<br />

Wastewater Treatment. IWA Publishing. STOWA.<br />

Zenon (2005). Website: http://www.zenon.com/mbr/design_considerations.shtml.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

17


18<br />

JAMES F. DECAROLIS is a Senior Engineer with the Applied Research Department<br />

of the consulting firm, MWH, where he has been involved with several low-pressure<br />

membrane pilot studies conducted at the Aqua 2030 Research Center located in San<br />

Diego, California. In 2002/2003, he served as an on-site Project Engineer for a United<br />

States Department of Interior, Bureau of Reclamation (USBR) study evaluating the<br />

feasibility of using membrane bioreactor technology for water reclamation. In tandem<br />

with this project, he served as Project Engineer for a Desalination Research Innovation<br />

Partnership project to assess the ability of membrane bioreactors to serve as<br />

pretreatment to reverse osmosis during the treatment of municipal wastewater. Recently, he served as an<br />

on-site Engineer for an advanced water treatment pilot study conducted at North City <strong>Water</strong> Reclamation<br />

Plant, which evaluated ultrafiltration followed by reverse osmosis followed by ultraviolet plus peroxide for<br />

indirect potable reuse. He is currently serving as Project Manager for a USBR project evaluating newly<br />

developed membrane bioreactor systems for water reuse. DeCarolis received both a B.S. and M.S. in<br />

Environmental Engineering from the University of Central Florida.


Session 2: Fundamentals and Applications<br />

Evaluation of Conventional Activated Sludge<br />

Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />

R. SHANE TRUSSELL, PH.D., P.E.<br />

Trussell Technologies, Inc.<br />

Pasadena, California<br />

Introduction<br />

Amembrane bioreactor (MBR) is a biological wastewater treatment process that<br />

implements a low-pressure membrane — microfiltration (MF) or ultrafiltration (UF) — to<br />

provide solid-liquid separation. Due to its compact footprint and consistent high-quality<br />

effluent, MBRs have captured the attention of the international wastewater treatment<br />

community. Although MBRs are ideal for water reclamation projects, the high-quality effluent<br />

and additional pathogen removal make MBRs a promising technology for discharging highquality,<br />

partially disinfected wastewater into streams and water bodies while using little or no<br />

chemical addition for disinfection. The purpose of this presentation is to compare and<br />

evaluate the principle differences, advantages, and disadvantages of the MBR process<br />

compared to a conventional, gravity-settled activated sludge.<br />

Brief Perspective on <strong>Membrane</strong> Bioreactor Development<br />

Biological processes have become the preferred process for municipal wastewater treatment.<br />

The activated sludge process (ASP) was pioneered by Arden and Lockett, who reused the<br />

flocculent solids from the previous aeration cycle to accelerate treatment rates (Ardern and<br />

Lockett, 1914). They called the accumulation of these flocculent solids activated sludge and<br />

found that treatment efficiency increased with higher proportions of activated sludge. The<br />

ASP has continued to develop over the past nine decades, and wastewater treatment plants<br />

are being designed today with an excellent understanding of how to optimize plant<br />

performance for organic, solids, and (more frequently) nutrient removal. However, regardless<br />

of how sophisticated and automated the plant design is, the solid-liquid separation is still<br />

performed by gravity sedimentation, and this means that operations staff must understand<br />

what influences sludge settleability to maintain good effluent quality.<br />

Relatively new to biological wastewater treatment is the MBR process. The development of<br />

the MBR process began in the United States with the direct filtration of activated sludge<br />

through a cloth filter along with the concept of coupling a membrane with activated sludge by<br />

Dorr-Oliver in Stamford, Connecticut (Stiefel and Washington, 1966). Thetford Systems in<br />

Ann Arbor, Michigan, commercialized the MBR process in the early 1970s. This new MBR<br />

process combined the three separate unit operations required in a conventional activated<br />

Correspondence should be addressed to:<br />

R. Shane Trussell, Ph.D., P.E.<br />

Principal<br />

Trussell Technologies, Inc.<br />

232 North Lake Avenue, Suite 300<br />

Pasadena, CA 91101 USA<br />

Phone: (626) 486-0560 • Email: shane.trussell@trusselltech.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

19


sludge treatment train into one compact process (Figure 1). The original MBR was an external<br />

MBR (EMBR) where mixed liquor was pumped from an aeration basin to the membrane<br />

module for solid-liquid separation. Yamamoto et al. (1989) developed the submerged MBR<br />

(SMBR) configuration where the membrane module was immersed directly in the mixed<br />

liquor and operated under suction pressure. It is the SMBR configuration that is currently<br />

dominating the municipal wastewater market and is the focus of this presentation, while the<br />

EMBR configuration is principally implemented on high-strength industrial wastewaters.<br />

Activated Sludge Process<br />

Aeration Basin<br />

Secondary Clarifier<br />

Microfiltration<br />

or Ultrafiltration<br />

Tertiary Treated<br />

Wastewater<br />

Primary Treated<br />

Wastewater<br />

(Equivalent to a<br />

1–3 mm screen)<br />

SMBR Process<br />

Aeration Basin<br />

Backwash <strong>Water</strong><br />

WASTE<br />

Tertiary Treated<br />

Wastewater<br />

WASTE<br />

Figure 1. Flow schemes for activated sludge and SMBR processes.<br />

Submerged <strong>Membrane</strong> <strong>Bioreactors</strong> Versus the Activated Sludge Process<br />

Process Design: The SMBR process uses activated sludge technology, combining it with membrane<br />

filtration, to expand the normal operating region. The SMBR process is not affected by the<br />

limitations associated with gravity sedimentation for solid-liquid separation, and this allows<br />

operation at much higher mixed liquor suspended solids (MLSS) concentrations. The peak<br />

MLSS concentration at which the SMBR process is not sustainable due to rapid membrane<br />

fouling is complex and is an area of ongoing research. However, today’s SMBR plants are<br />

optimally designed for MLSS concentrations between 8 and 12 grams per liter (g/L)<br />

(Trussell et al., 2005a; Trussell et al., 2005b).<br />

Higher MLSS concentrations translate into a longer solids retention time (SRT) for a given<br />

hydraulic retention time (HRT). This means that for the same aeration basin volume needed<br />

for the ASP, the SMBR process could double the design SRT. Longer SRTs provide a more<br />

stable biological process that results in wastewater effluent with low oxygen demand.<br />

Traditionally, SMBRs have been designed to operate at SRTs greater than 20 days (d), and<br />

some small facilities only waste once or twice per year. These longer SRTs ensure that<br />

adequate organics removal and complete nitrification can occur even in cold climates. Longer<br />

SRTs also bring about the possibility that specialized microorganisms could propagate and<br />

remove organics that are difficult and slow to degrade. Most importantly, longer SRTs reduce<br />

biological sludge production, reducing the mass of solids that needs to be disposed.<br />

20


Alternatively, higher MLSS concentrations can translate into reduced aeration basin volume.<br />

This means that for the same SRT as the ASP, the SMBR process could reduce aeration basin<br />

volume significantly, reducing HRT by close to one-half. However, this concept brings to light<br />

one of the principle disadvantages of the SMBR process compared to ASP: the SMBR process<br />

has a minimum SRT, where organics present in the mixed liquor have not been adequately<br />

stabilized, and these organics result in rapid membrane fouling (Trussell et al., 2005a;<br />

Trussell et al., 2004). Some manufacturers have set a minimum SRT at 12 d, while others are<br />

willing to work with design engineers to design at reduced SRTs (as low as 8 d). A common<br />

design for the minimum SRT is to determine where nitrification fails at the wastewater<br />

temperature and then apply a safety factor to ensure nitrification does not fail. The ASP is not<br />

restricted by the interaction of the membrane with the mixed liquor, and many wastewater<br />

treatment plants with ASP operate with low SRTs to inhibit nitrification. Operation at these<br />

low SRTs in SMBRs results in rapid membrane fouling, and SMBR manufacturers do not<br />

recommend plant designs at these low SRTs.<br />

Effluent <strong>Water</strong> Quality: The principle difference in effluent water quality between an SMBR<br />

and an ASP is the solid-liquid separation mechanism. Both SMBR and ASP depend principally<br />

on the biological process to oxidize influent organics and nitrogen. However, SMBR uses a<br />

membrane for solid-liquid separation to obtain a higher quality effluent. A well-operated ASP<br />

will contain suspended solids ≤ 10 milligrams per liter (mg/L), turbidity ≤ 10 nephelometric<br />

turbidity units (NTU), and 5-day biological oxygen demand (BOD 5 ) ≤ 10 mg/L, while the SMBR<br />

process typically contains suspended solids ≤ 2 mg/L (non-detect), turbidity ≤ 0.2 NTU, and<br />

BOD 5 ≤ 2 mg/L (non-detect) (Trussell et al., 2000). The SMBR is retaining all suspended<br />

solids in the reactor and, even though the degree of biological soluble organics removal is solely<br />

a function of the SRT, the SMBR process is removing additional soluble organics because of<br />

the direct filtration of activated sludge. Any organics larger than the membrane pores are<br />

being retained in the reactor, and organics even smaller than the membrane pores are being<br />

retained due to additional filtration provided by the cake layer that develops in these high<br />

solids environments. The SMBR process uses membrane separations to improve the biological<br />

process and produce an effluent that exceeds the effluent quality produced in ASP.<br />

Peak Flows: The principle advantage of the SMBR process — the membrane — is also its<br />

principle weakness when it comes to addressing peak flows. Although highly dependent on<br />

the specifics of the design (i.e., temperature, design flux, etc.), the SMBR process is typically<br />

limited to a peaking factor of 1.5 Q (flow rate), while the ASP is capable of sustaining much<br />

larger peak flows (>2.5 Q) for a longer period of time. This is because all of the peak flow<br />

must be filtered through the membranes to exit the facility in the SMBR, but the peak flow<br />

passes effortlessly over a weir in the ASP. The SMBR process is most economical when<br />

designed to operate at a constant flow rate, and large peak flows are best addressed with flow<br />

equalization in most facilities. As future membrane costs continue to decrease, the issue of<br />

peak flows in SMBRs will become less important because design engineers will be able to<br />

ensure that adequate membrane area is installed to sustain membrane performance during<br />

peak flow events.<br />

Mixed Liquor Properties: The mixed liquor properties are important because they affect how<br />

easily sludge can be filtered through membranes, settled, or dewatered. There is a significant<br />

difference in selective pressures between the ASP and SMBR, and one would expect<br />

significant differences in mixed liquor properties as well. While the ASP requires biology that<br />

flocculates and settles well to remain in the system, the SMBR process retains all biomass,<br />

even single cells, in the mixed liquor.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

21


Although research is still needed to completely understand the differences and what<br />

influences these mixed liquor properties between the ASP and SMBR, Merlo et al. (2004) has<br />

revealed some key findings that highlight the differences in mixed liquor properties:<br />

1. SMBR sludge has a higher colloidal material content than ASP sludge.<br />

2. SMBR sludge has higher filament concentrations than ASP sludge.<br />

3. SMBR sludge particle size distribution (excluding colloidal) was controlled<br />

exclusively by the mixing intensity, G, and the same particle size distribution for an<br />

ASP was obtained for the SMBR.<br />

Merlo et al. (2004) provides explanations for these observed differences between SMBR and<br />

ASP mixed liquor properties:<br />

1. The SMBR mixed liquor has higher colloidal content because the membrane is<br />

retaining materials that would normally exit the ASP over the effluent weir.<br />

2. The SMBR mixed liquor has higher filament concentrations because the SMBR<br />

process is the perfect “trapping” environment. Unless designed with a surface<br />

wasting system, the SMBR process will retain all floating material, including<br />

filamentous microorganisms that float and may cause foam.<br />

3. A similar particle size distribution was obtained for an activated sludge reactor at high<br />

shear conditions (ASP) as that obtained for the SMBR (Figure 2).<br />

0.6<br />

0.5<br />

ASP<br />

Frequency<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

0.6<br />

0.5<br />

2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />

SMBR<br />

Frequency<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0.0<br />

2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />

Characteristic Length, micron<br />

Figure 2. Particle size distribution for ASP and SMBR at 5-d mean cell residence time<br />

(Adapted from Merlo et al., 2004).<br />

22


Still Need to Flocculate: A key conclusion of the SMBR process is that despite all of its<br />

differences from the ASP and the membrane providing an absolute barrier, the mixed liquor<br />

properties still play a significant role in the successful application of the process. A mixed<br />

liquor that is well flocculated and contains a lower concentration of colloidal material is<br />

inherently easier to filter and has a lower fouling potential than a dispersed sludge with high<br />

concentrations of colloidal material (Fan et al., 2006). Recently, this topic has become the<br />

focus of the two leading SMBR manufacturers in the United States market. One gave a<br />

recent workshop in 2005 on “Biohydraulics” while another presented a plot of colloidal<br />

material versus time to filter and indicated the preferred region for good sludge filterability.<br />

As SMBR technology advances, engineers will need to understand mixed liquor properties and<br />

biological characteristics to design an optimized SMBR for a specific application.<br />

Conclusions<br />

Relatively new to the wastewater treatment industry, SMBRs offer significant advantages<br />

compared to conventional ASP: a more compact reactor, higher effluent quality, and higher<br />

MLSS concentrations. However, there are currently significant disadvantages of the SMBR<br />

process that design engineers need to be informed about: high MLSS limit, low SRT limit,<br />

and peak flow issues. Finally, although the SMBR process retains everything larger than the<br />

membrane pores, the mixed liquor properties are still important to minimize fouling and<br />

ensure successful plant operation. We need to change from the concept of sludge settleability<br />

to sludge filterability.<br />

References<br />

Ardern, E., and W.T. Lockett (1914). “Experiments on the oxidation of sewage without the aid of filters.”<br />

J. Soc. Chem. Indtr., (33): 523.<br />

Fan, F., Z. Hongde, and H. Husain (2006). “Identification of wastewater sludge characteristics to predict<br />

critical flux for membrane bioreactor processes.” <strong>Water</strong> Res., (40): 205.<br />

Merlo, R., R.S. Trussell, S.H. Hermanowicz, and D. Jenkins (2004). “Physical, chemical and biological<br />

properties of submerged membrane bioreactor and conventional activated sludges.” WEFTEC,<br />

New Orleans, LA.<br />

Stiefel, R.C., and D.R. Washington (1966). “Aeration of concentrated activated sludge.” Biotechnol. Bioeng.,<br />

(8): 379.<br />

Trussell, R.S., S. Adham, P. Gagliardo, R. Merlo, and R.R. Trussell (2000). “WERF: Application of membrane<br />

bioreactor (MBR) technology for wastewater treatment.” WEFTEC, Anaheim, CA.<br />

Trussell, R.S., S. Adham, and R.R. Trussell (2005a). “Process limits of municipal wastewater treatment with<br />

the submerged membrane bioreactor.” J. Environ. Eng.-ASCE, 131: 410.<br />

Trussell, R.S., R. Merlo, S.H. Hermanowicz, and D. Jenkins (2005b). “The effect of high mixed liquor<br />

suspended solids concentration, mixed liquor properties, and coarse bubble aeration flow rate on membrane<br />

permeability.” WEFTEC, Washington D.C.<br />

Trussell, R.S., R.P. Merlo, S. Hermanowicz, and D. Jenkins (2004). “The effect of organic loading on<br />

membrane fouling in a submerged membrane bioreactor treating municipal wastewater.” WEFTEC,<br />

New Orleans, LA.<br />

Yamamoto, K., M. Hiasa, T. Mahmood, and T. Matsuo (1989). “Direct solid-liquid separation using hollow fiber<br />

membrane in an activated-sludge aeration tank.” <strong>Water</strong> Sci. Technol., 21: 43.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

23


24<br />

R. SHANE TRUSSELL, Ph.D., P.E., is a Principal at Trussell Technologies, Inc., an<br />

environmental engineering firm that focuses on the quality and treatment of water<br />

and wastewater. He has 8 years of hands-on experience with processes for advanced<br />

wastewater treatment, particularly membrane filtration of secondary and tertiary<br />

effluents, membrane bioreactors, reverse osmosis, electrodialysis, ion exchange,<br />

granular activated carbon adsorption, and disinfection with ozone, chlorine, and<br />

chloramines. Where membrane bioreactors are concerned, he is a recognized<br />

authority, and he was the first to demonstrate that membrane fouling due to high<br />

solids concentrations and high food-to-microorganism ratios (low mean cell residence times) are fundamentally<br />

different in their nature. Trussel received a B.S. in Chemical Engineering from the University<br />

of California, Riverside, an M.S. in Environmental Engineering from the University of California, Los<br />

Angeles, and a Ph.D. in Environmental Engineering from the University of California, Berkeley.


Session 2: Fundamentals and Applications<br />

<strong>Membrane</strong> Bioreactor Global Knowledgebase<br />

GLEN T. DAIGGER, PH.D., P.E., BCEE, NAE<br />

CH2M HILL<br />

Englewood, Colorado<br />

Introduction<br />

In 2001, the <strong>Water</strong> Environment Research Foundation (WERF) authorized a project to<br />

assemble a global knowledgebase summarizing the applications and performance of membrane<br />

bioreactors (MBRs) (Daigger et al., 2001). Available on the WERF website to WERF<br />

subscribers or for purchase as a CD-ROM, the knowledgebase contains eight elements,<br />

including:<br />

1. Tutorials (PowerPoint-based) to provide an introduction and overview to parties<br />

potentially interested in MBRs for a particular application.<br />

2. Published Literature Database Search Tool, which is an extensive searchable database<br />

consisting of abstracts from relevant technical papers.<br />

3. Gray Literature Database Search Tool, which is an extensive searchable database<br />

providing listing and source information for relevant gray literature (pilot-plant reports,<br />

manufacturer’s information, etc).<br />

4. Installation Database Search Tool, which is a searchable database providing summary<br />

information for a wide range of MBR installations and more detailed information for<br />

selected examples of various types of installations.<br />

5. Decision Tool, which provides a set of questions and answers to help the website user<br />

determine whether MBRs are potentially applicable for a specific application (should<br />

they be interested in learning more!).<br />

6. Preliminary Sizing Tool, which is used to develop preliminary sizes for a particular<br />

application (used in conjunction with the Decision Tool).<br />

7. Installations Survey Tool, which allows owners of MBR installations to input data on their<br />

application to share with others.<br />

8. Links to Related Websites, which allow access to information on MBRs contained in<br />

other websites.<br />

The searchable database format was selected due to the rapid development of this technology<br />

and allows updates to be completed easily as needed.<br />

Correspondence should be addressed to:<br />

Glen T. Daigger, Ph.D., P.E., BCEE, NAE<br />

Senior Vice President and Chief Technology Officer<br />

CH2M HILL<br />

9191 South Jamaica Street<br />

Englewood, CO 80112 USA<br />

Phone: (720) 286-2542 • Email: gdaigger@ch2m.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

25


The website was initially completed and made available in 2002, then updated in 2004 due to<br />

the rapid development of the technology (Schwartz et al., 2006). Key observations associated<br />

with this knowledgebase are summarized below.<br />

Key Observations<br />

1. Several thousand MBR installations exist on a worldwide basis, with significant<br />

installations located on virtually every continent. A wide range of wastewaters are<br />

treated in MBRs, including municipal and a diverse range of industrial wastewaters,<br />

along with other applications such as landfill leachate.<br />

2. The vast majority of existing MBR applications are small, reflecting historical approaches<br />

to the application of MBR technology (Crawford et al., 2000). However, MBRs are<br />

increasingly being applied to larger plants (Crawford et al., 2005; Daigger et al., 2002).<br />

3. Technical analysis indicates that MBR technology is ready for a wide range of<br />

applications in both developed and developing countries (Daigger et al., 2005), including<br />

advanced wastewater treatment, water reclamation and reuse, pretreatment prior to<br />

reverse osmosis for water reclamation, grey water recycling, and the treatment of highly<br />

polluted environmental waters (Fleischer et al., 2005).<br />

4. MBR design and application has progressed through “three generations,” beginning with<br />

small installations intended to reliably produce high-quality effluent with minimal<br />

attention, to modest sized facilities capable of not only removing biodegradable organic<br />

matter, but also removing nutrients (Crawford et al., 2000). Fourth generation plants<br />

are now being implemented that resemble larger, conventional wastewater treatment<br />

facilities, but are using MBRs rather than conventional biological processes (Daigger and<br />

Crawford, 2005; Daigger et al., 2002).<br />

5. As the size and complexity of MBR facilities have increased, the method of procuring<br />

MBR equipment for these facilities has evolved from one similar to that used to procure<br />

“package” wastewater treatment plants to that used to procure conventional wastewater<br />

treatment equipment (Crawford et al., 2002). As a consequence, owners (and their<br />

engineers) are taking increased responsibility for the overall design of the wastewater<br />

treatment plant and are more carefully defining the responsibilities and scope of supply<br />

of the membrane suppliers.<br />

6. The performance characteristics of MBRs are increasingly well understood (Schwartz et<br />

al., 2006), resulting in increased consensus on the design of these facilities (Daigger and<br />

Crawford, 2005; Daigger et al., 2002).<br />

A result of these trends is that MBRs are becoming an accepted approach to wastewater<br />

treatment that can be successfully applied to a wide range of applications and facility sizes.<br />

The features of MBRs lead some to conclude that they can play an important role in delivering<br />

needed water to even the most disadvantaged worldwide, thereby playing an important role in<br />

meeting Millennium Development goals (DiGiano et al., 2004).<br />

26


References<br />

Crawford, G., G. Daigger, J. Fisher, S. Blair, and R. Lewis (2005). “Parallel Operation of Large <strong>Membrane</strong><br />

<strong>Bioreactors</strong> at Traverse City.” Proceedings of the <strong>Water</strong> Environment Federation 78 th Annual Conference &<br />

Exposition, Washington DC, CD-ROM.<br />

Crawford, G., A. Fernandez, A. Shawwa, and G. Daigger (2002). “Competitive Bidding and Evaluation of<br />

<strong>Membrane</strong> Bioreactor Equipment – Three Large Plant Case Studies.” Proceedings of the <strong>Water</strong> Environment<br />

Federation 75 th Annual Conference & Exposition, Chicago, IL, CD-ROM.<br />

Crawford, G., D. Thompson, J. Lozier, G. Daigger, and E. Fleischer (2000). “<strong>Membrane</strong> <strong>Bioreactors</strong> – A<br />

Designer’s Perspective.” Proceedings of the <strong>Water</strong> Environment Federation 73 rd Annual Conference &<br />

Exposition on <strong>Water</strong> Quality and Wastewater Treatment, Anaheim, CA, CD-ROM.<br />

Daigger, G.T., B.E. Rittmann, S. Adham, and G. Andreottola (2005). “Are <strong>Membrane</strong> <strong>Bioreactors</strong> Ready for<br />

Widespread Application?” Environmental Science and Technology, 399A-406A.<br />

Daigger, G.T. and G.V. Crawford (2005). “Incorporation of Biological Nutrient Removal (BNR) Into <strong>Membrane</strong><br />

<strong>Bioreactors</strong> (MBRs).” Proceedings of the IWA Specialized Conference, Nutrient Management in Wastewater<br />

Treatment Processes and Recycle Streams, Krakow, Poland, 235.<br />

Daigger, G.T., G.V. Crawford, and J.C. Lozier 2002). “<strong>Membrane</strong> Bioreactor Practices and Applications in<br />

North America.” Proceedings of the First Leading Edge Drinking <strong>Water</strong> and Wastewater Treatment Technology<br />

Conference, International <strong>Water</strong> Association.<br />

Daigger, G.T., G. Crawford, A. Fernandez, J.C. Lozier, and E. Fleischer (2001). “WERF Project: Feasibility of<br />

<strong>Membrane</strong> Technology for Biological Wastewater Treatment – Identification of Issues and MBR Technology<br />

Assessment Tool.” Proceedings of the <strong>Water</strong> Environment Federation 74 th Annual Conference & Exposition,<br />

Atlanta, GA, CD-ROM.<br />

DiGiano, F.A., G. Andreottola, S. Adham, C. Buckley, P. Cornel, G.T. Daigger, A.G. Fane, N. Galil, J.G. Jacangelo,<br />

A. Pollice, B.E. Rittmann, A. Rozzi, T. Stephenson, and Z. Ujani (2004). “Safe <strong>Water</strong> for Everyone.”<br />

<strong>Water</strong> Environment and Technology, 31-35.<br />

Fleischer, E.J., T.A. Broderick, G.T. Daigger, A.D. Fonseca, R.D. Holbrook, and S.N. Murthy (2005).<br />

“Evaluation of <strong>Membrane</strong> Bioreactor Process Capabilities to Meet Stringent Effluent Nutrient Discharge<br />

Requirements.” <strong>Water</strong> Environment Research, (77): 162-178.<br />

Schwartz, A.E., B.E. Rittmann, G.V. Crawford, A.M. Klein, and G.T. Daigger (2006). “Critical Review on the<br />

Effects of Mixed Liquor Suspended Solids on <strong>Membrane</strong> Bioreactor Operation.” Separation Science and<br />

Technology, In Press.<br />

GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE, is a recognized expert in wastewater<br />

treatment, especially the use of biological processes. At present, he is a Senior Vice<br />

President and Chief Technology Officer for the international consulting engineering<br />

firm CH2M HILL, where he has been employed for over 23 years. Among his<br />

responsibilities, he oversees wastewater process engineering on both municipal and<br />

industrial wastewater treatment projects on a firmwide basis. He is also the first<br />

Technical Fellow for the firm, an honor recognizing the leadership that he provides<br />

for CH2M HILL and for the profession in the development and implementation of<br />

new wastewater treatment technology. From 1994 to 1996, Daigger also served as Professor and Chair<br />

of the Environmental Systems Engineering Department at Clemson University. In addition, he formerly<br />

served as Chair of the Board of Editorial Review of <strong>Water</strong> Environment Research and as Chair of the<br />

<strong>Water</strong> Environmental Federation Technical Practice Committee. He is currently Chair of the<br />

Committee Leadership Council. Daigger received a B.S. and M.S. in Civil Engineering and a Ph.D. in<br />

Environmental Engineering from Purdue University.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

27


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Design, Procurement, and Costs<br />

of <strong>Membrane</strong> Bioreactor Systems<br />

STEPHEN M. LACY, P.E., DEE<br />

MWH Americas, Inc.<br />

Las Vegas, Nevada<br />

The membrane bioreactor (MBR) has integrated microfiltration with activated sludge to<br />

create a space-efficient facility capable of producing high-quality water. Like any process,<br />

there are advantages and disadvantages to using MBRs. Because of rapid growth in the<br />

application of plant configurations, it is important to understand the design principles<br />

necessary to result in a successful installation. Since MBRs are used in both large and<br />

“end-of-pipe” facilities, understanding the limitations of the process and the proper sizing<br />

of components becomes critical to success.<br />

The MBR process can have the same features and performance of any advanced secondary or<br />

Biological Nutrient Removal (BNR) facility, combined with the flexibility and performance of<br />

membrane filtration. In general, the membrane portion functions as a solid-liquid separation<br />

process. The effluent from an MBR can be expected to outperform any traditional or<br />

conventional treatment system.<br />

Initially, MBRs were installed in small facilities to handle a wastewater flow from a small area,<br />

or as a scalping plant to supply reuse-quality water to an individual user. Today, MBRs are<br />

seeing an expanded use as “end-of-pipe” facilities and to supply clusters of reuse water users<br />

as remote reclamation facilities.<br />

In this presentation, we will discuss several important design concepts and suggest design<br />

parameters that will provide flexibility in the operation of facilities, including the ability to<br />

properly maintain components. We will also discuss a procurement process for the membrane<br />

system. Finally, we will look at some of the costing developed for scalping-type facilities.<br />

Design Considerations<br />

It is important to note that with an MBR, there is no other option for producing an effluent<br />

other than through the membranes. The configuration of an MBR is greatly impacted by<br />

whether the facility will be used as a scalping plant or “end-of-pipe” treatment plant.<br />

Understanding both 1) how the MBR is being applied and 2) the required components needed<br />

for reliable operation are critical to proper design. Several MBR design considerations that<br />

will be discussed during the presentation include:<br />

• Screening (which is critical).<br />

• Handling peak flows.<br />

Correspondence should be addressed to:<br />

Stephen M. Lacy, P.E., DEE<br />

MWH Americas, Inc.<br />

3014 West Charleston Boulevard<br />

Las Vegas, NV 89102 USA<br />

Phone: (702)878-8010 • Email: stephen.lacy@mwhglobal.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

29


• <strong>Membrane</strong> flux rate (which should be selected to allow flexibility).<br />

• Foam control.<br />

• Waste sludge handling.<br />

• Low demand at scalping plants.<br />

A typical layout of an MBR facility configured for full BNR treatment is shown in Figure 1.<br />

This presentation will discuss the configuration of return streams and how to gain some<br />

advantage from the air used to agitate the membranes and avoid negatively impacting the<br />

biological process.<br />

Solids Recirculating System<br />

Anoxic<br />

Zones<br />

Screened<br />

& Degritted<br />

Wastewater<br />

Anaerobic<br />

Zones<br />

OxicZones<br />

<strong>Membrane</strong><br />

Bays<br />

MLSS Recycle System<br />

Selectors Nitrification <strong>Membrane</strong>s<br />

Figure 1. MBR flow schematic.<br />

Procurement of <strong>Membrane</strong> Systems<br />

MBR systems that are commercially available today do not lend themselves to a common<br />

design arrangement, thereby requiring custom application of each manufacturer’s system.<br />

There are three general ways to proceed with the selection and procurement of an MBR system:<br />

• Sufficiently isolate the membrane system from the remainder of the process units so<br />

that the system is independent with minimal impact on the plant layout, allowing the<br />

design to proceed without specific details required of the membrane system.<br />

• Implement the project on an alternative delivery basis, allowing the design-builder to<br />

select and work with a membrane system supplier.<br />

• Procure the membrane system early in the project design so that the facility is<br />

configured around specific equipment.<br />

In this presentation, we will focus on the latter of the options.<br />

The early procurement of the membrane systems can shorten the project schedule by allowing<br />

both the designers to customize the design around the specific equipment being installed and<br />

the equipment supplier to commence manufacturing while design is underway. Commonly,<br />

this procurement is accomplished in a two-step process. The first is a qualification-based<br />

selection to create a short-list of manufacturers. These manufacturers are invited to furnish<br />

proposals for their equipment as part of the second step. Because the equipment is varied in<br />

configuration and operation, an evaluated bid process is used to review the proposals and the<br />

final selection of the supplier.<br />

30


Cost Analysis of <strong>Membrane</strong> Bioreactor Systems for <strong>Water</strong> Reclamation<br />

Cost estimates were developed for full-scale MBR reclamation (scalping) systems ranging from<br />

0.2 to 10 million gallons per day (mgd). These estimates included both capital and operational<br />

costs related to the MBR process and subsequent disinfection. The costs associated with the<br />

membrane portion of the MBR systems were developed from cost quotes from four leading<br />

MBR suppliers. All other costs, including headworks, biological process, and disinfection<br />

costs, were estimated from preliminary conceptual design. Results of the analysis indicate<br />

that the total costs ($/1000 gallons) for 1-mdg MBR water reclamation systems, designed<br />

to operate on raw wastewater, ranged from $1.81 to $2.24.<br />

STEPHEN M. LACY, P.E., DEE, has more than 30-years experience in all facets of<br />

water and wastewater projects, from development through construction. He is a<br />

Project Manager for MWH Americas, Inc., working with the wastewater technical<br />

group. Over the past several years, Lacy has been involved in the testing, evaluation,<br />

and conceptual design for clients who are considering membrane treatment of their<br />

wastewater. He has also looked at wastewater membranes in the membrane<br />

bioreactor process and ultrafiltration of secondary effluent using submerged and<br />

pressure membrane configurations. A member of the Nevada <strong>Water</strong> Environment<br />

Association, he is currently Co-Chairman of both the Professional Development and Government Affair<br />

Committees. Lacy received a B.S. in Civil Engineering and an M.E. in Sanitary Engineering from the<br />

University of Idaho.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

31


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Retrofit of an Existing Conventional Wastewater<br />

Treatment Plant with Zenon <strong>Membrane</strong><br />

Bioreactor Technology<br />

DAVE N. COMMONS<br />

City of Redlands Municipal Utilities Department<br />

Redlands, California<br />

On May 31, 2001, the State of California Waste Discharge Requirement (WDR) permit<br />

for the wastewater treatment facility of the Wastewater Division of the City of Redlands<br />

Municipal Utilities Department was modified from requiring a Total Inorganic Nitrogen (TIN)<br />

12-month average effluent limitation of 15 milligrams per liter (mg/L) to a new permit effluent<br />

compliance level of 10 mg/L. The wastewater treatment plant, as configured at that time,<br />

could not meet this new compliance limitation because of insufficient aeration basin capacity.<br />

Because California was experiencing energy shortages in 2001, the City of Redlands<br />

Wastewater Division was also asked to provide to the Mountain View Power Company (a<br />

division of the Southern California Edison Company) a reliable source of high-quality cooling<br />

water that was not only low in total suspended solids (TSS) and biochemical oxygen demands<br />

(BOD), but also had less than 5 mg/L of total phosphates.<br />

The Wastewater Division evaluated the capability of a step feed, multi-anoxic zone nitrification/<br />

denitrification treatment process modification with both pre-anoxic and post-anoxic zone<br />

configurations to the current treatment process to meet these nutrient requirements. It was<br />

determined that even thought both of these process modifications met the required effluent<br />

TIN limitation of 10 mg/L, neither would be able to meet the effluent TIN limitation on a<br />

sustained basis. It was also determined that the Division would not meet the total phosphates<br />

requirement of the power plant with the current plant configuration and treatment processes.<br />

After an extensive evaluation of the capabilities of conventional granular filtration technology<br />

versus membrane bioreactor (MBR) technology in different configurations, the City decided to<br />

upgrade 22.7 megaliters per day (ML/d) (6.0 million gallons per day [mgd]) of the Wastewater<br />

Division’s 35.96 ML/d (9.5 mgd) secondary-level activated sludge facility to a full tertiary-level<br />

treatment by using a dual-stage MBR facility. The dual-stage MBR configuration places the<br />

membrane cassettes in separate bioreactor tanks rather than within aeration basins. It was<br />

also decided that because the plant used anaerobic digestion for biosolids stabilization and<br />

because space was limited in the aeration basins for separate anaerobic zones, chemical<br />

precipitation using iron salts would be used for phosphate removal instead of using biological<br />

phosphorus removal. The iron salts were chosen over aluminum salts because ferrous chloride<br />

was already being used in the facility for hydrogen sulfide control in the anaerobic digesters.<br />

Correspondence should be addressed to:<br />

Dave N. Commons<br />

<strong>Water</strong> Operations Manager<br />

City of Redlands Municipal Utilities Department<br />

P.O. Box 3005<br />

35 Cajon Street, Suite 15A<br />

Redlands, CA 92373 USA<br />

Phone: (909) 798-7588 • Email: dcommons@cityofredlands.org<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

33


This presentation will give a description of the treatment technology evaluation that led to the<br />

decision to construct an MBR facility instead of using conventional granular filtration<br />

technology to meet California’s Title 22 requirements for reclaimed water usage. A detailed<br />

evaluation of the start-up problems will then follow. This will include dealing with such issues<br />

as a lower-than-expected aeration influent soluble BOD, which required evaluating long-term<br />

methanol addition to resolve the low soluble BOD issue. An extensive explanation of start-up<br />

procedures will then follow, which will include testing protocol, treatment methodology<br />

experimentation, and treatment evaluation results that were necessary for the Wastewater<br />

Division to bring this dual-stage MBR facility into compliance with the both the State of<br />

California WDR permit requirements and the needs of the electrical power generating facility.<br />

The final section of the presentation will deal with a discussion of long-term process problems,<br />

challenges, and recommendations that resulted from the start-up and operations of a full<br />

tertiary treatment level, dual-stage MBR wastewater reclamation facility.<br />

As more wastewater treatment facilities use MBR facilities to meet high-quality wastewater<br />

effluent criteria needed for water reclamation because of the technology’s ability to meet<br />

high-level criteria on a consistent, low-cost basis, it is importance to evaluate the operational<br />

problems and challenges that these plants present. This presentation will provide insights into<br />

both start-up and long-term operating process issues. Since this conference is being held in<br />

California, a discussion of the operational issues and problems of the largest membrane<br />

bioreactor facility in the State of California (at the time of this submission), where water<br />

reclamation issues are paramount, should be relevant to conference attendees.<br />

Further Reading<br />

Commons, D. (2002). Twenty Week Evaluation of the Multi-Anoxic Zones Nitrification/ Denitrification<br />

Treatment Process for Removing Low Level Total Inorganic Nitrogen at the City of Redlands, California<br />

Wastewater Treatment Facility, WEFTEC 2002, Chicago, IL.<br />

Commons, D., G. Beliew, S.S. Nedic, and J. Cumin (2005). “MBR Reduces Potable <strong>Water</strong> Use, Increases<br />

Revenue,” <strong>Water</strong>world, September, Volume 21, No. 9.<br />

Pearson, D. (2005). “New Dual-Stage MBR Technology Yields Higher Quality Effluent at Reduced Operating<br />

Costs,” Industrial <strong>Water</strong>world, March/ April, Volume 6, No. 2.<br />

U.S. Environmental Protection Agency (1987). Phosphorus Removal, EPA/625/1-87/001, Washington, D.C.<br />

U.S. Environmental Protection Agency (1993). Nitrogen Control, EPA/625/R-93/010, Washington, D.C.<br />

<strong>Water</strong> Environment Federation (1996). Operation of Municipal Wastewater Treatment Plants, Volume III, 5 th<br />

Edition, Alexandria, VA.<br />

<strong>Water</strong> Environment Federation (1998). Biological and Chemical Systems for Nutrient Removal, Special<br />

Publication, Alexandria, VA.<br />

34


DAVE N. COMMONS has over 25 years of experience with wastewater treatment<br />

and collection and over 18 years of experience in the water treatment and distribution<br />

field. At present, he is the <strong>Water</strong> Operations Manager for the City of Redlands<br />

Municipal Utilities Department, where he oversees all City water supply sources,<br />

water and wastewater treatment facilities, and potable water distribution and<br />

wastewater collection systems, among others. Prior to joining the City of Redlands,<br />

he was the <strong>Water</strong> Utilities Operations Manager for the City of Corona <strong>Water</strong> Utilities<br />

Department in California and Field Operations Division Manager for the Sarasota<br />

County Utilities Department in Florida. Commons received a B.A. in Divinity and Education from<br />

Antioch Baptist Bible College and a Masters degree in Divinity and Religious Education from<br />

Southwestern Baptist Theological Seminary. He also holds Grade V Wastewater Operator, Grade T5<br />

<strong>Water</strong> Operator, and D5 Distribution Operator certificates in the State of California, with equivalent<br />

wastewater certificates in both the States of Georgia and Florida.<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

35


Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

Retrofit of an Existing Conventional Wastewater<br />

Treatment Plant with USFilter <strong>Membrane</strong><br />

Bioreactor Technology<br />

JOHN HATCHER<br />

Oconee County Utility Department<br />

Watkinsville, Georgia<br />

In 2002, the Oconee County Utility Department (OCUD) sought to increase plant capacity<br />

at Calls Creek Wastewater Treatment Plant in Georgia. Different traditional treatment<br />

processes were looked at and weighed against the quality of the effluent that each produced.<br />

For the cost and quality of the system, membrane microfiltration emerged as the leading<br />

candidate. Traditional equipment would provide the quality of water needed to meet the<br />

present discharge permit, but may not have met it in the future. The quality of the water<br />

produced by membranes surpassed any other available technology for the price, and the<br />

decision was made to proceed in that direction.<br />

After deciding on the manufacturer, a pilot plant was provided by USFilter for evaluation and<br />

testing. The pilot plant passed all testing and met the effluent quality parameters that were<br />

needed. After completion of the pilot, OCUD moved forward with awarding the bid to<br />

USFilter to complete a design/build upgrade at Calls Creek.<br />

The construction process worked alongside the existing Orbal aeration basin and was<br />

integrated into it. Submersible pumps were installed in the center channel of the aeration<br />

tank, which pumped the mixed liquor into ultrafine wedge wire rotary screens. The screens<br />

removed all types of trash before the mixed liquor entered the membrane bioreactor (MBR)<br />

building for filtration. After filtration, the effluent was discharged to the existing ultraviolet<br />

system for disinfection before final discharge. The return activated sludge leaving the MBR<br />

was sent back to the aeration tank to begin the process all over again.<br />

The MBR system went online in April 2004 and has been in service since then. The system<br />

has provided high quality effluent and has allowed OCUD to look into the possibility of<br />

providing the treated effluent back to our customers as reuse water for irrigation.<br />

Correspondence should be addressed to:<br />

John Hatcher<br />

Wastewater Supervisor<br />

Oconee County Utility Department<br />

P..O Box 88<br />

Watkinsville, GA 30677 USA<br />

Phone: (706) 769-3963 • Email: callscreek@msn.com<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

37


38<br />

JOHN HATCHER is the Wastewater Supervisor for Oconee County Utility Department,<br />

which provides drinking water and sanitary sewer service to its customers within the<br />

service areas inside Oconee County, Georgia. As Wastewater Supervisor, he is<br />

responsible for the daily operation and compliance of a conventional wastewater<br />

treatment plant and a land-application wastewater plant. Recently, he won two<br />

awards from the Georgia <strong>Water</strong> and Pollution Control Association, one of which was<br />

for the Calls Creek Wastewater Treatment Plant, which discharges into the Calls<br />

Creek watershed. Hatcher received a B.S. in Environmental Health Science from<br />

the University of Georgia. He is also a licensed water and wastewater treatment plant operator in the<br />

State of Georgia.


Session 3: Case Studies - Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />

<strong>Membrane</strong> Bioreactor Applications:<br />

A Global Perspective<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Pilot-Plant Studies<br />

Since membrane bioreactor (MBR) performance is highly dependent upon feedwater<br />

quality, a true comparison of the performance of different MBR technologies can only be<br />

achieved when they are tested against the same feedwater matrix. A number of comparative<br />

pilot trials have been conducted over the past 5 years, which permit a useful technology<br />

comparison (Table 1), albeit with certain caveats. The studies identified in Table 1 have all<br />

been conducted this millennium, and all employ at least one full-scale membrane module and<br />

at least three different technologies. Not all of these studies have been published, however.<br />

Table 1.<br />

Comparative Pilot-Plant Trials<br />

Reference<br />

Technology Adham Van der Tao Honolulu Lawrence Trento EAWAG<br />

Tested et al. Roest et al. et al.<br />

(2005) et al. (2005) (2005)<br />

(2002)<br />

Zenon X X X X X X<br />

Kubota X X X X X X<br />

Mitsubishi Rayon X X X X X<br />

Norit – X –<br />

Huber (X) X<br />

Memcor X X X<br />

Toray<br />

X<br />

Comparative Parameters<br />

To allow a comparison of disparate sets of data from various full-scale plants, normalization of<br />

the data is required. The most convenient parameters to use are flux (J, liters per cubic meter<br />

per hour [LMH]), permeability (K, LMH/bar), and specific aeration demand with respect to<br />

membrane area (SAD m , Nm 3 hr -1 m -2 or m hr -1 ) and permeate volume (SAD p , Nm 3 air per m 3<br />

permeate [i.e., unitless]). A comparison of such data for full- and pilot-scale plants is provided<br />

in Table 2.<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

39


Table 2. Summary of Key Parameters<br />

Cap 1 Flux K SAD m<br />

2 SAD p<br />

2 MLSS Filt. cycle3 (min) Cleaning Cycle 4<br />

(MLD) (LMH) (LMH/bar) (Nm/h) (–) (g/L) on r or b Interval Type<br />

Zenon<br />

p 20 225 0.54 27 10-11<br />

p 35 225 0.54 15 10-11<br />

p 37.2 270 0.52 14 8-10 9.5 0.5b<br />

p 16 120 0.33 22 9 1b<br />

p 10 200 0.54 28 7 5 0.5b<br />

p 12.4 124 5 0.31 25 4-13 12 0.5b<br />

2* 18 95 1 56 15 10 0.75b 1w/6m mCIP/R<br />

48 18 144 0.29 16 8-10 10.5 1.5r 1w/15m mCIP/R<br />

0.15,i 12 71 0.65 54 10-15 10 0.5b 0.5w mCIP<br />

48 25 175 0.4 17 12 7 1 0.5m mCIA<br />

Mitsubishi Rayon<br />

p 7.5 200 0.33 52 9-12 1200 240r<br />

p 4.8 90 0.37 38 8 8 0.5b/1.5r<br />

0.38 10 30 0.65 65 12<br />

p 23 140 1 45 8-14 12 2r<br />

p 20 66 5 0.48 20 6-14 13 2r<br />

USF Memcor<br />

p 21.7 150 0.39 18 6-8<br />

p 21 182 0.2 17<br />

0.61 16 150 5 0.18 11<br />

Asahi-kasei<br />

0.9,i 16 80 0.24 15 Ind<br />

Koch Puron<br />

0.63 25 160 0.25 10 Mun 5 3w mCIP<br />

Kubota<br />

p 10.4 650 0.75 75 10-12 8 2r<br />

p 25 250 0.6 24 9-12 9 1r<br />

p 15 261 0.98 79 9 1r<br />

p 9.5 200 1.5 88 8 8 2r<br />

p 26 650 4 0.94 39 6-12 9 1r<br />

1.9 20 350 0.75 32 12-18 1380 60r 8-9m CIP<br />

13 33 330 1.06 32 8-12 1380 60r 6m CIP<br />

4.3 25 680 0.56 23 10-20 1-2 6m CIP<br />

Brightwater<br />

1.2 27 150 1.28 47 12-15 55 5r >18m CIP<br />

Toray<br />

0.53 25 208 0.54 22 6<br />

Huber<br />

0.11 24 250 0.35 22 Mun 9 1 none<br />

Colloide<br />

0.29 25 62.5 0.5 20 Mun 6 2 na<br />

1 Plant capacity or plant type (p = pilot plant); MLD = Megaliters per day.<br />

2 Specific aeration demand; Nm/h = Cubic namometers per hour air per cubic meters membrane.<br />

3 Filtration cycle (r = relaxation; b = backflush); on = Filtration period.<br />

4 Cleaning intervals (w = weeks; m = months).<br />

5 Maximum permeability.<br />

Intermittent aeration used for all Zenon plants other than *.<br />

CIP = Cleaning in place. mCIP = Maintenance cleaning in place.<br />

mCIP/R = Maintenance cleaning in place with relaxation. mCIA = Maintenance cleaning in air.<br />

40


It has generally been observed from lab-scale studies that attainable flux increases with increasing<br />

aeration rates due to increased scouring. This is manifested either as an increase in the<br />

critical or sustainable flux. In a full-scale plant, this would be expected to be manifested as an<br />

increase in sustainable net permeability with an increasing aeration rate. This, indeed, appears<br />

to be the case, with a general tendency for increasing permeability with increasing SAD m ,<br />

though the data is highly scattered (Figure 1). Some of this data scatter can be attributed to<br />

obvious outliers, namely either a plant operating under sub-optimal conditions and/or a very<br />

small unstaffed plant, where blowers are more likely to be oversized to maintain permeability<br />

and, therefore, limit maintenance. Sustainable permeability also changes according to<br />

clearning protocols and the nature of aeration (i.e., the specifications of the aerator itself and<br />

the mode of application [continuous or intermittent]). Although physical cleaning is, to some<br />

extent, accounted for by using net rather than gross flux in calculating permeability,<br />

maintenance cleaning with hypochlorite permits higher permeabilities to be sustained.<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

✶<br />

▲<br />

❖<br />

♦<br />

✦<br />

✦ ❖<br />

❖ ✦<br />

✣ ▲<br />

▲●<br />

■<br />

✦<br />

✦<br />

✦ ❊<br />

■<br />

✦▲<br />

■<br />

■<br />

■<br />

■<br />

▲<br />

✦<br />

■<br />

✦ Zenon<br />

■ Kubota<br />

▲ M Rayon<br />

❖ USF<br />

✶ Huber<br />

● Colloide<br />

✣ Asahi-k<br />

♦ Puron<br />

✧ Brightwater<br />

❊ Toray<br />

✧<br />

■<br />

0<br />

0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6<br />

SADm, NM^3/hr per m^2<br />

Figure 1. Operating permeability versus specific aeration demand for data in Table 2.<br />

If the more obvious outliers are ignored, then some general trends can be identified from<br />

the data:<br />

a) Flat sheet (FS) systems tend to operate at high permeabilities (generally >200 LMH/bar)<br />

and are associated with high aeration demands, both as SAD m and SAD p . No trend<br />

is evident in this data subset, though all but the highest (and probably non-optimal)<br />

SAD p values lie within the range 20 to 39.<br />

b) Hollow fiber (HF) systems tend to operate at lower permeabilities (generally<br />


Physical cleaning appears to be predominantly by relaxation rather than by backflushing.<br />

Pilot−plant data indicate that the downtime for physical cleaning accounts for between 4 and<br />

20 percent of the operating time, with no profound difference between the two configurations.<br />

On the other hand, maintenance cleaning every 3 to 4 days using relatively low concentrations<br />

of hypochlorite (250 to 500 milligrams per liter [mg/L]) is routinely employed for the Zenon<br />

technology, whereas chemical cleaning is limited to infrequent recovery cleans alone for<br />

FS systems. For both FS and HF systems, such cleans are generally applied at intervals of<br />

6 to 18 months (depending on the flux) and generally employ hypochlorite concentrations<br />

between 1,000 and 5,000 mg/L sodium hypochlorite (NaOCl). Both maintenance and<br />

recovery cleaning are either brief or infrequent enough to add little to the percentage<br />

downtime. For example, an overnight soak of 16 hours every 6 months amounts to less than<br />

0.25 percent in such cases. For Zenon plants, the maintenance cleaning cycle is complete<br />

within 10 minutes and is employed no more than three times a week, again amounting to less<br />

than 0.4-percent downtime. Thus, for the majority of the most recent plants, the ratio of the<br />

net-to gross flux is determined by a period of relaxation alone, and the most onerous impact of<br />

chemical cleaning is chemical usage and chemical waste discharge.<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.<br />

42


Session 4: Innovative Applications and Future Outlook of the Technology<br />

<strong>Membrane</strong> Aeration, Biofilms,<br />

and <strong>Membrane</strong> <strong>Bioreactors</strong><br />

MICHAEL J. SEMMENS, PH.D., P.E.<br />

University of Minnesota<br />

Minneapolis, Minnesota<br />

The theory of membrane gas transfer has been studied and characterized in detail over the<br />

past 30 years. It is possible to accurately predict the gas transfer performance of<br />

membranes using numerous dimensionless correlations if the membrane area and operating<br />

conditions are known. <strong>Membrane</strong>s are now widely used for gas transfer in a variety of<br />

applications, including blood oxygenation, vacuum degassing, and pervaporation.<br />

Environmental applications of membrane gas transfer have been slower to develop because of<br />

problems with biofilm fouling of the membrane surface. If we are to design effective<br />

membrane gas transfer processes for water/wastewater treatment, we need to understand how<br />

these biofilms impact gas transfer. How do these biofilms behave? Is biofilm formation<br />

always a bad thing or are there advantages? This presentation will examine the influence of<br />

biofilms on the gas transfer performance of membranes and explore opportunities for novel<br />

applications in membrane bioreactors.<br />

PROFESSOR MICHAEL J. SEMMENS, P.E., is Professor in the Department of<br />

Civil and Mineral Engineering at the University of Minnesota, where he has taught<br />

since 1977. His research interests include the development of physical and chemical<br />

processes for water, wastewater, and waste treatment; processes to identify factors<br />

that limit mass transfer and the kinetics of separation; membrane bioreactors, module<br />

design, and membrane applications in water and wastewater treatment; and the use<br />

of membranes for controlled gas delivery in biologically active environments, such as<br />

groundwater and sediment remediation projects, and wastewater treatment.<br />

Semmens received a B.S. in Chemical Engineering from the Imperial College of Science and Technology<br />

in London, England, an M.S. in Environmental Engineering from Harvard University, and Ph.D. in<br />

Environmental Engineering from University College in London, England.<br />

Correspondence should be addressed to:<br />

Michael J. Semmens, Ph.D., P.E.<br />

Professor, Department of Civil Engineering<br />

University of Minnesota<br />

500 Pillsbury Drive SE<br />

Minneapolis, MN 55455 USA<br />

Phone: (612) 625-9857 • Email: semme001@umn.edu<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

43


Session 4: Innovative Applications and Future Outlook of the Technology<br />

Future Outlook on<br />

<strong>Membrane</strong> Bioreactor Technology<br />

SIMON J. JUDD, PH.D.<br />

Cranfield University<br />

Bedfordshire, United Kingdom<br />

Challenges<br />

Two areas having a direct bearing on the effective and efficient operation of membrane<br />

bioreactors (MBRs) are 1) cleaning and 2) dynamic effects. The cleaning of surfaces, as<br />

a subject for scientific investigation, pre-dates membrane process development since the<br />

fouling of heat exchangers, and the consequent loss of thermal efficiency has been an issue for<br />

many years. The fouling and cleaning of membranes relating to industrial process separations<br />

have also been the subject of research and development for over 20 years. Compared to this,<br />

the science of membrane cleaning in the context of MBRs is a young one — there have been a<br />

great number of investigations of MBR fouling, but much less on the appropriate chemicals<br />

and protocol for recovering permeability for irreversibly fouled membranes. Given the large<br />

number of parameters that determine the degree of permanent fouling and the candidate<br />

variable parameters that could determine cleaning efficacy, the scope of a rigorous study of<br />

cleaning is potentially extremely broad. Thus, it is not surprising that cleaning protocols have<br />

been developed in an ad hoc way through heuristic investigation.<br />

Dynamic effects exert the greatest influence on consistency in MBR performance, ultimately<br />

leading to equipment and/or consent failures, but have also been largely overlooked by the<br />

academic research community. Specifications for full-scale MBR installations are generally<br />

based on conservative estimates of hydraulic and organic (and or ammoniacal) loading.<br />

However, in reality, these parameters fluctuate significantly. Moreover, even more significant<br />

and potentially catastrophic deterioration in performance can arise through equipment<br />

malfunction and operator error. Such events can be expected to produce over short periods of<br />

time (Table 1):<br />

• Decreases in mixed liquor suspended solids (MLSS) concentration (either through<br />

the loss of solids by foaming or by dilution with feedwater).<br />

• Foaming problems, usually associated with the above.<br />

• Loss of aeration (through control equipment malfunction or aerator port clogging).<br />

• Loss of permeability (through the misapplication of backflush and cleaning<br />

protocols, hydraulic shocks, or contamination of the feed with some unexpected<br />

component).<br />

Correspondence should be addressed to:<br />

Simon J. Judd, Ph.D.<br />

Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />

Building 61<br />

Cranfield University<br />

Bedfordshire MK43 0AL United Kingdom<br />

Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

45


Table 1. Key Dynamic Determinants and Their Impacts<br />

Determinants<br />

MLSS dilution<br />

Aeration loss<br />

Backflush/cleaning loss<br />

Hydraulic shock<br />

Saline intrusion<br />

Variables<br />

Dilution factor and rate of concentration increase<br />

Percentage and period of reduction<br />

Period of loss<br />

Rate and level of flow increase<br />

Ultimate concentration factor and rate of<br />

concentration decrease<br />

An example of feedwater constituent fluctuation is seawater intrusion. It has been recognized<br />

for some time that rapid changes in salinity can impact microbial physiology, increasing levels<br />

of organic matter (as chemical oxygen demand [COD] or biochemical oxygen demand [BOD])<br />

arising in activated sludge process (ASP) effluent and decreasing microbial activity. However,<br />

the phenomenon has not been investigated for MBRs, where such physiological changes might<br />

be expected to impact fouling. Further examples include fats, oils, and grease (FOGs) and<br />

bacteriological inhibitory substances, since the latter can then alter the system microbiology<br />

and, therefore, generate fouling.<br />

Outlook<br />

Despite the limitation imposed by fouling, the future of membrane bioreactors in municipal<br />

and industrial wastewater treatment seems assured. Valued at an estimated $216.6 million in<br />

2005, the global MBR market is rising at an average annual growth rate of 10.9 percent,<br />

significantly faster than the larger market for advanced wastewater treatment equipment and<br />

more rapidly than the markets for other types of membrane systems. It is expected to<br />

approach $363 million in 2010 (Hanft, 2006). The number of installations for both of the<br />

leading suppliers has undergone exponential growth since the first pilot trials of the submerged<br />

process in 1989 (Figure 1), driven by opportunities presented by increasingly stringent<br />

environmental legislation and by ever-decreasing process costs (Figure 2). Further<br />

incremental improvements can be expected as more is understood about the interrelationship<br />

between biomass characteristics, permanent fouling, and cleaning, and as membrane costs<br />

continue to be driven downwards. More significant “quantum leap” improvements are less<br />

easily envisioned, however, and it remains to be seen whether any profoundly original MBR<br />

products will arise from current research and development activity.<br />

References<br />

Hanft, S. (2006). <strong>Membrane</strong> <strong>Bioreactors</strong> in the Changing World <strong>Water</strong> Market. Business Communications<br />

Company, Report C-240.<br />

Kennedy, S., and C. Churchouse (2005). Progress in <strong>Membrane</strong> <strong>Bioreactors</strong>: New Advances, Experiences, and<br />

Applications of <strong>Membrane</strong> <strong>Bioreactors</strong> in the Treatment of Domestic and Industrial Wastewaters. Wakefield,<br />

United Kingdom.<br />

46


Kubota<br />

Zenon<br />

1500000<br />

1250000<br />

1000000<br />

750000<br />

500000<br />

250000<br />

0<br />

1995<br />

1996<br />

1997<br />

1998<br />

1999<br />

2000<br />

2001<br />

2002<br />

2003<br />

2004<br />

Figure 1. Cumulative installed capacity in cubic meters per day (m3/d) for Kubota and Zenon.<br />

Relative cost / m 3 at 100 l/s<br />

160<br />

140<br />

120<br />

100<br />

80<br />

60<br />

40<br />

@ 8640 m 3 /d<br />

Costs Projected in<br />

1999<br />

Rent and rates<br />

Sludge disposal<br />

Screenings<br />

<strong>Membrane</strong> replacement<br />

Chemicals<br />

Maintenance<br />

Power<br />

Amortised capital<br />

Actual Costs<br />

20<br />

0<br />

1992 1994 1995 1996 1998 2000 2002 2004 2005<br />

Year<br />

Figure 2. MBR process costs (Kubota) versus time (Kennedy and Churchouse, 2005).<br />

A <strong>Short</strong> <strong>Course</strong> on<br />

<strong>Membrane</strong> <strong>Bioreactors</strong><br />

47


48<br />

PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />

University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />

1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />

all biomass separation membrane bioreactor (MBR) programs conducted within the<br />

School and has been Principal or Co-Investigator on three major UK research<br />

council-sponsored programs dedicated to MBRs with respect to in-building water<br />

recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />

also serves as Chairman of the Project Steering Committee of the multi-centered<br />

EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />

Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />

2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />

Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!