Membrane Bioreactors Short Course Abstracts - National Water ...
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Published by the<br />
<strong>National</strong> <strong>Water</strong> Research Institute<br />
NWRI-2006-02<br />
10500 Ellis Avenue • P.O. Box 20865<br />
Fountain Valley, California 92728-0865 USA<br />
(714) 378-3278 • Fax: (714) 378-3375<br />
www.NWRI-USA.org
Conference Planning Committee<br />
Chair:<br />
✦ SAMER S. ADHAM, Ph.D., MWH<br />
✦ SIMON J. JUDD, Ph.D., Cranfield University<br />
✦ GINA MELIN, <strong>National</strong> <strong>Water</strong> Research Institute<br />
✦ JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute<br />
✦ TAMMY RUSSO, <strong>National</strong> <strong>Water</strong> Research Institute<br />
Sponsors<br />
The Conference Planning Committee is indebted to the following organizations and<br />
corporations whose support has helped make this conference a success.<br />
✦ NATIONAL WATER RESEARCH INSTITUTE<br />
✦ MWH<br />
✦ CRANFIELD UNIVERSITY<br />
✦ USFILTER<br />
✦ ZENON ENVIRONMENTAL CORPORATION<br />
✦ ORANGE COUNTY WATER DISTRICT<br />
✦ CORONA DEPARTMENT OF WATER AND POWER<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
iii
Foreword<br />
ICROFILTRATION IV is the fourth in a series of conferences sponsored by the <strong>National</strong><br />
M<strong>Water</strong> Research Institute (NWRI) devoted to low-pressure membrane (microfiltration<br />
and ultrafiltration) applications to water and wastewater treatment.<br />
Since the first NWRI-sponsored Microfiltration Conference in 1994, the technology has<br />
advanced and become a popular alternative to conventional treatment. MICROFILTRATION IV<br />
provides an update on the status of the technology and a focus on critical issues faced by<br />
end-users, such as new applications, regulatory perspectives, operational experiences, and<br />
fouling control.<br />
A special feature of MICROFILTRATION IV is a one-day short course on membrane bioreactors<br />
(MBRs), a promising technology that uses microfiltration to enhance the wastewater and<br />
reclaimed water treatment processes. The short course provides information on the state-of-the-art<br />
in MBRs and focuses on topics such as MBR design, procurement issues, and costs.<br />
The extended abstracts presented in this document were the contributions of conference speakers.<br />
The opinions expressed within the abstracts are those of individual authors and do not<br />
necessarily reflect those of the sponsors.<br />
NWRI gratefully acknowledges the efforts of all those involved with the planning, organizing,<br />
and sponsoring the conference, including MWH, Cranfield University, USFilter, Zenon<br />
Environmental Corporation, the Corona Department of <strong>Water</strong> and Power, and Orange County<br />
<strong>Water</strong> District. NWRI also extends special thanks to the conference moderators and speakers,<br />
whose expertise provided invaluable insight into the status and needs of membrane technology.<br />
NWRI would also like to extend sincere thanks to Gina Melin, Editor, and Tim Hogan,<br />
Graphic Designer, for their efforts in bringing this document to press and ensuring that the<br />
quality of each and every abstract reached their fullest potential.<br />
Lastly, this conference would not have been possible without the vision of Ronald B. Linsky,<br />
Executive Director of NWRI until his passing in August 2005. Ron will be fondly<br />
remembered for his energy, enthusiasm, and dedication to NWRI and the water community.<br />
Jeffrey J. Mosher<br />
Acting Executive Director<br />
<strong>National</strong> <strong>Water</strong> Research Institute<br />
Fountain Valley, California<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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Program and Contents<br />
WEDNESDAY, MARCH 22, 2006<br />
7:00 am - 9:00 am Registration Foyer of California Ballroom<br />
Session 1: Introduction<br />
California Ballroom<br />
Moderated by JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />
8:30 am - 8:45 am Welcome<br />
JEFFREY J. MOSHER, <strong>National</strong> <strong>Water</strong> Research Institute, California<br />
8:45 am - 9:15 am <strong>Membrane</strong> <strong>Bioreactors</strong> and ............................. 1<br />
the Future of Wastewater Treatment<br />
R. RHODES TRUSSELL, Ph.D., P.E., DEE,<br />
Trussell Technologies, Inc., California<br />
9:15 am - 9:45 am Biological Process Principles ............................ 3<br />
GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />
University of California, Davis, California<br />
9:45 am - 10:00 am Break<br />
Session 2: Fundamentals and Applications<br />
Moderated by SAMER S. ADHAM, Ph.D., MWH, California<br />
10:00 am - 10:45 am <strong>Membrane</strong> Bioreactor Process Fundamentals .............. 5<br />
SIMON J. JUDD, Ph.D., Cranfield University, England<br />
10:45 am - 11:05 am Commercially Available <strong>Membrane</strong> Bioreactor Systems ...... 11<br />
JAMES F. DECAROLIS, MWH, California<br />
11:05 am - 11:25 am Evaluation of Conventional Activated Sludge .............. 19<br />
Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />
R. SHANE TRUSSELL, Ph.D., P.E.,<br />
Trussell Technologies, Inc., California<br />
11:25 am - 11:45 am <strong>Membrane</strong> Bioreactor Global Knowledgebase .............. 25<br />
GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE,<br />
CH2M HILL, Colorado<br />
11:45 am - 12:15 pm Panel Discussion<br />
12:15 pm - 1:30 pm Lunch The Atrium<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />
Moderated by GEORGE TCHOBANOGLOUS, Ph.D., P.E.,<br />
University of California, Davis, California<br />
1:30 pm - 2:00 pm Design, Procurement, and Costs of. ...................... 29<br />
<strong>Membrane</strong> Bioreactor Systems<br />
STEPHEN M. LACY, P.E., DEE, MWH, Nevada<br />
2:00 pm - 2:20 pm Retrofit of an Existing .................................. 33<br />
Conventional Wastewater Treatment Plant with<br />
Zenon <strong>Membrane</strong> Bioreactor Technology<br />
DAVE N. COMMONS,<br />
City of Redlands Municipal Utilities Department, California<br />
2:20 pm - 2:40 pm Retrofit of an Existing .................................. 37<br />
Conventional Wastewater Treatment Plant<br />
with USFilter <strong>Membrane</strong> Bioreactor Technology<br />
JOHN HATCHER, Oconee County Utility Department, Georgia<br />
2:40 pm - 3:20 pm <strong>Membrane</strong> Bioreactor Applications: A Global Perspective .... 39<br />
SIMON J. JUDD, Ph.D., Cranfield University, England<br />
3:20 pm - 3:45 pm Panel Discussion<br />
3:45 pm - 4:00 pm Break<br />
Session 4: Innovative Applications and Future Outlook of the Technology<br />
Moderated by R. RHODES TRUSSELL, Ph.D., P.E., DEE<br />
Trussell Technologies, Inc., California<br />
4:00 pm - 4:30 pm <strong>Membrane</strong> Aeration, Biofilms, ........................... 43<br />
and <strong>Membrane</strong> <strong>Bioreactors</strong><br />
MICHAEL J. SEMMENS, Ph.D., P.E.,<br />
University of Minnesota, Minnesota<br />
4:30 pm - 4:50 pm Future Outlook on <strong>Membrane</strong> Bioreactor Technology ....... 45<br />
SIMON J. JUDD, Ph.D., Cranfield University, England<br />
4:50 pm - 5:15 pm Panel Discussion<br />
5:15 pm <strong>Short</strong> <strong>Course</strong> on <strong>Membrane</strong> <strong>Bioreactors</strong> Adjourns<br />
viii
THURSDAY, MARCH 23, 2006 ~ FIELD TRIPS<br />
8:30 am - 11:30 am Field Trips<br />
Those who are attending field trips must turn in field trip passes prior to bus departure. Please check in<br />
at the Foyer of the California Ball Room at least 30 minutes prior to departure.<br />
Field Trip Option A:<br />
MICROFILTRATION AT THE ORANGE COUNTY WATER DISTRICT<br />
The Groundwater Replenishment System Phase One plant is a 5-million gallon per day (mgd)<br />
advanced water treatment facility that contains three major processes: microfiltration, reverse<br />
osmosis, and advanced oxidation. The microfiltration<br />
process consists of a 6-mgd USFilter<br />
CMF-S submersible system. This process is a<br />
smaller-scale version of the 86-mgd microfiltration<br />
facility currently under construction at<br />
the same site. Driving time from the hotel to<br />
the Orange County <strong>Water</strong> District in<br />
Fountain Valley, California, is approximately<br />
20 minutes.<br />
Field Trip Option B:<br />
MEMBRANE BIOREACTOR AT THE CORONA DEPARTMENT OF WATER AND POWER<br />
Wastewater Treatment Plant 3 at the Corona Department of <strong>Water</strong> and Power was<br />
commissioned in 2001 to treat 1.1-mgd raw wastewater to Title 22 standards for recycling<br />
purposes. Currently, about 0.4 mgd of recycled water is<br />
produced, which is used to irrigate a nearby golf course<br />
and will soon irrigate surrounding schools and parks.<br />
The foundation for Plant 3 is the ZenoGem Process, a<br />
technology designed by Zenon that consists of a<br />
suspended growth biological reactor integrated with a<br />
microfiltration membrane system. Driving time from<br />
the hotel to the Corona Department of <strong>Water</strong> and Power<br />
in Corona, California, is approximately 35 minutes.<br />
Photos courtesy of the Orange County <strong>Water</strong> District,<br />
and the Corona Department of <strong>Water</strong> and Power<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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<strong>Abstracts</strong><br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
xi
xii
Session 1: Introduction<br />
<strong>Membrane</strong> <strong>Bioreactors</strong> and<br />
the Future of Wastewater Treatment<br />
R. RHODES TRUSSELL, PH.D., P.E., DEE<br />
Trussell Technologies, Inc.<br />
Pasadena, California<br />
Adecade ago, membrane bioreactors (MBRs) weren’t even on our radar screen. Today,<br />
MBRs are the process of choice for small-scale reuse projects with demands for high<br />
water quality. Projects are popping up everywhere. Soon, MBRs will change the way we think<br />
about treatment for reuse, opening a new era of decentralized treatment. In the very longterm,<br />
just as membrane filtration will replace granular media filtration, MBRs will replace<br />
conventional biological processes that depend on gravity sedimentation or granular media<br />
filtration for solids separation.<br />
What is the appeal of the MBR? What are some of the limits of the process? How is our<br />
thinking about MBRs changing, and how will it change in the future? What problems must<br />
we solve for MBRs to reach their full potential? What can MBRs do to help us meet future<br />
regulations?<br />
The most obvious appeal of the MBR is that it produces an excellent effluent quality. The<br />
compactness of the MBR is another important element in its appeal. Finally, the MBR has<br />
great potential for automation. Important to both the design engineer and operator, the MBR<br />
eliminates the need for good sludge settleability as a central requirement. Effluent quality is<br />
less sensitive to operations, and precise control of the sludge residence time (SRT)/mixed<br />
liquor suspended solids (MLSS)/food to microorganisms (F:M) ratio is not as important.<br />
Finally, the MBR puts much greater distance between reclamation and the risk of microbial<br />
disease. Pathogens are not just reduced by a highly selective chemical or photochemical<br />
reaction, they are rejected by size exclusion. The MBR also makes longer SRTs feasible in a<br />
compact space, resulting in less biomass to waste, the removal of a broader variety of resistant<br />
compounds, and a more biostable effluent with a lower oxidant demand. Finally, the MBR<br />
produces an effluent that is immediately suitable for reverse osmosis treatment, should that be<br />
a requirement.<br />
In today’s world, there are two kinds of issues that we face in making decision about the<br />
deployment of MBRs:<br />
Type I Issues — Issues that must be resolved to improve reliability, cost, and/or<br />
performance.<br />
Type II Issues — Issues that are inherent to the process and must be understood by<br />
designers and operators of successful MBR projects.<br />
Correspondence should be addressed to:<br />
R. Rhodes Trussell, Ph.D., P.E., DEE<br />
President<br />
Trussell Technologies, Inc.<br />
232 North Lake Avenue, Suite 300<br />
Pasadena, CA 91101-1862 USA<br />
Phone: (626) 486-0560 • Email: rhodes.trussell@trusselltech.com<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
1
Examples of Type I issues are: (a) understanding the upper limits of the MLSS that the<br />
process can handle and how the reactor configuration affects this, (b) understanding the lower<br />
limits of SRT and hydraulic residence time (HRT), (c) the optimization of air scouring and<br />
energy consumption, (d) membrane cleaning, (e) design and operational practices that will<br />
extend membrane life, and (f) designing and operating the MBR process to optimize sludge<br />
filterability.<br />
Examples of Type II issues are the design and operation requirements imposed by the impact<br />
that fouling can have on hydraulic performance, by MBR’s limited ability to handle peaking,<br />
and on MBRs by reduced oxygen transfer at high MLSS.<br />
To date, most MBR installations have been small enough that it has basically been possible to<br />
ignore the biology. This will not do in the future. The future belongs to those who take full<br />
advantage of all that we have learned about the behavior of this complex biological system and<br />
integrate it with the unique capabilities and limitations of MBRs. Some examples of problems<br />
that must be addressed include:<br />
• The management of organisms associated with foaming.<br />
• The management of the biological system to produce a sludge that is easily<br />
filtered and dewatered.<br />
• The full integration of what we know about nutrient removal with the MBR<br />
process.<br />
In the meantime, there are places where MBR is attractive today, even for the conservative<br />
engineer. MBR is most appealing when its small footprint, ease of automation, and excellent<br />
effluent quality are all requirements. It is also most appealing when flow peaking can be<br />
easily addressed. Reuse projects that scalp the flow from nearby sewers are one of the more<br />
obvious examples. Moreover, MBR has the potential to rearrange our thinking about reuse.<br />
There are limits to the idea of pumping treated wastewater up into and throughout a<br />
community in purple pipe. MBR creates the potential for decentralized reuse systems with<br />
treatment systems located closer to the point of application and smaller, less-intrusive purple<br />
infrastructure.<br />
R. RHODES TRUSSELL, Ph.D., P.E., DEE, is recognized worldwide as an authority<br />
in methods and criteria for water quality and in the development of advanced<br />
processes for treating water or wastewater to achieve the highest standards. A Civil<br />
and Corrosion Engineer with 35 years of experience, he has worked on the process<br />
design for dozens of treatment plants ranging in size from 1 to 900 million gallons per<br />
day in capacity. At present, he is President of Trussell Technologies, Inc., an<br />
environmental engineering firm that focuses on the quality and treatment of water<br />
and wastewater. He is also active on numerous boards and committees, such as<br />
serving as Chair of the <strong>Water</strong> Science and Technology Board for the <strong>National</strong> Academies. Just recently,<br />
he retired from the U.S. Environmental Protection Agency’s Science Advisory Board after 17 years of<br />
service. Trussell received a B.S. in Civil Engineering and both an M.S. and Ph.D. in Sanitary<br />
Engineering from the University of California, Berkeley.<br />
2
Session 1: Introduction<br />
Biological Process Principles<br />
GEORGE TCHOBANOGLOUS, PH.D., P.E.<br />
University of California, Davis<br />
Davis, California<br />
With proper analysis and environmental control, almost all wastewaters containing<br />
biodegradable constituents can be treated biologically. Therefore, it is essential that the<br />
environmental engineer understand the characteristics of each biological process to ensure<br />
that the proper environment is produced and controlled effectively. The overall objectives of<br />
the biological treatment of domestic wastewater are to:<br />
• Transform (i.e., oxidize) dissolved and particulate biodegradable constituents into<br />
acceptable end-products.<br />
• Capture and incorporate suspended and nonsettleable colloidal solids into a biological<br />
floc or biofilm.<br />
• Transform or remove nutrients, such as nitrogen and phosphorus.<br />
• More recently, to remove specific trace constituents and compounds.<br />
For industrial wastewater, the objective is to remove or reduce the concentration of organic<br />
and inorganic compounds. Because some of the constituents and compounds found in<br />
industrial wastewater are toxic to microorganisms, pretreatment may be required before<br />
industrial wastewater can be discharged to a municipal collection system. For agricultural<br />
irrigation runoff, the objective is to remove nutrients (specifically nitrogen and phosphorus),<br />
pesticides, and trace constituents that are capable of affecting the aquatic environment.<br />
The principal biological processes used for wastewater treatment can be divided into three<br />
main categories: suspended growth, attached growth (or biofilm), and combined suspended and<br />
attached growth processes. The successful design and operation of the biological processes<br />
requires an understanding of the:<br />
• Types of microorganisms involved.<br />
• Specific reactions that they perform.<br />
• Environmental factors that affect their performance.<br />
• Nutritional needs of microorganisms.<br />
• Microorganism reaction kinetics.<br />
These subjects are reviewed in light of process developments that have occurred over the past<br />
century.<br />
Correspondence should be addressed to:<br />
George Tchobanoglous, Ph.D., P.E.<br />
Professor Emeritus of Civil and Environmental Engineering<br />
University of California, Davis<br />
662 Diego Place<br />
Davis, CA 95616 USA<br />
Phone: (530) 756-5747 • Email: gtchobanoglous@ucdavis.edu<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
3
4<br />
For over 35 years, wastewater expert GEORGE TCHOBANOGLOUS, PH.D., P.E.,<br />
has taught courses on water and wastewater treatment and solid waste management<br />
at the University of California, Davis, where he is Professor Emeritus in the Department<br />
of Civil and Environmental Engineering. He has authored or coauthored over<br />
350 publications, including 13 textbooks and five engineering reference books.<br />
Tchobanoglous has been past President of the Association of Environmental<br />
Engineering and Science Professors and currently serves as a national and international<br />
consultant to both government agencies and private concerns. Among his<br />
honors, he received the Athalie Richardson Irvine Clarke Prize from the <strong>National</strong> <strong>Water</strong> Research<br />
Institute in 2003 and was inducted to the <strong>National</strong> Academy of Engineers in 2004. In 2005, he<br />
received an Honorary Doctor of Engineering degree from the Colorado School of Mines.<br />
Tchobanoglous received a B.S. in Civil Engineering from the University of the Pacific, an M.S. in<br />
Sanitary Engineering from the University of California, Berkeley, and a Ph.D. in Environmental<br />
Engineering from Stanford University.
Session 2: Fundamentals and Applications<br />
<strong>Membrane</strong> Bioreactor Process Fundamentals<br />
SIMON J. JUDD, PH.D.<br />
Cranfield University<br />
Bedfordshire, United Kingdom<br />
Introduction<br />
The use of microfiltration (MF) or ultrafiltration (UF) membranes in biological wastewater<br />
treatment has been well documented and extensively reviewed. <strong>Membrane</strong> filtration<br />
produces a high-quality, clarified, and disinfected permeate product. It also permits absolute<br />
control of solids retention time (SRT) and, thus, correspondingly, control of the mixed liquor<br />
suspended solids (MLSS) concentration. This both reduces the required reactor size and<br />
promotes the development of specific nitrifying bacteria, thereby enhancing ammonia removal,<br />
as well as producing less sludge.<br />
However, as with almost all other membrane processes, the production rate of membrane<br />
bioreactors (MBRs) is ultimately limited by membrane fouling. Fouling arises from the<br />
accumulation of solute, colloidal, and particulate species on or within the membrane, leading<br />
to a deterioration in membrane permeability. This phenomenon has led to the development<br />
of the low-fouling submerged configuration, first introduced 15 years ago, as opposed to<br />
sidestream systems, wherein the membrane is immersed in the bioreactor rather than fitted<br />
external to it (Figure 1). Submerged systems tend to allow greater hydraulic efficiencies,<br />
reflected in greater permeabilities, due to their operation at substantially lower fluxes than<br />
sidestream systems (Table 1), since fouling tends to increase with increasing flux.<br />
Out<br />
(membrane fouling)<br />
Feed<br />
(Screens)<br />
Bioreactor<br />
(Activity + Nature)<br />
Air<br />
(Energy)<br />
Sludge Waste<br />
(Quantity and Quality)<br />
Figure 1.<br />
Elements of a membrane bioreactor.<br />
Correspondence should be addressed to:<br />
Simon J. Judd, Ph.D.<br />
Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />
Building 61<br />
Cranfield University<br />
Bedfordshire MK43 0AL United Kingdom<br />
Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
5
Table 1. Summary of <strong>Membrane</strong> Bioreactor Process Conditions for Sewage Treatment<br />
Mitsubushi<br />
Orelis or<br />
Parameter Kubota Rayon Zenon Wehrle<br />
<strong>Membrane</strong> Geometry FS HF HF MT<br />
Process Configuration Submerged Submerged Submerged Side-stream<br />
Mean Air Velocity (m/s) 0.05 0.03 0.1 –<br />
Mean Liquid Velocity (m/s) 0.5* – – 1-3<br />
TMP (bar) 0.05-0.15 0.1-0.5 0.1-0.5 2-5<br />
Flux (LMH) ~25 ~15 ~25 70-100<br />
FS = Flat sheet. HF = Hollow fiber. MT = Multitube. LMH = Liters per cubic meter per hour.<br />
TMP= Transmembrane pressure. m/s = Meters per second. *As quoted by supplier.<br />
Fouling<br />
Fouling is a particularly acute problem in the case of MBRs, since the membrane is challenged<br />
with highly contaminated liquors having total solids concentrations of 20 grams per liter (g/L) or<br />
more arising from concentrated biomass. A second limitation, clogging – which refers to the<br />
filling of the membrane interstices with solids – is generally of less significance, but must still<br />
be suppressed for successful operation. There are a number of elements of a submerged MBR<br />
system (see Figure 1), all contributing to varying degrees of fouling and clogging, and their<br />
interrelationship is complex (Figure 2).<br />
In considering fouling and its causes and implications, the various elements of the system<br />
(see Figure 1) can be discussed in turn. Firstly, there are the feed characteristics. Various<br />
biochemical transformations in the bioreactor convert the organic matter in the feed into largely<br />
EPS<br />
• Free<br />
• Bound<br />
Feed Characteristics<br />
Biomass Characteristics<br />
Floc Characteristics<br />
• Size<br />
• Structure<br />
Bulk Characteristics<br />
• Viscosity/Rheology<br />
• Hydrophobicity<br />
Operation<br />
Retention Time<br />
• Hydraulic<br />
• Solids<br />
Hydraulics<br />
• Flux<br />
• TMP<br />
Reversible<br />
Fouling<br />
Irreversible<br />
Clogging<br />
<strong>Membrane</strong><br />
Channels<br />
Aerator<br />
Ports<br />
Cleaning<br />
• Physical<br />
• Chemical<br />
<strong>Membrane</strong> Module Characteristics<br />
Pore<br />
• Size<br />
• Shape<br />
Surface Characteristics<br />
• Porosity<br />
• Charge/Hydrophobicity<br />
Configuration<br />
• Geometry<br />
• Dimensions<br />
Aeration<br />
• Design (Port Size)<br />
• Mean Flow Rate<br />
• Pulse Rate<br />
Figure 2. Inter-relationships between membrane bioreactor parameters and fouling.<br />
6
mineralized products, principally carbon dioxide and nitrate. In doing so, a variety of materials<br />
are released from the biomass in the reactor, which are collectively referred to as extracellular<br />
polymeric substances (EPS) and which contain a number of components that can foul the<br />
membrane to various extents. The relative and overall concentrations of the various components<br />
are determined both by feed characteristics and operational facets of the system and, in<br />
particular, by microbial speciation. Other foulants originate directly from unbiodegraded<br />
components of the feedwater, particularly for feeds of low biodegrability.<br />
Secondly, there is the actual process design and configuration of the MBR process, which in<br />
turn affects the key operator parameter values chosen. Submerged MBRs operate at lower<br />
fluxes and, as a result, lower transmembrane pressure (TMP) values (and so permeabilities)<br />
than the sidestream configuration. Therefore, they are inherently higher in energy efficiency,<br />
manifested as the specific energy demand in kilowatt-hour per cubic meter (kWh/m 3 )<br />
permeate product. The configuration of the membrane module — principally, the membrane<br />
element geometry (planar or cylindrical), material physical properties (pore size, tortuosity,<br />
hydrophobicity, and surface porosity), and chemistry (polymeric or ceramic) — can also<br />
influence fouling. Although there are now a number of proprietary MBR technologies in the<br />
marketplace, the majority of them are based either on a flat sheet (FS) membrane<br />
configuration or on hollow fibers (HF).<br />
Thirdly, the operation of the MBR can profoundly impact fouling. There are two components<br />
of MBR operation: the membrane and the bioreactor. The bioreactor component (as with a<br />
conventional activated sludge process) is controlled by the relative values of the retention of<br />
solids and liquid (i.e., the solids [SRT] and hydraulic [HRT] retention times). Increasing the<br />
SRT and decreasing the HRT leads to higher levels of suspended solids (usually referred to as<br />
mixed liquor suspended solids [MLSS]) in the bioreactor, which increases the risk of clogging<br />
in both the membrane interstices and aerator ports. However, the impact of retention times<br />
on fouling is normally not significant in sewage treatment provided the MLSS is kept within a<br />
range of values in which fouling and foaming are suppressed (which tends to prevail at low<br />
MLSS values of around 4 to 6 g/L) and clogging is avoided by operating below a threshold<br />
MLSS value (which depends largely upon the membrane configuration). The main<br />
determinants for fouling control, however, relate directly to the membrane itself.<br />
Fouling Control<br />
In submerged MBRs, generally only three strategies are available for limiting fouling with<br />
regards to operation: reducing the flux, increasing aeration, or employing physical or chemical<br />
cleaning. Coarse bubble aeration produces scouring action at the surface of the membrane,<br />
which limits the build-up of foulant material. Lowering the flux reduces the rate at which<br />
foulants arrive at the membrane. However, both these modifications have cost implications,<br />
since a reduced flux implies a greater membrane area requirement and energy demand<br />
increases roughly linearly with increasing air flow rate. Cleaning demands downtime, and<br />
more rigorous cleaning using chemicals exerts chemical demand and produces chemical waste.<br />
A good operation of submerged MBR systems is based on obtaining the appropriate balance<br />
between operational flux, aeration, and cleaning. It follows that good MBR design is associated<br />
with maximizing the impact of aeration (in terms of reducing fouling) and facilitating<br />
cleaning with minimal downtime and chemicals consumption, as well as providing a high<br />
membrane area at low cost so as to permit a low flux.<br />
The constraints imposed by the challenging environment in which the membranes operate<br />
have meant that the municipal wastewater treatment MBR market is dominated by just two<br />
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<strong>Membrane</strong> <strong>Bioreactors</strong><br />
7
designs: the HF membrane-based product (Zenon) and the FS (Kubota). Much debate exists<br />
as to the relative merits offered by these two designs. The flat plate configuration tends to run<br />
at slightly higher permeabilities (flux per unit TMP) and is simpler in operation. On the other<br />
hand, unlike the HF, it cannot be backflushed. Both systems appear to maintain reasonable<br />
fluxes by applying relaxation – intermittent physical cleaning attained simply by closing the<br />
permeate valve and allowing air to scour the membrane surface. Both Kubota and Zenon have<br />
also recently developed design modifications for increasing efficiency. In the case of Kubota,<br />
this is achieved by stacking the membrane modules (already employed by Mitsubishi Rayon in<br />
its MBRs based on its Sterapore HF membrane). Zenon has introduced intermittent aeration,<br />
which effectively halves the specific energy demand associated with aeration, the main<br />
operating cost component.<br />
Technologies<br />
There are an increasing number of commercial MBR technologies, many of which are listed in<br />
Tables 2 and 3. It appears that almost all immersed MBRs are either rectangular FS or HF,<br />
and that most sidestream MBR technologies are multi-tubes (MT). The exceptions to these<br />
general observations appear to be:<br />
a. The Orelis Pleaide FS membrane used for sidestream treatment.<br />
b. The Polymem and Ultraflo sidestream HF systems.<br />
c. The hexagonal/octagonal rotating immersed Huber FS membrane.<br />
d) The Millenniumpore MT membrane, which has been used as an immersed module,<br />
as well as for air-lift sidestream.<br />
Table 2. Commercial Technologies<br />
Process Configuration<br />
Immersed<br />
Sidestream<br />
FS Colloide Novasep-Orelis<br />
Brightwater<br />
Huber*<br />
ITRI NWF<br />
Kubota<br />
Microdyn Nadir<br />
Toray<br />
<strong>Membrane</strong><br />
Configuration<br />
HF Asahi-kasie Polymem<br />
Han-S Environmental<br />
Ultraflo<br />
ITT<br />
Koch/Puron<br />
Kolon<br />
Mitsubishi Rayon<br />
Motimo<br />
Siemens/USF-Memcor<br />
Zenon<br />
MT Millenniumpore Berghof**<br />
Millenniumpore<br />
Norit-Xflow**<br />
*Rotating membrane.<br />
**MT membrane products used by process suppliers such as Aquabio, Dynatec, Triqua, and Wehrle.<br />
8
Table 3. Commercial <strong>Membrane</strong> Product Specifications<br />
<strong>Membrane</strong> Pore Specific Propietary Name,<br />
Supplier (Configuration, Size Surface <strong>Membrane</strong>,<br />
Material) (µm) Area (m -1 ) or Module<br />
Berghof MT, PES 0.08 110 HyPerm-AE<br />
or PVDF 0.12 Hyperflux<br />
Brightwater FS, PES 0.08 110 Membright<br />
Toray FS, PVDF 0.08 130 Toray<br />
Kubota FS, PE 0.4 150 Kubota<br />
Colloide FS, PES 0.04 160 Sub Snake<br />
Huber FS, PES 0.038 160 VRM<br />
Millenniumpore MT, PES 0.1 180 Millenniumpore<br />
Koch HF, PES 0.05 260 Puron<br />
Zenon HF, PVDF 0.04 300 ZW500C-D<br />
Norit-Stork MT, PVDF 0.038 320 F4385<br />
290 F5385<br />
Mitsubishi Rayon HF, PE 0.4 425 SUR<br />
HF, PVDF 0.4 333 SADF<br />
USF-Memcor HF, PVDF 0.04 600-700 B10R, B30R<br />
Asahi-kasie HF, PVDF 0.1 710 Microza<br />
Polymem HF, PS 0.08 800 WW120<br />
Motimo HF, PVDF 0.1-0.2 1100 Flat Plat<br />
Moreover, almost all HF MBR membrane products currently on the market are verticallymounted<br />
and polyvinylidene difluoride (PVDF)-based, the exceptions being the Koch-Puron<br />
membrane (which is polyethersulphone [PES]), the Polymem polysulfone (PS) membrane,<br />
and the Mitsubishi Rayon SUR module (which is polyethylene [PE] material and also<br />
horizontally oriented). All HF products are in the coarse UF/tight MF region of selectivity,<br />
having pore sizes predominantly between 0.03 and 0.4 micrometers (µm), and all such<br />
vertically-mounted systems are between 0.7 and 2.5 millimeters (mm) in external diameter.<br />
Distinctions in HF MBR systems can be found mainly in the use of membrane reinforcement<br />
(essential for those HF elements designed to provide significant lateral movement) and,<br />
perhaps most crucially, the air-to-membrane contact.<br />
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10<br />
PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />
University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />
1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />
all biomass separation membrane bioreactor (MBR) programs conducted within the<br />
School and has been Principal or Co-Investigator on three major UK research<br />
council-sponsored programs dedicated to MBRs with respect to in-building water<br />
recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />
also serves as Chairman of the Project Steering Committee of the multi-centered<br />
EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />
Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />
2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />
Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.
Session 2: Fundamentals and Applications<br />
Commercially Available<br />
<strong>Membrane</strong> Bioreactor Systems<br />
JAMES F. DECAROLIS<br />
MWH<br />
San Diego, California<br />
ZAKIR HIRANI<br />
MWH<br />
San Diego, California<br />
SAMER S. ADHAM, PH.D.<br />
MWH<br />
Pasadena, California<br />
NEIL TRAN, P.E.<br />
City of San Diego<br />
San Diego, California<br />
STEVE LAGOS<br />
City of San Diego<br />
San Diego, California<br />
Introduction<br />
The following paper provides a detailed description of four commercially available<br />
membrane bioreactor (MBR) systems currently established in the municipal wastewater<br />
treatment/water reclamation market in the United States. These systems are supplied by<br />
Zenon Environmental, Inc., USFilter, Ionics/Mitsubishi Rayon Corporation, and Enviroquip, Inc./<br />
Kubota Corporation. Each of these suppliers has full-scale MBRs currently operating in the<br />
United States, and their systems are approved by the California Department of Health<br />
Services (CDHS) to meet Title 22 water recycling criteria. Details of each system are based<br />
on knowledge gained during hands-on pilot testing performed by the project team along with<br />
information provided by the manufacturers. The paper will also describe four newly developed<br />
MBR systems currently entering the United States market. These suppliers include Koch<br />
<strong>Membrane</strong> Systems (KMS), Kruger, Parkson Corporation, and Huber, Inc. The project team<br />
is currently evaluating the ability of these new technologies to meet Title 22 recycling criteria<br />
under grant funding provided by the United States Department of Interior, Bureau of<br />
Correspondence should be addressed to:<br />
James F. DeCarolis<br />
MWH Americas, Inc.<br />
Aqua 2030 Research Center<br />
North City <strong>Water</strong> Reclamation Plant<br />
4949 Eastgate Mall<br />
San Diego, CA 92121 USA<br />
Phone: (858) 824-6067 • Email: jdecarolis@sandiego.gov<br />
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11
Reclamation. Lastly, the paper discusses MBR pilot-testing considerations based on nearly a<br />
decade of MBR research performed by the project team at the Aqua 2030 Research Center<br />
located in San Diego, California.<br />
Commercially Available <strong>Membrane</strong> Bioreactor Systems<br />
(Established in the United States)<br />
Zenon <strong>Membrane</strong> Bioreactor System<br />
The Zenon MBR system uses polyvinylidene fluoride (PVDF) ultrafiltration (UF) reinforced<br />
hollow fiber membranes (nominal pore size = 0.04 micron [µm]). Individual membrane<br />
elements are configured into membrane cassettes that are typically submerged directly into a<br />
designated membrane tank in direct contact with mixed liquor suspended solids (MLSS). The<br />
commercial designation of the membrane module currently used in the Zenon MBR system is<br />
ZW 500d, which has superseded previous generation modules offered by Zenon, including the<br />
ZW 500a and ZW 500c. Benefits of the<br />
ZW 500d configuration over its predecessors<br />
include a higher membrane packing density<br />
and lower air scouring requirements (Benedek<br />
and Cote, 2003). A photograph of a ZW 500d<br />
cassette is provided in Figure 1. Each cassette<br />
used in full-scale applications is typically<br />
designed to contain up to 48 individual<br />
membrane elements. Coarse bubble air is<br />
introduced from the bottom of the cassette to<br />
scour the surface of the membranes. This<br />
prevents solids from accumulating on the<br />
membrane surface, which could result in<br />
increased transmembrane pressure (TMP). A<br />
unique feature of the Zenon MBR system is<br />
the intermittent application of membrane air<br />
scour, which reduces energy consumption<br />
Figure 1. Photograph of Zenon 500d membrane<br />
cassette (Zenon, 2005).<br />
USFilter <strong>Membrane</strong> Bioreactor System<br />
The USFilter MBR system utilizes microfiltration (MF) hollow fiber PVDF membranes<br />
(nominal pore size of 0.08 µm) that are submerged in a separate membrane tank. The<br />
commercial designation of the original membranes used in USFilter’s MBR systems is B10R.<br />
Though still used in MBR package plants (
A unique feature of the USFilter MBR system is that it incorporates MemJet technology,<br />
which includes the injection of both air and mixed liquor at the bottom of the membrane<br />
modules. This operation causes the membranes to be scoured and fluidized and prevents<br />
particulate matter from accumulating on the membrane surface.<br />
Ionics/Mitsubishi Rayon <strong>Membrane</strong> Bioreactor System<br />
The Ionics/Mitsubishi Rayon MBR system uses<br />
polyethylene MF hollow fiber membranes (nominal<br />
pore size of 0.4 µm) that are submerged directly<br />
in an aeration basin. The commercial designation<br />
for the membranes is Sterapore HF. Though<br />
classified as MF, the membranes are characterized<br />
with a tight pore size distribution (absolute pore<br />
size= 0.5 µm). As shown in Figure 3, each<br />
membrane cassette contains individual hollow<br />
fibers membranes configured horizontally to make<br />
up an element. Each membrane cassette contains<br />
50 of the 1-square meter (m 2 ) Mitsubishi<br />
Sterapore HF MF membranes, for a total<br />
membrane area of 100 m 2 (1,076 ft 2 ). Air is<br />
supplied at the bottom of the tank for scour and Figure 3. Mitsubishi Sterapore HF membrane<br />
cassette.<br />
biological process. During filtration, vacuum<br />
pressure is applied, causing water to permeate through the membrane from the top and bottom.<br />
Kubota <strong>Membrane</strong> Bioreactor System<br />
The Kubota MBR system contains flat sheet, chlorinated polyethylene MF membranes (nominal<br />
pore = 0.4 µm) that are submerged directly in an aeration basin. The commercial designation<br />
of the flat sheet membrane cartridge is Type 510. Each cartridge is 1 m (H) x 0.49 m (W) x<br />
6 millimeters (mm) thick, and contains a membrane surface area of 0.8 m 2 . A photograph of<br />
the Type 510 membrane cartridge is provided in<br />
Figure 4. Each cartridge contains a support<br />
plate, spacer, permeate nozzle, and membrane<br />
layer on each side. Recently (2005), Kubota<br />
introduced a Type 515 membrane cartridge<br />
primarily for applications of 2 mgd or greater.<br />
The Type 515 cartridges are larger in dimension<br />
than Type 510 cartridges, resulting in increased<br />
membrane area per cassette. The Type 510<br />
cassette contains up to 150 individual cartridges<br />
(spaced 7 mm apart) and is equipped with a<br />
permeate manifold. During filtration, permeate<br />
water flows out of the cartridges through the<br />
permeate nozzle and into collection tubes that<br />
Figure 4. Kubota Type 510 membrane cassette.<br />
feed into the permeate manifold. A unique<br />
feature of the Kubota MBR system is that can be designed as a single or double deck (DD)<br />
configuration. The DD systems contain both upper and lower membrane cassettes. The<br />
lower cassettes are equipped with a coarse air bubble diffuser and provide structural support<br />
to the upper casts. This DD configuration offers several benefits (van der Roest et al, 2002),<br />
including the reduction of 1) the membrane footprint, 2) the biological volume consumed by<br />
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13
the membrane system, and 3) air consumption used for membrane cleaning. The DD also<br />
yields a more controllable biological process and reduces the possibility of short circuiting.<br />
Newly Developed <strong>Membrane</strong> Bioreactor Systems<br />
Koch <strong>Membrane</strong> Systems <strong>Membrane</strong> Bioreactor System<br />
The KMS membrane bioreactor uses PURON ® hollow fiber UF membranes (nominal pore<br />
size = 0.05 µm) that are made of polyethersulfone (PES) and casted onto a braided support.<br />
The hollow fiber membranes are configured in bundles to form membrane modules and are<br />
submerged in a designated membrane tank. A unique feature of the KMS MBR is that each<br />
membrane is sealed at the top and potted only at the lower end. This design allows the nonpotted<br />
ends to move freely in the MLSS, which eliminates the possibility of clogging. An air<br />
nozzle is located in the center of each bundle to provide membrane air scour. A standard<br />
module contains nine membrane bundles for a total membrane area of 30 m 2 . The PURON<br />
hollow fiber module is shown in Figure 5.<br />
Figure 5. PURON membrane module (Koch <strong>Membrane</strong> Systems, 2005).<br />
Huber <strong>Membrane</strong> Bioreactor System<br />
The Huber MBR system uses flat sheet UF membranes (nominal pore size= 0.038 µm)<br />
submerged in a designated membrane tank. A unique feature of the Huber MBR system is<br />
that the membranes are supported on a Vacuum Rotation <strong>Membrane</strong> (VRM ® ) unit, which<br />
consists of individual rotating VRM plate membranes installed around a stationary hollow<br />
shaft. Two centrally arranged air tubes<br />
introduce scouring air into the interspaces<br />
between the plates. Permeate<br />
is drawn from the each plate via<br />
permeate tubes that collect permeate<br />
to a common pipe. These horizontal<br />
pipes meet at a center manifold, from<br />
which the permeate exits the system.<br />
The constant rotation (1.8 revolutions<br />
per minute [RPM]) of the VRM unit<br />
allows the membrane plates to be air<br />
scoured alternatively by just two<br />
centrally placed air tubes, thereby Figure 6. Huber VRM unit (plan view).<br />
14
educing the scouring air requirements. Energy efficiency is maintained by using only a<br />
2−horsepower motor for the rotation of the VRM.<br />
The VRM membranes are configured in plates (3-m 2 filter surface area per plate) that contain<br />
permeate channels, spacers, and permeate discharge nozzles. A VRM module is comprised of<br />
four such plates; modules (when arranged circularly) form a membrane element. Huber MBR<br />
membrane elements are offered in two sizes: VRM 20 (containing six modules) and VRM 30<br />
(containing eight modules). Standard VRM 20 systems are designed with a minimum of 10<br />
and maximum of 50 elements, while standard VRM 30 systems are designed with a minimum<br />
of 20 and maximum of 60 elements. A photograph of a VRM 20 unit mounted on the VRM<br />
drive is provided in Figure 6.<br />
Kruger <strong>Membrane</strong> Bioreactor System<br />
Kruger MBR system uses flat-sheet PVDF UF<br />
membranes (nominal pore size of 0.08 µm)<br />
submerged in a designated membrane tank.<br />
<strong>Membrane</strong>s are supported on a polyolefin nonwoven<br />
material and Acrylonitrile Butadiene<br />
Styrene (ABS) plate. Each module contains<br />
100 flat-sheet membrane elements, with a total<br />
membrane area of 1,500 ft 2 . A photograph of the<br />
flat sheet module is provided in Figure 7. A<br />
unique feature of the Kruger MBR system is that<br />
the membrane is characterized with a tight pore<br />
size distribution (0.03 µm), allowing the fluid to<br />
Figure 7. Flat sheet module (Kruger, 2005).<br />
be equally distributed along the membrane surface<br />
during filtration (Kruger, 2005). It also allows the cleaning chemicals to be evenly distributed<br />
during maintenance cleaning, making cleaning more effective.<br />
Parkson Dynalift <strong>Membrane</strong> Bioreactor System<br />
The Parkson Dynalift MBR contains X-Flow ® PVDF tubular<br />
UF membranes with a nominal pore size of 0.03 µm. A unique<br />
feature of the Parkson MBR system is that the membranes are<br />
configured in modules and are external to the biological process.<br />
These tubular membranes provide a wide-channel, non-clogging<br />
design and, according to the manufacturer, can be operated at<br />
high MLSS levels of up to 15,000 milligrams per liter (mg/L).<br />
To eliminate high pumping energies, membranes are placed in a<br />
vertical orientation and MLSS is kept suspended inside the<br />
module using air-lift assisted cross-flow pumping. A photograph<br />
of the X-Flow membranes is provided in Figure 8.<br />
Aqua 2030 <strong>Membrane</strong> Bioreactor Research Program<br />
Figure 8. Parkson Corporation’s<br />
X-Flow membrane<br />
(Parkson, 2005)<br />
For nearly a decade, MWH and the City of San Diego in California have been researching<br />
MBR technology and its application for water reuse at the Aqua 2030 Research Center.<br />
The majority of this research was made possible under funding provided by the United States<br />
Department of Interior, Bureau of Reclamation, and was conducted in multiple phases from<br />
1997 to the present. Phase I (Adham and Gagliardo, 1998) included an extensive literature<br />
search on MBR technology and identified major MBR suppliers in the field. In addition, the<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
15
project team implemented a worldwide survey of full-scale MBR applications for domestic<br />
wastewater treatment and developed rough cost estimates for the technology. Information<br />
gathered during the survey included operational characteristics such as capacity, MLSS<br />
concentrations, food-to-microorganism ratio, permeate flux, solids retention time (SRT), and<br />
hydraulic retention time (HRT), along with performance in terms of particulate, organic,<br />
nutrient, and microbial contaminant removal.<br />
Phase II testing (Adham et al., 2000) included the operation and evaluation of two pilot-scale<br />
MBRs (Zenon and Mitsubishi) over a 1-year period. The purpose of testing was to evaluate<br />
the performance of these systems during the treatment of municipal wastewater and to<br />
establish baseline operating conditions. Towards the end of the pilot-testing period, the<br />
project team worked with CDHS to establish criteria for MBR systems to gain Title 22<br />
approval. Based on these criteria, further testing of the Zenon and Mitsubishi systems was<br />
done in 2001 under funding provided by the <strong>National</strong> <strong>Water</strong> Research Institute (Adham et al.,<br />
2001a and 2001b). Results from this testing, along with those acquired during the<br />
1-year operating period, were submitted to CDHS in September 2001. <strong>Short</strong>ly after, the two<br />
systems were granted conditional approval to meet Title 22 water recycling criteria.<br />
In June 2002, the project team embarked on Phase III (Adham and DeCarolis, 2004), which<br />
included the evaluation of four MBR pilot units (USFilter Corporation/Jet Tech Products Group;<br />
Zenon Environmental, Inc.; Ionics/Mitsubishi Rayon Corporation; and Enviroquip Inc./<br />
Kubota Corporation). Pilot testing of these systems was conducted over a 16-month period on<br />
raw and advanced primary effluent to evaluate MBR performance and to determine the<br />
suitability of MBR effluent as a feed to reverse osmosis units. Data generated during this<br />
study demonstrated the ability of the Kubota and USFilter MBR systems to meet Title 22<br />
<strong>Water</strong> Recycling Criteria, and both were granted approval in 2002/2003 (California<br />
Department of Health Services, 2005). In addition, it was shown that MBR systems could<br />
successfully operate on advanced primary treated wastewater containing coagulant and<br />
polymer residual.<br />
Recently, the project team has begun Phase IV (U.S. Department of Interior, Bureau of<br />
Reclamation, 2005) of the MBR program. The purpose of this ongoing project is to evaluate<br />
four newly developed MBR systems entering the municipal wastewater market in the United<br />
States. These include systems from Koch <strong>Membrane</strong> Systems (Wilmington, Massachusetts),<br />
Parkson Corporation (Fort Lauderdale, Florida), Huber Technology, Inc. (Huntersville, North<br />
Carolina), and Kruger (Cary, North Carolina). Each of these systems has been designed with<br />
innovative features aimed to optimize operational performance and efficiency. As part of<br />
testing, each system will be evaluated to meet Title 22 requirements, which (upon approval)<br />
would double the number of approved systems available to the water reclamation industry.<br />
Based on the research program described above, the project team has identified several<br />
important factors to consider when pilot testing MBR systems for water reuse applications.<br />
These include:<br />
• <strong>Water</strong> Quality Goals (total nitrogen, phosphorus, establish a water quality sampling plan).<br />
• Selecting a Supplier(s) (system configuration, customer support, suppliers experience,<br />
capacity of full-scale potential plant, pilot rental fee).<br />
• Pilot Site (access to raw wastewater [20- to 40 gallons per minute]), access to sewer to<br />
dispose of waste, potable water supply for cleaning, adequate power supply available).<br />
16
• MBR Operating Conditions (flux, HRT, SRT, membrane cleaning frequency [maintenance<br />
and recovery cleans], backwash/relax frequency, recirculation rate for denitrification).<br />
• Special Considerations (pretreatment, operator requirements, duration of testing, post<br />
treatment requirements, operation and maintenance requirements, biological tank mixing<br />
requirements, redundancy and location of feed pumps, wasting, foaming control).<br />
Additional information regarding these considerations will be provided during the conference<br />
presentation.<br />
References<br />
Adham, S., and P. Gagliardo (1998). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Repurification – Phase I. Desalination<br />
Research and Development Program Report No. 34, Project No. 1425-97-FC-81-30006J, United States<br />
Department of Interior, Bureau of Reclamation.<br />
Adham, S., R. Mirlo R. and P. Gagliardo (2000). <strong>Membrane</strong> <strong>Bioreactors</strong> for <strong>Water</strong> Reclamation – Phase II.<br />
Desalination Research and Development Program Report No. 60; Project No. 98-FC-81-0031, United<br />
States Department of Interior, Bureau of Reclamation.<br />
Adham, S., D. Askenaizer, R. Trussell, and P. Gagliardo (2001a). Assessing the Ability of the Zenon Zenogem<br />
<strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong> Research<br />
Institute.<br />
Adham, S., D. Askenaizer, R. Trussell, P. and Gagliardo (2001b). Assessing the Ability of the Zenon Mitsubishi<br />
Sterapore <strong>Membrane</strong> Bioreactor to Meet Existing <strong>Water</strong> Reuse Criteria, Final Report. <strong>National</strong> <strong>Water</strong><br />
Research Institute.<br />
Adham, S., and J. DeCarolis (2004). Optimization of Various MBR Systems for <strong>Water</strong> Reclamation – Phase III.<br />
Final Report Project No. 01-FC-81-0736, Bureau of Reclamation.<br />
Benedek, A., and P. Cote (2003). “Long-Term Experience with Hollow Fiber <strong>Membrane</strong> <strong>Bioreactors</strong>.”<br />
Proceedings, International Desalination Association Conference.<br />
California Department of Health Services (2005). Treatment Technology Report for Recycled <strong>Water</strong>. Department<br />
of Health Services, State of California Division of Drinking <strong>Water</strong> and Environmental Management.<br />
Koch <strong>Membrane</strong> Systems (2005). Technical literature on the KMS <strong>Membrane</strong> Bioreactor.<br />
Kruger (2005). Technical literature on the BIOSEP FS MBR Process.<br />
Parkson Corporation (2005). Website: http://www.parkson.com/Content.aspx?ntopicid=196.<br />
U.S. Department of Interior, Bureau of Reclamation (2005). Project agreement number 05 FC 81157,<br />
October.<br />
USFilter-Memcor (2005). Technical information and correspondence provided by Wenjun Liu, Director of<br />
Bioprocess Technology.<br />
van der Roest, H.F., D.P. Lawrence, and A.G.N. van Bentem, (2002) <strong>Membrane</strong> <strong>Bioreactors</strong> for Municipal<br />
Wastewater Treatment. IWA Publishing. STOWA.<br />
Zenon (2005). Website: http://www.zenon.com/mbr/design_considerations.shtml.<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
17
18<br />
JAMES F. DECAROLIS is a Senior Engineer with the Applied Research Department<br />
of the consulting firm, MWH, where he has been involved with several low-pressure<br />
membrane pilot studies conducted at the Aqua 2030 Research Center located in San<br />
Diego, California. In 2002/2003, he served as an on-site Project Engineer for a United<br />
States Department of Interior, Bureau of Reclamation (USBR) study evaluating the<br />
feasibility of using membrane bioreactor technology for water reclamation. In tandem<br />
with this project, he served as Project Engineer for a Desalination Research Innovation<br />
Partnership project to assess the ability of membrane bioreactors to serve as<br />
pretreatment to reverse osmosis during the treatment of municipal wastewater. Recently, he served as an<br />
on-site Engineer for an advanced water treatment pilot study conducted at North City <strong>Water</strong> Reclamation<br />
Plant, which evaluated ultrafiltration followed by reverse osmosis followed by ultraviolet plus peroxide for<br />
indirect potable reuse. He is currently serving as Project Manager for a USBR project evaluating newly<br />
developed membrane bioreactor systems for water reuse. DeCarolis received both a B.S. and M.S. in<br />
Environmental Engineering from the University of Central Florida.
Session 2: Fundamentals and Applications<br />
Evaluation of Conventional Activated Sludge<br />
Compared to <strong>Membrane</strong> <strong>Bioreactors</strong><br />
R. SHANE TRUSSELL, PH.D., P.E.<br />
Trussell Technologies, Inc.<br />
Pasadena, California<br />
Introduction<br />
Amembrane bioreactor (MBR) is a biological wastewater treatment process that<br />
implements a low-pressure membrane — microfiltration (MF) or ultrafiltration (UF) — to<br />
provide solid-liquid separation. Due to its compact footprint and consistent high-quality<br />
effluent, MBRs have captured the attention of the international wastewater treatment<br />
community. Although MBRs are ideal for water reclamation projects, the high-quality effluent<br />
and additional pathogen removal make MBRs a promising technology for discharging highquality,<br />
partially disinfected wastewater into streams and water bodies while using little or no<br />
chemical addition for disinfection. The purpose of this presentation is to compare and<br />
evaluate the principle differences, advantages, and disadvantages of the MBR process<br />
compared to a conventional, gravity-settled activated sludge.<br />
Brief Perspective on <strong>Membrane</strong> Bioreactor Development<br />
Biological processes have become the preferred process for municipal wastewater treatment.<br />
The activated sludge process (ASP) was pioneered by Arden and Lockett, who reused the<br />
flocculent solids from the previous aeration cycle to accelerate treatment rates (Ardern and<br />
Lockett, 1914). They called the accumulation of these flocculent solids activated sludge and<br />
found that treatment efficiency increased with higher proportions of activated sludge. The<br />
ASP has continued to develop over the past nine decades, and wastewater treatment plants<br />
are being designed today with an excellent understanding of how to optimize plant<br />
performance for organic, solids, and (more frequently) nutrient removal. However, regardless<br />
of how sophisticated and automated the plant design is, the solid-liquid separation is still<br />
performed by gravity sedimentation, and this means that operations staff must understand<br />
what influences sludge settleability to maintain good effluent quality.<br />
Relatively new to biological wastewater treatment is the MBR process. The development of<br />
the MBR process began in the United States with the direct filtration of activated sludge<br />
through a cloth filter along with the concept of coupling a membrane with activated sludge by<br />
Dorr-Oliver in Stamford, Connecticut (Stiefel and Washington, 1966). Thetford Systems in<br />
Ann Arbor, Michigan, commercialized the MBR process in the early 1970s. This new MBR<br />
process combined the three separate unit operations required in a conventional activated<br />
Correspondence should be addressed to:<br />
R. Shane Trussell, Ph.D., P.E.<br />
Principal<br />
Trussell Technologies, Inc.<br />
232 North Lake Avenue, Suite 300<br />
Pasadena, CA 91101 USA<br />
Phone: (626) 486-0560 • Email: shane.trussell@trusselltech.com<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
19
sludge treatment train into one compact process (Figure 1). The original MBR was an external<br />
MBR (EMBR) where mixed liquor was pumped from an aeration basin to the membrane<br />
module for solid-liquid separation. Yamamoto et al. (1989) developed the submerged MBR<br />
(SMBR) configuration where the membrane module was immersed directly in the mixed<br />
liquor and operated under suction pressure. It is the SMBR configuration that is currently<br />
dominating the municipal wastewater market and is the focus of this presentation, while the<br />
EMBR configuration is principally implemented on high-strength industrial wastewaters.<br />
Activated Sludge Process<br />
Aeration Basin<br />
Secondary Clarifier<br />
Microfiltration<br />
or Ultrafiltration<br />
Tertiary Treated<br />
Wastewater<br />
Primary Treated<br />
Wastewater<br />
(Equivalent to a<br />
1–3 mm screen)<br />
SMBR Process<br />
Aeration Basin<br />
Backwash <strong>Water</strong><br />
WASTE<br />
Tertiary Treated<br />
Wastewater<br />
WASTE<br />
Figure 1. Flow schemes for activated sludge and SMBR processes.<br />
Submerged <strong>Membrane</strong> <strong>Bioreactors</strong> Versus the Activated Sludge Process<br />
Process Design: The SMBR process uses activated sludge technology, combining it with membrane<br />
filtration, to expand the normal operating region. The SMBR process is not affected by the<br />
limitations associated with gravity sedimentation for solid-liquid separation, and this allows<br />
operation at much higher mixed liquor suspended solids (MLSS) concentrations. The peak<br />
MLSS concentration at which the SMBR process is not sustainable due to rapid membrane<br />
fouling is complex and is an area of ongoing research. However, today’s SMBR plants are<br />
optimally designed for MLSS concentrations between 8 and 12 grams per liter (g/L)<br />
(Trussell et al., 2005a; Trussell et al., 2005b).<br />
Higher MLSS concentrations translate into a longer solids retention time (SRT) for a given<br />
hydraulic retention time (HRT). This means that for the same aeration basin volume needed<br />
for the ASP, the SMBR process could double the design SRT. Longer SRTs provide a more<br />
stable biological process that results in wastewater effluent with low oxygen demand.<br />
Traditionally, SMBRs have been designed to operate at SRTs greater than 20 days (d), and<br />
some small facilities only waste once or twice per year. These longer SRTs ensure that<br />
adequate organics removal and complete nitrification can occur even in cold climates. Longer<br />
SRTs also bring about the possibility that specialized microorganisms could propagate and<br />
remove organics that are difficult and slow to degrade. Most importantly, longer SRTs reduce<br />
biological sludge production, reducing the mass of solids that needs to be disposed.<br />
20
Alternatively, higher MLSS concentrations can translate into reduced aeration basin volume.<br />
This means that for the same SRT as the ASP, the SMBR process could reduce aeration basin<br />
volume significantly, reducing HRT by close to one-half. However, this concept brings to light<br />
one of the principle disadvantages of the SMBR process compared to ASP: the SMBR process<br />
has a minimum SRT, where organics present in the mixed liquor have not been adequately<br />
stabilized, and these organics result in rapid membrane fouling (Trussell et al., 2005a;<br />
Trussell et al., 2004). Some manufacturers have set a minimum SRT at 12 d, while others are<br />
willing to work with design engineers to design at reduced SRTs (as low as 8 d). A common<br />
design for the minimum SRT is to determine where nitrification fails at the wastewater<br />
temperature and then apply a safety factor to ensure nitrification does not fail. The ASP is not<br />
restricted by the interaction of the membrane with the mixed liquor, and many wastewater<br />
treatment plants with ASP operate with low SRTs to inhibit nitrification. Operation at these<br />
low SRTs in SMBRs results in rapid membrane fouling, and SMBR manufacturers do not<br />
recommend plant designs at these low SRTs.<br />
Effluent <strong>Water</strong> Quality: The principle difference in effluent water quality between an SMBR<br />
and an ASP is the solid-liquid separation mechanism. Both SMBR and ASP depend principally<br />
on the biological process to oxidize influent organics and nitrogen. However, SMBR uses a<br />
membrane for solid-liquid separation to obtain a higher quality effluent. A well-operated ASP<br />
will contain suspended solids ≤ 10 milligrams per liter (mg/L), turbidity ≤ 10 nephelometric<br />
turbidity units (NTU), and 5-day biological oxygen demand (BOD 5 ) ≤ 10 mg/L, while the SMBR<br />
process typically contains suspended solids ≤ 2 mg/L (non-detect), turbidity ≤ 0.2 NTU, and<br />
BOD 5 ≤ 2 mg/L (non-detect) (Trussell et al., 2000). The SMBR is retaining all suspended<br />
solids in the reactor and, even though the degree of biological soluble organics removal is solely<br />
a function of the SRT, the SMBR process is removing additional soluble organics because of<br />
the direct filtration of activated sludge. Any organics larger than the membrane pores are<br />
being retained in the reactor, and organics even smaller than the membrane pores are being<br />
retained due to additional filtration provided by the cake layer that develops in these high<br />
solids environments. The SMBR process uses membrane separations to improve the biological<br />
process and produce an effluent that exceeds the effluent quality produced in ASP.<br />
Peak Flows: The principle advantage of the SMBR process — the membrane — is also its<br />
principle weakness when it comes to addressing peak flows. Although highly dependent on<br />
the specifics of the design (i.e., temperature, design flux, etc.), the SMBR process is typically<br />
limited to a peaking factor of 1.5 Q (flow rate), while the ASP is capable of sustaining much<br />
larger peak flows (>2.5 Q) for a longer period of time. This is because all of the peak flow<br />
must be filtered through the membranes to exit the facility in the SMBR, but the peak flow<br />
passes effortlessly over a weir in the ASP. The SMBR process is most economical when<br />
designed to operate at a constant flow rate, and large peak flows are best addressed with flow<br />
equalization in most facilities. As future membrane costs continue to decrease, the issue of<br />
peak flows in SMBRs will become less important because design engineers will be able to<br />
ensure that adequate membrane area is installed to sustain membrane performance during<br />
peak flow events.<br />
Mixed Liquor Properties: The mixed liquor properties are important because they affect how<br />
easily sludge can be filtered through membranes, settled, or dewatered. There is a significant<br />
difference in selective pressures between the ASP and SMBR, and one would expect<br />
significant differences in mixed liquor properties as well. While the ASP requires biology that<br />
flocculates and settles well to remain in the system, the SMBR process retains all biomass,<br />
even single cells, in the mixed liquor.<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
21
Although research is still needed to completely understand the differences and what<br />
influences these mixed liquor properties between the ASP and SMBR, Merlo et al. (2004) has<br />
revealed some key findings that highlight the differences in mixed liquor properties:<br />
1. SMBR sludge has a higher colloidal material content than ASP sludge.<br />
2. SMBR sludge has higher filament concentrations than ASP sludge.<br />
3. SMBR sludge particle size distribution (excluding colloidal) was controlled<br />
exclusively by the mixing intensity, G, and the same particle size distribution for an<br />
ASP was obtained for the SMBR.<br />
Merlo et al. (2004) provides explanations for these observed differences between SMBR and<br />
ASP mixed liquor properties:<br />
1. The SMBR mixed liquor has higher colloidal content because the membrane is<br />
retaining materials that would normally exit the ASP over the effluent weir.<br />
2. The SMBR mixed liquor has higher filament concentrations because the SMBR<br />
process is the perfect “trapping” environment. Unless designed with a surface<br />
wasting system, the SMBR process will retain all floating material, including<br />
filamentous microorganisms that float and may cause foam.<br />
3. A similar particle size distribution was obtained for an activated sludge reactor at high<br />
shear conditions (ASP) as that obtained for the SMBR (Figure 2).<br />
0.6<br />
0.5<br />
ASP<br />
Frequency<br />
0.4<br />
0.3<br />
0.2<br />
0.1<br />
0.0<br />
0.6<br />
0.5<br />
2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />
SMBR<br />
Frequency<br />
0.4<br />
0.3<br />
0.2<br />
0.1<br />
0.0<br />
2-4 4-6 6-8 8-10 10-20 20-40 40-100 100-200<br />
Characteristic Length, micron<br />
Figure 2. Particle size distribution for ASP and SMBR at 5-d mean cell residence time<br />
(Adapted from Merlo et al., 2004).<br />
22
Still Need to Flocculate: A key conclusion of the SMBR process is that despite all of its<br />
differences from the ASP and the membrane providing an absolute barrier, the mixed liquor<br />
properties still play a significant role in the successful application of the process. A mixed<br />
liquor that is well flocculated and contains a lower concentration of colloidal material is<br />
inherently easier to filter and has a lower fouling potential than a dispersed sludge with high<br />
concentrations of colloidal material (Fan et al., 2006). Recently, this topic has become the<br />
focus of the two leading SMBR manufacturers in the United States market. One gave a<br />
recent workshop in 2005 on “Biohydraulics” while another presented a plot of colloidal<br />
material versus time to filter and indicated the preferred region for good sludge filterability.<br />
As SMBR technology advances, engineers will need to understand mixed liquor properties and<br />
biological characteristics to design an optimized SMBR for a specific application.<br />
Conclusions<br />
Relatively new to the wastewater treatment industry, SMBRs offer significant advantages<br />
compared to conventional ASP: a more compact reactor, higher effluent quality, and higher<br />
MLSS concentrations. However, there are currently significant disadvantages of the SMBR<br />
process that design engineers need to be informed about: high MLSS limit, low SRT limit,<br />
and peak flow issues. Finally, although the SMBR process retains everything larger than the<br />
membrane pores, the mixed liquor properties are still important to minimize fouling and<br />
ensure successful plant operation. We need to change from the concept of sludge settleability<br />
to sludge filterability.<br />
References<br />
Ardern, E., and W.T. Lockett (1914). “Experiments on the oxidation of sewage without the aid of filters.”<br />
J. Soc. Chem. Indtr., (33): 523.<br />
Fan, F., Z. Hongde, and H. Husain (2006). “Identification of wastewater sludge characteristics to predict<br />
critical flux for membrane bioreactor processes.” <strong>Water</strong> Res., (40): 205.<br />
Merlo, R., R.S. Trussell, S.H. Hermanowicz, and D. Jenkins (2004). “Physical, chemical and biological<br />
properties of submerged membrane bioreactor and conventional activated sludges.” WEFTEC,<br />
New Orleans, LA.<br />
Stiefel, R.C., and D.R. Washington (1966). “Aeration of concentrated activated sludge.” Biotechnol. Bioeng.,<br />
(8): 379.<br />
Trussell, R.S., S. Adham, P. Gagliardo, R. Merlo, and R.R. Trussell (2000). “WERF: Application of membrane<br />
bioreactor (MBR) technology for wastewater treatment.” WEFTEC, Anaheim, CA.<br />
Trussell, R.S., S. Adham, and R.R. Trussell (2005a). “Process limits of municipal wastewater treatment with<br />
the submerged membrane bioreactor.” J. Environ. Eng.-ASCE, 131: 410.<br />
Trussell, R.S., R. Merlo, S.H. Hermanowicz, and D. Jenkins (2005b). “The effect of high mixed liquor<br />
suspended solids concentration, mixed liquor properties, and coarse bubble aeration flow rate on membrane<br />
permeability.” WEFTEC, Washington D.C.<br />
Trussell, R.S., R.P. Merlo, S. Hermanowicz, and D. Jenkins (2004). “The effect of organic loading on<br />
membrane fouling in a submerged membrane bioreactor treating municipal wastewater.” WEFTEC,<br />
New Orleans, LA.<br />
Yamamoto, K., M. Hiasa, T. Mahmood, and T. Matsuo (1989). “Direct solid-liquid separation using hollow fiber<br />
membrane in an activated-sludge aeration tank.” <strong>Water</strong> Sci. Technol., 21: 43.<br />
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<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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24<br />
R. SHANE TRUSSELL, Ph.D., P.E., is a Principal at Trussell Technologies, Inc., an<br />
environmental engineering firm that focuses on the quality and treatment of water<br />
and wastewater. He has 8 years of hands-on experience with processes for advanced<br />
wastewater treatment, particularly membrane filtration of secondary and tertiary<br />
effluents, membrane bioreactors, reverse osmosis, electrodialysis, ion exchange,<br />
granular activated carbon adsorption, and disinfection with ozone, chlorine, and<br />
chloramines. Where membrane bioreactors are concerned, he is a recognized<br />
authority, and he was the first to demonstrate that membrane fouling due to high<br />
solids concentrations and high food-to-microorganism ratios (low mean cell residence times) are fundamentally<br />
different in their nature. Trussel received a B.S. in Chemical Engineering from the University<br />
of California, Riverside, an M.S. in Environmental Engineering from the University of California, Los<br />
Angeles, and a Ph.D. in Environmental Engineering from the University of California, Berkeley.
Session 2: Fundamentals and Applications<br />
<strong>Membrane</strong> Bioreactor Global Knowledgebase<br />
GLEN T. DAIGGER, PH.D., P.E., BCEE, NAE<br />
CH2M HILL<br />
Englewood, Colorado<br />
Introduction<br />
In 2001, the <strong>Water</strong> Environment Research Foundation (WERF) authorized a project to<br />
assemble a global knowledgebase summarizing the applications and performance of membrane<br />
bioreactors (MBRs) (Daigger et al., 2001). Available on the WERF website to WERF<br />
subscribers or for purchase as a CD-ROM, the knowledgebase contains eight elements,<br />
including:<br />
1. Tutorials (PowerPoint-based) to provide an introduction and overview to parties<br />
potentially interested in MBRs for a particular application.<br />
2. Published Literature Database Search Tool, which is an extensive searchable database<br />
consisting of abstracts from relevant technical papers.<br />
3. Gray Literature Database Search Tool, which is an extensive searchable database<br />
providing listing and source information for relevant gray literature (pilot-plant reports,<br />
manufacturer’s information, etc).<br />
4. Installation Database Search Tool, which is a searchable database providing summary<br />
information for a wide range of MBR installations and more detailed information for<br />
selected examples of various types of installations.<br />
5. Decision Tool, which provides a set of questions and answers to help the website user<br />
determine whether MBRs are potentially applicable for a specific application (should<br />
they be interested in learning more!).<br />
6. Preliminary Sizing Tool, which is used to develop preliminary sizes for a particular<br />
application (used in conjunction with the Decision Tool).<br />
7. Installations Survey Tool, which allows owners of MBR installations to input data on their<br />
application to share with others.<br />
8. Links to Related Websites, which allow access to information on MBRs contained in<br />
other websites.<br />
The searchable database format was selected due to the rapid development of this technology<br />
and allows updates to be completed easily as needed.<br />
Correspondence should be addressed to:<br />
Glen T. Daigger, Ph.D., P.E., BCEE, NAE<br />
Senior Vice President and Chief Technology Officer<br />
CH2M HILL<br />
9191 South Jamaica Street<br />
Englewood, CO 80112 USA<br />
Phone: (720) 286-2542 • Email: gdaigger@ch2m.com<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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The website was initially completed and made available in 2002, then updated in 2004 due to<br />
the rapid development of the technology (Schwartz et al., 2006). Key observations associated<br />
with this knowledgebase are summarized below.<br />
Key Observations<br />
1. Several thousand MBR installations exist on a worldwide basis, with significant<br />
installations located on virtually every continent. A wide range of wastewaters are<br />
treated in MBRs, including municipal and a diverse range of industrial wastewaters,<br />
along with other applications such as landfill leachate.<br />
2. The vast majority of existing MBR applications are small, reflecting historical approaches<br />
to the application of MBR technology (Crawford et al., 2000). However, MBRs are<br />
increasingly being applied to larger plants (Crawford et al., 2005; Daigger et al., 2002).<br />
3. Technical analysis indicates that MBR technology is ready for a wide range of<br />
applications in both developed and developing countries (Daigger et al., 2005), including<br />
advanced wastewater treatment, water reclamation and reuse, pretreatment prior to<br />
reverse osmosis for water reclamation, grey water recycling, and the treatment of highly<br />
polluted environmental waters (Fleischer et al., 2005).<br />
4. MBR design and application has progressed through “three generations,” beginning with<br />
small installations intended to reliably produce high-quality effluent with minimal<br />
attention, to modest sized facilities capable of not only removing biodegradable organic<br />
matter, but also removing nutrients (Crawford et al., 2000). Fourth generation plants<br />
are now being implemented that resemble larger, conventional wastewater treatment<br />
facilities, but are using MBRs rather than conventional biological processes (Daigger and<br />
Crawford, 2005; Daigger et al., 2002).<br />
5. As the size and complexity of MBR facilities have increased, the method of procuring<br />
MBR equipment for these facilities has evolved from one similar to that used to procure<br />
“package” wastewater treatment plants to that used to procure conventional wastewater<br />
treatment equipment (Crawford et al., 2002). As a consequence, owners (and their<br />
engineers) are taking increased responsibility for the overall design of the wastewater<br />
treatment plant and are more carefully defining the responsibilities and scope of supply<br />
of the membrane suppliers.<br />
6. The performance characteristics of MBRs are increasingly well understood (Schwartz et<br />
al., 2006), resulting in increased consensus on the design of these facilities (Daigger and<br />
Crawford, 2005; Daigger et al., 2002).<br />
A result of these trends is that MBRs are becoming an accepted approach to wastewater<br />
treatment that can be successfully applied to a wide range of applications and facility sizes.<br />
The features of MBRs lead some to conclude that they can play an important role in delivering<br />
needed water to even the most disadvantaged worldwide, thereby playing an important role in<br />
meeting Millennium Development goals (DiGiano et al., 2004).<br />
26
References<br />
Crawford, G., G. Daigger, J. Fisher, S. Blair, and R. Lewis (2005). “Parallel Operation of Large <strong>Membrane</strong><br />
<strong>Bioreactors</strong> at Traverse City.” Proceedings of the <strong>Water</strong> Environment Federation 78 th Annual Conference &<br />
Exposition, Washington DC, CD-ROM.<br />
Crawford, G., A. Fernandez, A. Shawwa, and G. Daigger (2002). “Competitive Bidding and Evaluation of<br />
<strong>Membrane</strong> Bioreactor Equipment – Three Large Plant Case Studies.” Proceedings of the <strong>Water</strong> Environment<br />
Federation 75 th Annual Conference & Exposition, Chicago, IL, CD-ROM.<br />
Crawford, G., D. Thompson, J. Lozier, G. Daigger, and E. Fleischer (2000). “<strong>Membrane</strong> <strong>Bioreactors</strong> – A<br />
Designer’s Perspective.” Proceedings of the <strong>Water</strong> Environment Federation 73 rd Annual Conference &<br />
Exposition on <strong>Water</strong> Quality and Wastewater Treatment, Anaheim, CA, CD-ROM.<br />
Daigger, G.T., B.E. Rittmann, S. Adham, and G. Andreottola (2005). “Are <strong>Membrane</strong> <strong>Bioreactors</strong> Ready for<br />
Widespread Application?” Environmental Science and Technology, 399A-406A.<br />
Daigger, G.T. and G.V. Crawford (2005). “Incorporation of Biological Nutrient Removal (BNR) Into <strong>Membrane</strong><br />
<strong>Bioreactors</strong> (MBRs).” Proceedings of the IWA Specialized Conference, Nutrient Management in Wastewater<br />
Treatment Processes and Recycle Streams, Krakow, Poland, 235.<br />
Daigger, G.T., G.V. Crawford, and J.C. Lozier 2002). “<strong>Membrane</strong> Bioreactor Practices and Applications in<br />
North America.” Proceedings of the First Leading Edge Drinking <strong>Water</strong> and Wastewater Treatment Technology<br />
Conference, International <strong>Water</strong> Association.<br />
Daigger, G.T., G. Crawford, A. Fernandez, J.C. Lozier, and E. Fleischer (2001). “WERF Project: Feasibility of<br />
<strong>Membrane</strong> Technology for Biological Wastewater Treatment – Identification of Issues and MBR Technology<br />
Assessment Tool.” Proceedings of the <strong>Water</strong> Environment Federation 74 th Annual Conference & Exposition,<br />
Atlanta, GA, CD-ROM.<br />
DiGiano, F.A., G. Andreottola, S. Adham, C. Buckley, P. Cornel, G.T. Daigger, A.G. Fane, N. Galil, J.G. Jacangelo,<br />
A. Pollice, B.E. Rittmann, A. Rozzi, T. Stephenson, and Z. Ujani (2004). “Safe <strong>Water</strong> for Everyone.”<br />
<strong>Water</strong> Environment and Technology, 31-35.<br />
Fleischer, E.J., T.A. Broderick, G.T. Daigger, A.D. Fonseca, R.D. Holbrook, and S.N. Murthy (2005).<br />
“Evaluation of <strong>Membrane</strong> Bioreactor Process Capabilities to Meet Stringent Effluent Nutrient Discharge<br />
Requirements.” <strong>Water</strong> Environment Research, (77): 162-178.<br />
Schwartz, A.E., B.E. Rittmann, G.V. Crawford, A.M. Klein, and G.T. Daigger (2006). “Critical Review on the<br />
Effects of Mixed Liquor Suspended Solids on <strong>Membrane</strong> Bioreactor Operation.” Separation Science and<br />
Technology, In Press.<br />
GLEN T. DAIGGER, Ph.D., P.E., BCEE, NAE, is a recognized expert in wastewater<br />
treatment, especially the use of biological processes. At present, he is a Senior Vice<br />
President and Chief Technology Officer for the international consulting engineering<br />
firm CH2M HILL, where he has been employed for over 23 years. Among his<br />
responsibilities, he oversees wastewater process engineering on both municipal and<br />
industrial wastewater treatment projects on a firmwide basis. He is also the first<br />
Technical Fellow for the firm, an honor recognizing the leadership that he provides<br />
for CH2M HILL and for the profession in the development and implementation of<br />
new wastewater treatment technology. From 1994 to 1996, Daigger also served as Professor and Chair<br />
of the Environmental Systems Engineering Department at Clemson University. In addition, he formerly<br />
served as Chair of the Board of Editorial Review of <strong>Water</strong> Environment Research and as Chair of the<br />
<strong>Water</strong> Environmental Federation Technical Practice Committee. He is currently Chair of the<br />
Committee Leadership Council. Daigger received a B.S. and M.S. in Civil Engineering and a Ph.D. in<br />
Environmental Engineering from Purdue University.<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
27
Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />
Design, Procurement, and Costs<br />
of <strong>Membrane</strong> Bioreactor Systems<br />
STEPHEN M. LACY, P.E., DEE<br />
MWH Americas, Inc.<br />
Las Vegas, Nevada<br />
The membrane bioreactor (MBR) has integrated microfiltration with activated sludge to<br />
create a space-efficient facility capable of producing high-quality water. Like any process,<br />
there are advantages and disadvantages to using MBRs. Because of rapid growth in the<br />
application of plant configurations, it is important to understand the design principles<br />
necessary to result in a successful installation. Since MBRs are used in both large and<br />
“end-of-pipe” facilities, understanding the limitations of the process and the proper sizing<br />
of components becomes critical to success.<br />
The MBR process can have the same features and performance of any advanced secondary or<br />
Biological Nutrient Removal (BNR) facility, combined with the flexibility and performance of<br />
membrane filtration. In general, the membrane portion functions as a solid-liquid separation<br />
process. The effluent from an MBR can be expected to outperform any traditional or<br />
conventional treatment system.<br />
Initially, MBRs were installed in small facilities to handle a wastewater flow from a small area,<br />
or as a scalping plant to supply reuse-quality water to an individual user. Today, MBRs are<br />
seeing an expanded use as “end-of-pipe” facilities and to supply clusters of reuse water users<br />
as remote reclamation facilities.<br />
In this presentation, we will discuss several important design concepts and suggest design<br />
parameters that will provide flexibility in the operation of facilities, including the ability to<br />
properly maintain components. We will also discuss a procurement process for the membrane<br />
system. Finally, we will look at some of the costing developed for scalping-type facilities.<br />
Design Considerations<br />
It is important to note that with an MBR, there is no other option for producing an effluent<br />
other than through the membranes. The configuration of an MBR is greatly impacted by<br />
whether the facility will be used as a scalping plant or “end-of-pipe” treatment plant.<br />
Understanding both 1) how the MBR is being applied and 2) the required components needed<br />
for reliable operation are critical to proper design. Several MBR design considerations that<br />
will be discussed during the presentation include:<br />
• Screening (which is critical).<br />
• Handling peak flows.<br />
Correspondence should be addressed to:<br />
Stephen M. Lacy, P.E., DEE<br />
MWH Americas, Inc.<br />
3014 West Charleston Boulevard<br />
Las Vegas, NV 89102 USA<br />
Phone: (702)878-8010 • Email: stephen.lacy@mwhglobal.com<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
29
• <strong>Membrane</strong> flux rate (which should be selected to allow flexibility).<br />
• Foam control.<br />
• Waste sludge handling.<br />
• Low demand at scalping plants.<br />
A typical layout of an MBR facility configured for full BNR treatment is shown in Figure 1.<br />
This presentation will discuss the configuration of return streams and how to gain some<br />
advantage from the air used to agitate the membranes and avoid negatively impacting the<br />
biological process.<br />
Solids Recirculating System<br />
Anoxic<br />
Zones<br />
Screened<br />
& Degritted<br />
Wastewater<br />
Anaerobic<br />
Zones<br />
OxicZones<br />
<strong>Membrane</strong><br />
Bays<br />
MLSS Recycle System<br />
Selectors Nitrification <strong>Membrane</strong>s<br />
Figure 1. MBR flow schematic.<br />
Procurement of <strong>Membrane</strong> Systems<br />
MBR systems that are commercially available today do not lend themselves to a common<br />
design arrangement, thereby requiring custom application of each manufacturer’s system.<br />
There are three general ways to proceed with the selection and procurement of an MBR system:<br />
• Sufficiently isolate the membrane system from the remainder of the process units so<br />
that the system is independent with minimal impact on the plant layout, allowing the<br />
design to proceed without specific details required of the membrane system.<br />
• Implement the project on an alternative delivery basis, allowing the design-builder to<br />
select and work with a membrane system supplier.<br />
• Procure the membrane system early in the project design so that the facility is<br />
configured around specific equipment.<br />
In this presentation, we will focus on the latter of the options.<br />
The early procurement of the membrane systems can shorten the project schedule by allowing<br />
both the designers to customize the design around the specific equipment being installed and<br />
the equipment supplier to commence manufacturing while design is underway. Commonly,<br />
this procurement is accomplished in a two-step process. The first is a qualification-based<br />
selection to create a short-list of manufacturers. These manufacturers are invited to furnish<br />
proposals for their equipment as part of the second step. Because the equipment is varied in<br />
configuration and operation, an evaluated bid process is used to review the proposals and the<br />
final selection of the supplier.<br />
30
Cost Analysis of <strong>Membrane</strong> Bioreactor Systems for <strong>Water</strong> Reclamation<br />
Cost estimates were developed for full-scale MBR reclamation (scalping) systems ranging from<br />
0.2 to 10 million gallons per day (mgd). These estimates included both capital and operational<br />
costs related to the MBR process and subsequent disinfection. The costs associated with the<br />
membrane portion of the MBR systems were developed from cost quotes from four leading<br />
MBR suppliers. All other costs, including headworks, biological process, and disinfection<br />
costs, were estimated from preliminary conceptual design. Results of the analysis indicate<br />
that the total costs ($/1000 gallons) for 1-mdg MBR water reclamation systems, designed<br />
to operate on raw wastewater, ranged from $1.81 to $2.24.<br />
STEPHEN M. LACY, P.E., DEE, has more than 30-years experience in all facets of<br />
water and wastewater projects, from development through construction. He is a<br />
Project Manager for MWH Americas, Inc., working with the wastewater technical<br />
group. Over the past several years, Lacy has been involved in the testing, evaluation,<br />
and conceptual design for clients who are considering membrane treatment of their<br />
wastewater. He has also looked at wastewater membranes in the membrane<br />
bioreactor process and ultrafiltration of secondary effluent using submerged and<br />
pressure membrane configurations. A member of the Nevada <strong>Water</strong> Environment<br />
Association, he is currently Co-Chairman of both the Professional Development and Government Affair<br />
Committees. Lacy received a B.S. in Civil Engineering and an M.E. in Sanitary Engineering from the<br />
University of Idaho.<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
31
Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />
Retrofit of an Existing Conventional Wastewater<br />
Treatment Plant with Zenon <strong>Membrane</strong><br />
Bioreactor Technology<br />
DAVE N. COMMONS<br />
City of Redlands Municipal Utilities Department<br />
Redlands, California<br />
On May 31, 2001, the State of California Waste Discharge Requirement (WDR) permit<br />
for the wastewater treatment facility of the Wastewater Division of the City of Redlands<br />
Municipal Utilities Department was modified from requiring a Total Inorganic Nitrogen (TIN)<br />
12-month average effluent limitation of 15 milligrams per liter (mg/L) to a new permit effluent<br />
compliance level of 10 mg/L. The wastewater treatment plant, as configured at that time,<br />
could not meet this new compliance limitation because of insufficient aeration basin capacity.<br />
Because California was experiencing energy shortages in 2001, the City of Redlands<br />
Wastewater Division was also asked to provide to the Mountain View Power Company (a<br />
division of the Southern California Edison Company) a reliable source of high-quality cooling<br />
water that was not only low in total suspended solids (TSS) and biochemical oxygen demands<br />
(BOD), but also had less than 5 mg/L of total phosphates.<br />
The Wastewater Division evaluated the capability of a step feed, multi-anoxic zone nitrification/<br />
denitrification treatment process modification with both pre-anoxic and post-anoxic zone<br />
configurations to the current treatment process to meet these nutrient requirements. It was<br />
determined that even thought both of these process modifications met the required effluent<br />
TIN limitation of 10 mg/L, neither would be able to meet the effluent TIN limitation on a<br />
sustained basis. It was also determined that the Division would not meet the total phosphates<br />
requirement of the power plant with the current plant configuration and treatment processes.<br />
After an extensive evaluation of the capabilities of conventional granular filtration technology<br />
versus membrane bioreactor (MBR) technology in different configurations, the City decided to<br />
upgrade 22.7 megaliters per day (ML/d) (6.0 million gallons per day [mgd]) of the Wastewater<br />
Division’s 35.96 ML/d (9.5 mgd) secondary-level activated sludge facility to a full tertiary-level<br />
treatment by using a dual-stage MBR facility. The dual-stage MBR configuration places the<br />
membrane cassettes in separate bioreactor tanks rather than within aeration basins. It was<br />
also decided that because the plant used anaerobic digestion for biosolids stabilization and<br />
because space was limited in the aeration basins for separate anaerobic zones, chemical<br />
precipitation using iron salts would be used for phosphate removal instead of using biological<br />
phosphorus removal. The iron salts were chosen over aluminum salts because ferrous chloride<br />
was already being used in the facility for hydrogen sulfide control in the anaerobic digesters.<br />
Correspondence should be addressed to:<br />
Dave N. Commons<br />
<strong>Water</strong> Operations Manager<br />
City of Redlands Municipal Utilities Department<br />
P.O. Box 3005<br />
35 Cajon Street, Suite 15A<br />
Redlands, CA 92373 USA<br />
Phone: (909) 798-7588 • Email: dcommons@cityofredlands.org<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
33
This presentation will give a description of the treatment technology evaluation that led to the<br />
decision to construct an MBR facility instead of using conventional granular filtration<br />
technology to meet California’s Title 22 requirements for reclaimed water usage. A detailed<br />
evaluation of the start-up problems will then follow. This will include dealing with such issues<br />
as a lower-than-expected aeration influent soluble BOD, which required evaluating long-term<br />
methanol addition to resolve the low soluble BOD issue. An extensive explanation of start-up<br />
procedures will then follow, which will include testing protocol, treatment methodology<br />
experimentation, and treatment evaluation results that were necessary for the Wastewater<br />
Division to bring this dual-stage MBR facility into compliance with the both the State of<br />
California WDR permit requirements and the needs of the electrical power generating facility.<br />
The final section of the presentation will deal with a discussion of long-term process problems,<br />
challenges, and recommendations that resulted from the start-up and operations of a full<br />
tertiary treatment level, dual-stage MBR wastewater reclamation facility.<br />
As more wastewater treatment facilities use MBR facilities to meet high-quality wastewater<br />
effluent criteria needed for water reclamation because of the technology’s ability to meet<br />
high-level criteria on a consistent, low-cost basis, it is importance to evaluate the operational<br />
problems and challenges that these plants present. This presentation will provide insights into<br />
both start-up and long-term operating process issues. Since this conference is being held in<br />
California, a discussion of the operational issues and problems of the largest membrane<br />
bioreactor facility in the State of California (at the time of this submission), where water<br />
reclamation issues are paramount, should be relevant to conference attendees.<br />
Further Reading<br />
Commons, D. (2002). Twenty Week Evaluation of the Multi-Anoxic Zones Nitrification/ Denitrification<br />
Treatment Process for Removing Low Level Total Inorganic Nitrogen at the City of Redlands, California<br />
Wastewater Treatment Facility, WEFTEC 2002, Chicago, IL.<br />
Commons, D., G. Beliew, S.S. Nedic, and J. Cumin (2005). “MBR Reduces Potable <strong>Water</strong> Use, Increases<br />
Revenue,” <strong>Water</strong>world, September, Volume 21, No. 9.<br />
Pearson, D. (2005). “New Dual-Stage MBR Technology Yields Higher Quality Effluent at Reduced Operating<br />
Costs,” Industrial <strong>Water</strong>world, March/ April, Volume 6, No. 2.<br />
U.S. Environmental Protection Agency (1987). Phosphorus Removal, EPA/625/1-87/001, Washington, D.C.<br />
U.S. Environmental Protection Agency (1993). Nitrogen Control, EPA/625/R-93/010, Washington, D.C.<br />
<strong>Water</strong> Environment Federation (1996). Operation of Municipal Wastewater Treatment Plants, Volume III, 5 th<br />
Edition, Alexandria, VA.<br />
<strong>Water</strong> Environment Federation (1998). Biological and Chemical Systems for Nutrient Removal, Special<br />
Publication, Alexandria, VA.<br />
34
DAVE N. COMMONS has over 25 years of experience with wastewater treatment<br />
and collection and over 18 years of experience in the water treatment and distribution<br />
field. At present, he is the <strong>Water</strong> Operations Manager for the City of Redlands<br />
Municipal Utilities Department, where he oversees all City water supply sources,<br />
water and wastewater treatment facilities, and potable water distribution and<br />
wastewater collection systems, among others. Prior to joining the City of Redlands,<br />
he was the <strong>Water</strong> Utilities Operations Manager for the City of Corona <strong>Water</strong> Utilities<br />
Department in California and Field Operations Division Manager for the Sarasota<br />
County Utilities Department in Florida. Commons received a B.A. in Divinity and Education from<br />
Antioch Baptist Bible College and a Masters degree in Divinity and Religious Education from<br />
Southwestern Baptist Theological Seminary. He also holds Grade V Wastewater Operator, Grade T5<br />
<strong>Water</strong> Operator, and D5 Distribution Operator certificates in the State of California, with equivalent<br />
wastewater certificates in both the States of Georgia and Florida.<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
35
Session 3: Case Studies – Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />
Retrofit of an Existing Conventional Wastewater<br />
Treatment Plant with USFilter <strong>Membrane</strong><br />
Bioreactor Technology<br />
JOHN HATCHER<br />
Oconee County Utility Department<br />
Watkinsville, Georgia<br />
In 2002, the Oconee County Utility Department (OCUD) sought to increase plant capacity<br />
at Calls Creek Wastewater Treatment Plant in Georgia. Different traditional treatment<br />
processes were looked at and weighed against the quality of the effluent that each produced.<br />
For the cost and quality of the system, membrane microfiltration emerged as the leading<br />
candidate. Traditional equipment would provide the quality of water needed to meet the<br />
present discharge permit, but may not have met it in the future. The quality of the water<br />
produced by membranes surpassed any other available technology for the price, and the<br />
decision was made to proceed in that direction.<br />
After deciding on the manufacturer, a pilot plant was provided by USFilter for evaluation and<br />
testing. The pilot plant passed all testing and met the effluent quality parameters that were<br />
needed. After completion of the pilot, OCUD moved forward with awarding the bid to<br />
USFilter to complete a design/build upgrade at Calls Creek.<br />
The construction process worked alongside the existing Orbal aeration basin and was<br />
integrated into it. Submersible pumps were installed in the center channel of the aeration<br />
tank, which pumped the mixed liquor into ultrafine wedge wire rotary screens. The screens<br />
removed all types of trash before the mixed liquor entered the membrane bioreactor (MBR)<br />
building for filtration. After filtration, the effluent was discharged to the existing ultraviolet<br />
system for disinfection before final discharge. The return activated sludge leaving the MBR<br />
was sent back to the aeration tank to begin the process all over again.<br />
The MBR system went online in April 2004 and has been in service since then. The system<br />
has provided high quality effluent and has allowed OCUD to look into the possibility of<br />
providing the treated effluent back to our customers as reuse water for irrigation.<br />
Correspondence should be addressed to:<br />
John Hatcher<br />
Wastewater Supervisor<br />
Oconee County Utility Department<br />
P..O Box 88<br />
Watkinsville, GA 30677 USA<br />
Phone: (706) 769-3963 • Email: callscreek@msn.com<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
37
38<br />
JOHN HATCHER is the Wastewater Supervisor for Oconee County Utility Department,<br />
which provides drinking water and sanitary sewer service to its customers within the<br />
service areas inside Oconee County, Georgia. As Wastewater Supervisor, he is<br />
responsible for the daily operation and compliance of a conventional wastewater<br />
treatment plant and a land-application wastewater plant. Recently, he won two<br />
awards from the Georgia <strong>Water</strong> and Pollution Control Association, one of which was<br />
for the Calls Creek Wastewater Treatment Plant, which discharges into the Calls<br />
Creek watershed. Hatcher received a B.S. in Environmental Health Science from<br />
the University of Georgia. He is also a licensed water and wastewater treatment plant operator in the<br />
State of Georgia.
Session 3: Case Studies - Real-World Issues with <strong>Membrane</strong> <strong>Bioreactors</strong><br />
<strong>Membrane</strong> Bioreactor Applications:<br />
A Global Perspective<br />
SIMON J. JUDD, PH.D.<br />
Cranfield University<br />
Bedfordshire, United Kingdom<br />
Pilot-Plant Studies<br />
Since membrane bioreactor (MBR) performance is highly dependent upon feedwater<br />
quality, a true comparison of the performance of different MBR technologies can only be<br />
achieved when they are tested against the same feedwater matrix. A number of comparative<br />
pilot trials have been conducted over the past 5 years, which permit a useful technology<br />
comparison (Table 1), albeit with certain caveats. The studies identified in Table 1 have all<br />
been conducted this millennium, and all employ at least one full-scale membrane module and<br />
at least three different technologies. Not all of these studies have been published, however.<br />
Table 1.<br />
Comparative Pilot-Plant Trials<br />
Reference<br />
Technology Adham Van der Tao Honolulu Lawrence Trento EAWAG<br />
Tested et al. Roest et al. et al.<br />
(2005) et al. (2005) (2005)<br />
(2002)<br />
Zenon X X X X X X<br />
Kubota X X X X X X<br />
Mitsubishi Rayon X X X X X<br />
Norit – X –<br />
Huber (X) X<br />
Memcor X X X<br />
Toray<br />
X<br />
Comparative Parameters<br />
To allow a comparison of disparate sets of data from various full-scale plants, normalization of<br />
the data is required. The most convenient parameters to use are flux (J, liters per cubic meter<br />
per hour [LMH]), permeability (K, LMH/bar), and specific aeration demand with respect to<br />
membrane area (SAD m , Nm 3 hr -1 m -2 or m hr -1 ) and permeate volume (SAD p , Nm 3 air per m 3<br />
permeate [i.e., unitless]). A comparison of such data for full- and pilot-scale plants is provided<br />
in Table 2.<br />
Correspondence should be addressed to:<br />
Simon J. Judd, Ph.D.<br />
Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />
Building 61<br />
Cranfield University<br />
Bedfordshire MK43 0AL United Kingdom<br />
Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
39
Table 2. Summary of Key Parameters<br />
Cap 1 Flux K SAD m<br />
2 SAD p<br />
2 MLSS Filt. cycle3 (min) Cleaning Cycle 4<br />
(MLD) (LMH) (LMH/bar) (Nm/h) (–) (g/L) on r or b Interval Type<br />
Zenon<br />
p 20 225 0.54 27 10-11<br />
p 35 225 0.54 15 10-11<br />
p 37.2 270 0.52 14 8-10 9.5 0.5b<br />
p 16 120 0.33 22 9 1b<br />
p 10 200 0.54 28 7 5 0.5b<br />
p 12.4 124 5 0.31 25 4-13 12 0.5b<br />
2* 18 95 1 56 15 10 0.75b 1w/6m mCIP/R<br />
48 18 144 0.29 16 8-10 10.5 1.5r 1w/15m mCIP/R<br />
0.15,i 12 71 0.65 54 10-15 10 0.5b 0.5w mCIP<br />
48 25 175 0.4 17 12 7 1 0.5m mCIA<br />
Mitsubishi Rayon<br />
p 7.5 200 0.33 52 9-12 1200 240r<br />
p 4.8 90 0.37 38 8 8 0.5b/1.5r<br />
0.38 10 30 0.65 65 12<br />
p 23 140 1 45 8-14 12 2r<br />
p 20 66 5 0.48 20 6-14 13 2r<br />
USF Memcor<br />
p 21.7 150 0.39 18 6-8<br />
p 21 182 0.2 17<br />
0.61 16 150 5 0.18 11<br />
Asahi-kasei<br />
0.9,i 16 80 0.24 15 Ind<br />
Koch Puron<br />
0.63 25 160 0.25 10 Mun 5 3w mCIP<br />
Kubota<br />
p 10.4 650 0.75 75 10-12 8 2r<br />
p 25 250 0.6 24 9-12 9 1r<br />
p 15 261 0.98 79 9 1r<br />
p 9.5 200 1.5 88 8 8 2r<br />
p 26 650 4 0.94 39 6-12 9 1r<br />
1.9 20 350 0.75 32 12-18 1380 60r 8-9m CIP<br />
13 33 330 1.06 32 8-12 1380 60r 6m CIP<br />
4.3 25 680 0.56 23 10-20 1-2 6m CIP<br />
Brightwater<br />
1.2 27 150 1.28 47 12-15 55 5r >18m CIP<br />
Toray<br />
0.53 25 208 0.54 22 6<br />
Huber<br />
0.11 24 250 0.35 22 Mun 9 1 none<br />
Colloide<br />
0.29 25 62.5 0.5 20 Mun 6 2 na<br />
1 Plant capacity or plant type (p = pilot plant); MLD = Megaliters per day.<br />
2 Specific aeration demand; Nm/h = Cubic namometers per hour air per cubic meters membrane.<br />
3 Filtration cycle (r = relaxation; b = backflush); on = Filtration period.<br />
4 Cleaning intervals (w = weeks; m = months).<br />
5 Maximum permeability.<br />
Intermittent aeration used for all Zenon plants other than *.<br />
CIP = Cleaning in place. mCIP = Maintenance cleaning in place.<br />
mCIP/R = Maintenance cleaning in place with relaxation. mCIA = Maintenance cleaning in air.<br />
40
It has generally been observed from lab-scale studies that attainable flux increases with increasing<br />
aeration rates due to increased scouring. This is manifested either as an increase in the<br />
critical or sustainable flux. In a full-scale plant, this would be expected to be manifested as an<br />
increase in sustainable net permeability with an increasing aeration rate. This, indeed, appears<br />
to be the case, with a general tendency for increasing permeability with increasing SAD m ,<br />
though the data is highly scattered (Figure 1). Some of this data scatter can be attributed to<br />
obvious outliers, namely either a plant operating under sub-optimal conditions and/or a very<br />
small unstaffed plant, where blowers are more likely to be oversized to maintain permeability<br />
and, therefore, limit maintenance. Sustainable permeability also changes according to<br />
clearning protocols and the nature of aeration (i.e., the specifications of the aerator itself and<br />
the mode of application [continuous or intermittent]). Although physical cleaning is, to some<br />
extent, accounted for by using net rather than gross flux in calculating permeability,<br />
maintenance cleaning with hypochlorite permits higher permeabilities to be sustained.<br />
800<br />
700<br />
600<br />
500<br />
400<br />
300<br />
200<br />
100<br />
✶<br />
▲<br />
❖<br />
♦<br />
✦<br />
✦ ❖<br />
❖ ✦<br />
✣ ▲<br />
▲●<br />
■<br />
✦<br />
✦<br />
✦ ❊<br />
■<br />
✦▲<br />
■<br />
■<br />
■<br />
■<br />
▲<br />
✦<br />
■<br />
✦ Zenon<br />
■ Kubota<br />
▲ M Rayon<br />
❖ USF<br />
✶ Huber<br />
● Colloide<br />
✣ Asahi-k<br />
♦ Puron<br />
✧ Brightwater<br />
❊ Toray<br />
✧<br />
■<br />
0<br />
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6<br />
SADm, NM^3/hr per m^2<br />
Figure 1. Operating permeability versus specific aeration demand for data in Table 2.<br />
If the more obvious outliers are ignored, then some general trends can be identified from<br />
the data:<br />
a) Flat sheet (FS) systems tend to operate at high permeabilities (generally >200 LMH/bar)<br />
and are associated with high aeration demands, both as SAD m and SAD p . No trend<br />
is evident in this data subset, though all but the highest (and probably non-optimal)<br />
SAD p values lie within the range 20 to 39.<br />
b) Hollow fiber (HF) systems tend to operate at lower permeabilities (generally<br />
Physical cleaning appears to be predominantly by relaxation rather than by backflushing.<br />
Pilot−plant data indicate that the downtime for physical cleaning accounts for between 4 and<br />
20 percent of the operating time, with no profound difference between the two configurations.<br />
On the other hand, maintenance cleaning every 3 to 4 days using relatively low concentrations<br />
of hypochlorite (250 to 500 milligrams per liter [mg/L]) is routinely employed for the Zenon<br />
technology, whereas chemical cleaning is limited to infrequent recovery cleans alone for<br />
FS systems. For both FS and HF systems, such cleans are generally applied at intervals of<br />
6 to 18 months (depending on the flux) and generally employ hypochlorite concentrations<br />
between 1,000 and 5,000 mg/L sodium hypochlorite (NaOCl). Both maintenance and<br />
recovery cleaning are either brief or infrequent enough to add little to the percentage<br />
downtime. For example, an overnight soak of 16 hours every 6 months amounts to less than<br />
0.25 percent in such cases. For Zenon plants, the maintenance cleaning cycle is complete<br />
within 10 minutes and is employed no more than three times a week, again amounting to less<br />
than 0.4-percent downtime. Thus, for the majority of the most recent plants, the ratio of the<br />
net-to gross flux is determined by a period of relaxation alone, and the most onerous impact of<br />
chemical cleaning is chemical usage and chemical waste discharge.<br />
PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />
University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />
1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />
all biomass separation membrane bioreactor (MBR) programs conducted within the<br />
School and has been Principal or Co-Investigator on three major UK research<br />
council-sponsored programs dedicated to MBRs with respect to in-building water<br />
recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />
also serves as Chairman of the Project Steering Committee of the multi-centered<br />
EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />
Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />
2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />
Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.<br />
42
Session 4: Innovative Applications and Future Outlook of the Technology<br />
<strong>Membrane</strong> Aeration, Biofilms,<br />
and <strong>Membrane</strong> <strong>Bioreactors</strong><br />
MICHAEL J. SEMMENS, PH.D., P.E.<br />
University of Minnesota<br />
Minneapolis, Minnesota<br />
The theory of membrane gas transfer has been studied and characterized in detail over the<br />
past 30 years. It is possible to accurately predict the gas transfer performance of<br />
membranes using numerous dimensionless correlations if the membrane area and operating<br />
conditions are known. <strong>Membrane</strong>s are now widely used for gas transfer in a variety of<br />
applications, including blood oxygenation, vacuum degassing, and pervaporation.<br />
Environmental applications of membrane gas transfer have been slower to develop because of<br />
problems with biofilm fouling of the membrane surface. If we are to design effective<br />
membrane gas transfer processes for water/wastewater treatment, we need to understand how<br />
these biofilms impact gas transfer. How do these biofilms behave? Is biofilm formation<br />
always a bad thing or are there advantages? This presentation will examine the influence of<br />
biofilms on the gas transfer performance of membranes and explore opportunities for novel<br />
applications in membrane bioreactors.<br />
PROFESSOR MICHAEL J. SEMMENS, P.E., is Professor in the Department of<br />
Civil and Mineral Engineering at the University of Minnesota, where he has taught<br />
since 1977. His research interests include the development of physical and chemical<br />
processes for water, wastewater, and waste treatment; processes to identify factors<br />
that limit mass transfer and the kinetics of separation; membrane bioreactors, module<br />
design, and membrane applications in water and wastewater treatment; and the use<br />
of membranes for controlled gas delivery in biologically active environments, such as<br />
groundwater and sediment remediation projects, and wastewater treatment.<br />
Semmens received a B.S. in Chemical Engineering from the Imperial College of Science and Technology<br />
in London, England, an M.S. in Environmental Engineering from Harvard University, and Ph.D. in<br />
Environmental Engineering from University College in London, England.<br />
Correspondence should be addressed to:<br />
Michael J. Semmens, Ph.D., P.E.<br />
Professor, Department of Civil Engineering<br />
University of Minnesota<br />
500 Pillsbury Drive SE<br />
Minneapolis, MN 55455 USA<br />
Phone: (612) 625-9857 • Email: semme001@umn.edu<br />
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Session 4: Innovative Applications and Future Outlook of the Technology<br />
Future Outlook on<br />
<strong>Membrane</strong> Bioreactor Technology<br />
SIMON J. JUDD, PH.D.<br />
Cranfield University<br />
Bedfordshire, United Kingdom<br />
Challenges<br />
Two areas having a direct bearing on the effective and efficient operation of membrane<br />
bioreactors (MBRs) are 1) cleaning and 2) dynamic effects. The cleaning of surfaces, as<br />
a subject for scientific investigation, pre-dates membrane process development since the<br />
fouling of heat exchangers, and the consequent loss of thermal efficiency has been an issue for<br />
many years. The fouling and cleaning of membranes relating to industrial process separations<br />
have also been the subject of research and development for over 20 years. Compared to this,<br />
the science of membrane cleaning in the context of MBRs is a young one — there have been a<br />
great number of investigations of MBR fouling, but much less on the appropriate chemicals<br />
and protocol for recovering permeability for irreversibly fouled membranes. Given the large<br />
number of parameters that determine the degree of permanent fouling and the candidate<br />
variable parameters that could determine cleaning efficacy, the scope of a rigorous study of<br />
cleaning is potentially extremely broad. Thus, it is not surprising that cleaning protocols have<br />
been developed in an ad hoc way through heuristic investigation.<br />
Dynamic effects exert the greatest influence on consistency in MBR performance, ultimately<br />
leading to equipment and/or consent failures, but have also been largely overlooked by the<br />
academic research community. Specifications for full-scale MBR installations are generally<br />
based on conservative estimates of hydraulic and organic (and or ammoniacal) loading.<br />
However, in reality, these parameters fluctuate significantly. Moreover, even more significant<br />
and potentially catastrophic deterioration in performance can arise through equipment<br />
malfunction and operator error. Such events can be expected to produce over short periods of<br />
time (Table 1):<br />
• Decreases in mixed liquor suspended solids (MLSS) concentration (either through<br />
the loss of solids by foaming or by dilution with feedwater).<br />
• Foaming problems, usually associated with the above.<br />
• Loss of aeration (through control equipment malfunction or aerator port clogging).<br />
• Loss of permeability (through the misapplication of backflush and cleaning<br />
protocols, hydraulic shocks, or contamination of the feed with some unexpected<br />
component).<br />
Correspondence should be addressed to:<br />
Simon J. Judd, Ph.D.<br />
Professor in <strong>Membrane</strong> Technology and Director of <strong>Water</strong> Sciences<br />
Building 61<br />
Cranfield University<br />
Bedfordshire MK43 0AL United Kingdom<br />
Phone: (+44) (0)1234 754173 • Email: s.j.judd@cranfield.ac.uk<br />
A <strong>Short</strong> <strong>Course</strong> on<br />
<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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Table 1. Key Dynamic Determinants and Their Impacts<br />
Determinants<br />
MLSS dilution<br />
Aeration loss<br />
Backflush/cleaning loss<br />
Hydraulic shock<br />
Saline intrusion<br />
Variables<br />
Dilution factor and rate of concentration increase<br />
Percentage and period of reduction<br />
Period of loss<br />
Rate and level of flow increase<br />
Ultimate concentration factor and rate of<br />
concentration decrease<br />
An example of feedwater constituent fluctuation is seawater intrusion. It has been recognized<br />
for some time that rapid changes in salinity can impact microbial physiology, increasing levels<br />
of organic matter (as chemical oxygen demand [COD] or biochemical oxygen demand [BOD])<br />
arising in activated sludge process (ASP) effluent and decreasing microbial activity. However,<br />
the phenomenon has not been investigated for MBRs, where such physiological changes might<br />
be expected to impact fouling. Further examples include fats, oils, and grease (FOGs) and<br />
bacteriological inhibitory substances, since the latter can then alter the system microbiology<br />
and, therefore, generate fouling.<br />
Outlook<br />
Despite the limitation imposed by fouling, the future of membrane bioreactors in municipal<br />
and industrial wastewater treatment seems assured. Valued at an estimated $216.6 million in<br />
2005, the global MBR market is rising at an average annual growth rate of 10.9 percent,<br />
significantly faster than the larger market for advanced wastewater treatment equipment and<br />
more rapidly than the markets for other types of membrane systems. It is expected to<br />
approach $363 million in 2010 (Hanft, 2006). The number of installations for both of the<br />
leading suppliers has undergone exponential growth since the first pilot trials of the submerged<br />
process in 1989 (Figure 1), driven by opportunities presented by increasingly stringent<br />
environmental legislation and by ever-decreasing process costs (Figure 2). Further<br />
incremental improvements can be expected as more is understood about the interrelationship<br />
between biomass characteristics, permanent fouling, and cleaning, and as membrane costs<br />
continue to be driven downwards. More significant “quantum leap” improvements are less<br />
easily envisioned, however, and it remains to be seen whether any profoundly original MBR<br />
products will arise from current research and development activity.<br />
References<br />
Hanft, S. (2006). <strong>Membrane</strong> <strong>Bioreactors</strong> in the Changing World <strong>Water</strong> Market. Business Communications<br />
Company, Report C-240.<br />
Kennedy, S., and C. Churchouse (2005). Progress in <strong>Membrane</strong> <strong>Bioreactors</strong>: New Advances, Experiences, and<br />
Applications of <strong>Membrane</strong> <strong>Bioreactors</strong> in the Treatment of Domestic and Industrial Wastewaters. Wakefield,<br />
United Kingdom.<br />
46
Kubota<br />
Zenon<br />
1500000<br />
1250000<br />
1000000<br />
750000<br />
500000<br />
250000<br />
0<br />
1995<br />
1996<br />
1997<br />
1998<br />
1999<br />
2000<br />
2001<br />
2002<br />
2003<br />
2004<br />
Figure 1. Cumulative installed capacity in cubic meters per day (m3/d) for Kubota and Zenon.<br />
Relative cost / m 3 at 100 l/s<br />
160<br />
140<br />
120<br />
100<br />
80<br />
60<br />
40<br />
@ 8640 m 3 /d<br />
Costs Projected in<br />
1999<br />
Rent and rates<br />
Sludge disposal<br />
Screenings<br />
<strong>Membrane</strong> replacement<br />
Chemicals<br />
Maintenance<br />
Power<br />
Amortised capital<br />
Actual Costs<br />
20<br />
0<br />
1992 1994 1995 1996 1998 2000 2002 2004 2005<br />
Year<br />
Figure 2. MBR process costs (Kubota) versus time (Kennedy and Churchouse, 2005).<br />
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<strong>Membrane</strong> <strong>Bioreactors</strong><br />
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48<br />
PROFESSOR SIMON JUDD is the Director of <strong>Water</strong> Sciences at Cranfield<br />
University. He has been on the staff at the School of <strong>Water</strong> Sciences since August<br />
1992, and occupies the Chair in <strong>Membrane</strong> Technology. Judd has managed almost<br />
all biomass separation membrane bioreactor (MBR) programs conducted within the<br />
School and has been Principal or Co-Investigator on three major UK research<br />
council-sponsored programs dedicated to MBRs with respect to in-building water<br />
recycling, sewage treatment, and contaminated groundwater/landfill leachate. He<br />
also serves as Chairman of the Project Steering Committee of the multi-centered<br />
EU-sponsored EUROMBRA project. In addition to publishing extensively in the research literature,<br />
Judd has co-authored two textbooks in membrane and MBR technology, with a third one due out in July<br />
2006. Judd received a B.Sc. in Chemistry from the University of Bath, M.Sc. in Electrochemical<br />
Science from Southampton University, and a Ph.D. in Filtration Science from Cranfield University.