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Surface and bulk passivation of multicrystalline silicon solar cells by ...

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53<br />

Figure 3.7 Measured Seff(Δn) dependence at the SiN X-passivated surfaces <strong>of</strong> three 1.5 (Ωcm<br />

FZ p-Si wafers. The SiN X films were fabricated <strong>by</strong> three different PECVD<br />

methods: low-frequency(100 kHz) direct PECVD, high-frequency (13.56<br />

MHz) direct PECVD, <strong>and</strong> remote PECVD [56].<br />

3.2.2.2 Seff dependence on resistivity. Figure3.8 shows the calculated S SA as a function <strong>of</strong><br />

the injection level Μ in the quasi neutral <strong>bulk</strong> for different wafer resistivities (1, 2, 3 <strong>and</strong><br />

5 Ω-cm) <strong>and</strong> p- <strong>and</strong> n-type <strong>silicon</strong>, respectively.<br />

For model calculations, a typical set <strong>of</strong> parameters for the dielectric-Si interface<br />

has been used. An interface state density, Dt <strong>of</strong> 5x10 10 cm 2 eV-1<br />

, a positive fixed charge<br />

Qf<strong>of</strong> 1x1011m-2 <strong>and</strong> capture cross-sections for electrons <strong>and</strong> holes <strong>of</strong> 10 14 <strong>and</strong> 10 -16cm2,<br />

respectively, were taken from measurements reported in the literature [83]. Furthermore,<br />

an assumption was made that the interface states were uniformly distributed across the<br />

b<strong>and</strong>gap <strong>and</strong> that all states below midgap were donor-like states whereas all states above

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