18.04.2014 Views

Dielectric Aluminum Oxides: Nano-Structural Features and ...

Dielectric Aluminum Oxides: Nano-Structural Features and ...

Dielectric Aluminum Oxides: Nano-Structural Features and ...

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

cut edges, air-electrolyte interfaces <strong>and</strong> other damaged areas of aluminum capacitor anodes.<br />

The formation of these plumes has been shown to depend upon voltage, current density <strong>and</strong><br />

the time of application of the current <strong>and</strong> represents a parasitic reaction in parallel with the<br />

desirable formation of barrier oxide on these raw aluminum surfaces.<br />

ACKNOWLEDGEMENTS<br />

The authors would like to thank Hitachi – HTA for their assistance in the FIB <strong>and</strong> TEM<br />

work for this study. In addition, the encouragement <strong>and</strong> appreciation of the management of<br />

St. Jude Medical, Inc. has made this work possible.<br />

REFERENCES<br />

1 ANODIC OXIDE FILMS; L. Young; Academic Press, New York, 1961, Chapter 17, pg.<br />

211.<br />

2 “Very high volt oxide formation of aluminum for electrolytic capacitors.”; T.F. Strange <strong>and</strong><br />

T.R.Marshall; U.S. Patent No. 6299752 B1, 2001.<br />

3<br />

“Improved <strong>Dielectric</strong> Properties fo Anodic <strong>Aluminum</strong> Oxide Films by Soft/Hard Two-<br />

Step Electrolytic Anodization”,; J.R. Dickey, J.L. Davidson, <strong>and</strong> Y. Tzeng,<br />

J.Electrochem.Soc., V136, N6, 1989, p.1772.<br />

4<br />

“Method of Manufacturing <strong>Aluminum</strong> Foil for <strong>Aluminum</strong> Electrolytic Capacitor.”; K.<br />

Yoshida, et.al.; U.S. Patent No. 6,096,184, Aug. 1, 2000.<br />

5 “The Barrier <strong>Aluminum</strong> Oxide Films in <strong>Aluminum</strong> Electrolytic Capacitors.”; Uchi, Kanno,<br />

& Alwitt; Ext. Abstracts Electrochem. Soc., V1999, N2.<br />

6 “Defects in Crystalline Anodic Alumina.”; J.L. Stevens <strong>and</strong> J.S. Shaffer; J. Electrochem.<br />

Soc., V133, N6, June 1986, p. 1160.<br />

7 “The Effects of Electrolyte Composition on the Deformation Characteristics of Wet<br />

<strong>Aluminum</strong> ICD Capacitors.”; J.L. Stevens, T.R. Marshall, A.C. Geiculescu, C.R. Feger, &<br />

T.F. Strange; Symp. Proc. CARTS 2006 – Orl<strong>and</strong>o, FL, Mar. 30-Apr.6, 2006, pg. 269.<br />

8 “Anodic Oxidation of <strong>Aluminum</strong> in Organic Electrolytes under Nearly Anhydrous<br />

Conditions.”; M. Ue, A. Hitoshi, <strong>and</strong> S. Mari; J. Electrochem. Soc., V142, N7, July, 1995,<br />

p.2266-71.<br />

9 “Side Reaction During the Anodization of <strong>Aluminum</strong> in a Glycol Borate Electrolyte.”; R.S.<br />

Santway <strong>and</strong> R.S. Alwitt; J.Electrochem.Soc., V117, N10, 1970, p.1282.<br />

10<br />

“Cellular Porous Anodic Alumina Grown in Neutral Organic Electrolyte: I. Structure,<br />

Composition <strong>and</strong> Properties of the Films.”; Liu, Alwitt & Shimizu; J. Electrochem.Soc.,<br />

V147, N4, 2000, p.1382.<br />

11 “Cellular Porous Anodic Alumina Grown in Neutral Organic Electrolyte: II. TEM<br />

Examination of Ultrathin Cross-sections <strong>and</strong> a Model for Film Growth.”; Liu, Alwitt &<br />

Shimizu; J. Electrochem.Soc., V147, N4, 2000, p.1388.<br />

76

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!