Dielectric Aluminum Oxides: Nano-Structural Features and ...
Dielectric Aluminum Oxides: Nano-Structural Features and ...
Dielectric Aluminum Oxides: Nano-Structural Features and ...
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
cut edges, air-electrolyte interfaces <strong>and</strong> other damaged areas of aluminum capacitor anodes.<br />
The formation of these plumes has been shown to depend upon voltage, current density <strong>and</strong><br />
the time of application of the current <strong>and</strong> represents a parasitic reaction in parallel with the<br />
desirable formation of barrier oxide on these raw aluminum surfaces.<br />
ACKNOWLEDGEMENTS<br />
The authors would like to thank Hitachi – HTA for their assistance in the FIB <strong>and</strong> TEM<br />
work for this study. In addition, the encouragement <strong>and</strong> appreciation of the management of<br />
St. Jude Medical, Inc. has made this work possible.<br />
REFERENCES<br />
1 ANODIC OXIDE FILMS; L. Young; Academic Press, New York, 1961, Chapter 17, pg.<br />
211.<br />
2 “Very high volt oxide formation of aluminum for electrolytic capacitors.”; T.F. Strange <strong>and</strong><br />
T.R.Marshall; U.S. Patent No. 6299752 B1, 2001.<br />
3<br />
“Improved <strong>Dielectric</strong> Properties fo Anodic <strong>Aluminum</strong> Oxide Films by Soft/Hard Two-<br />
Step Electrolytic Anodization”,; J.R. Dickey, J.L. Davidson, <strong>and</strong> Y. Tzeng,<br />
J.Electrochem.Soc., V136, N6, 1989, p.1772.<br />
4<br />
“Method of Manufacturing <strong>Aluminum</strong> Foil for <strong>Aluminum</strong> Electrolytic Capacitor.”; K.<br />
Yoshida, et.al.; U.S. Patent No. 6,096,184, Aug. 1, 2000.<br />
5 “The Barrier <strong>Aluminum</strong> Oxide Films in <strong>Aluminum</strong> Electrolytic Capacitors.”; Uchi, Kanno,<br />
& Alwitt; Ext. Abstracts Electrochem. Soc., V1999, N2.<br />
6 “Defects in Crystalline Anodic Alumina.”; J.L. Stevens <strong>and</strong> J.S. Shaffer; J. Electrochem.<br />
Soc., V133, N6, June 1986, p. 1160.<br />
7 “The Effects of Electrolyte Composition on the Deformation Characteristics of Wet<br />
<strong>Aluminum</strong> ICD Capacitors.”; J.L. Stevens, T.R. Marshall, A.C. Geiculescu, C.R. Feger, &<br />
T.F. Strange; Symp. Proc. CARTS 2006 – Orl<strong>and</strong>o, FL, Mar. 30-Apr.6, 2006, pg. 269.<br />
8 “Anodic Oxidation of <strong>Aluminum</strong> in Organic Electrolytes under Nearly Anhydrous<br />
Conditions.”; M. Ue, A. Hitoshi, <strong>and</strong> S. Mari; J. Electrochem. Soc., V142, N7, July, 1995,<br />
p.2266-71.<br />
9 “Side Reaction During the Anodization of <strong>Aluminum</strong> in a Glycol Borate Electrolyte.”; R.S.<br />
Santway <strong>and</strong> R.S. Alwitt; J.Electrochem.Soc., V117, N10, 1970, p.1282.<br />
10<br />
“Cellular Porous Anodic Alumina Grown in Neutral Organic Electrolyte: I. Structure,<br />
Composition <strong>and</strong> Properties of the Films.”; Liu, Alwitt & Shimizu; J. Electrochem.Soc.,<br />
V147, N4, 2000, p.1382.<br />
11 “Cellular Porous Anodic Alumina Grown in Neutral Organic Electrolyte: II. TEM<br />
Examination of Ultrathin Cross-sections <strong>and</strong> a Model for Film Growth.”; Liu, Alwitt &<br />
Shimizu; J. Electrochem.Soc., V147, N4, 2000, p.1388.<br />
76