Tutorials in Electrochemical Technology ... - ECS Transactions
Tutorials in Electrochemical Technology ... - ECS Transactions
Tutorials in Electrochemical Technology ... - ECS Transactions
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<strong>Tutorials</strong> <strong>in</strong> <strong>Electrochemical</strong> <strong>Technology</strong>:<br />
Impedance Spectroscopy<br />
Editors:<br />
M. E. Orazem<br />
University of Florida<br />
Ga<strong>in</strong>esville, Florida, USA<br />
B. Tribollet<br />
Université Pierre et Marie Curie<br />
Paris, France<br />
P. P<strong>in</strong>tauro<br />
Vanderbilt University<br />
Nashville, Tennessee, USA<br />
Sponsor<strong>in</strong>g Division:<br />
Industrial Electrochemistry and <strong>Electrochemical</strong> Eng<strong>in</strong>eer<strong>in</strong>g<br />
Published by<br />
The <strong>Electrochemical</strong> Society<br />
65 South Ma<strong>in</strong> Street, Build<strong>in</strong>g D<br />
Penn<strong>in</strong>gton, NJ 08534-2839, USA<br />
tel 609 737 1902<br />
fax 609 737 2743<br />
www.electrochem.org<br />
Vol. 13 No. 13<br />
TM
Copyright 2008 by The <strong>Electrochemical</strong> Society.<br />
All rights reserved.<br />
This book has been registered with Copyright Clearance Center.<br />
For further <strong>in</strong>formation, please contact the Copyright Clearance Center,<br />
Salem, Massachusetts.<br />
Published by:<br />
The <strong>Electrochemical</strong> Society<br />
65 South Ma<strong>in</strong> Street<br />
Penn<strong>in</strong>gton, New Jersey 08534-2839, USA<br />
Telephone 609.737.1902<br />
Fax 609.737.2743<br />
e-mail: ecs@electrochem.org<br />
Web: www.electrochem.org<br />
ISSN 1938-6737 (onl<strong>in</strong>e)<br />
ISSN 1938-5862 (pr<strong>in</strong>t)<br />
ISBN 978-1-56677-670-7 (PDF)<br />
ISBN 978-1-60768-022-2 (Softcover)<br />
Pr<strong>in</strong>ted <strong>in</strong> the United States of America.
Preface<br />
The papers <strong>in</strong>cluded <strong>in</strong> this issue of <strong>ECS</strong> <strong>Transactions</strong> were orig<strong>in</strong>ally presented <strong>in</strong> the<br />
symposium “G3 - <strong>Tutorials</strong> <strong>in</strong> <strong>Electrochemical</strong> <strong>Technology</strong>: Impedance Spectroscopy,”<br />
held dur<strong>in</strong>g the 213 th meet<strong>in</strong>g of The <strong>Electrochemical</strong> Society, <strong>in</strong> Phoenix, Arizona from<br />
May 18 to 23, 2008. This symposium is part of a recurr<strong>in</strong>g tutorial series sponsored by<br />
the Industrial Electrochemistry and <strong>Electrochemical</strong> Eng<strong>in</strong>eer<strong>in</strong>g Division of The<br />
<strong>Electrochemical</strong> Society.<br />
iii
<strong>ECS</strong> <strong>Transactions</strong>, Volume 13, Issue 13<br />
<strong>Tutorials</strong> <strong>in</strong> <strong>Electrochemical</strong> <strong>Technology</strong>: Impedance Spectroscopy<br />
Table of Contents<br />
Preface<br />
Impedance of Porous Electrodes *<br />
A. Lasia<br />
Impedance of a Disk Electrode with Reactions Involv<strong>in</strong>g an Adsorbed<br />
Intermediate: Local and Global Analysis<br />
S. Wu, M. E. Orazem, V. Vivier and B. Tribollet<br />
Predict<strong>in</strong>g the Long-term Performance of Coat<strong>in</strong>g Systems from Short-term EIS<br />
Test<strong>in</strong>g *<br />
S. R. Taylor and C. N. Hunter<br />
The Impedance of an Electrode Coated by a Film of Distributed Local Thickness<br />
and its Relationship with Constant Phase Elements (CPE) *<br />
S. Cattar<strong>in</strong>, N. Comisso, M. Musiani and B. Tribollet<br />
<strong>Electrochemical</strong> Impedance Spectroscopy for Characterization of <strong>Electrochemical</strong><br />
Sensors and Biosensors *<br />
C. Brett<br />
Effect of Large Perturbation Amplitudes on the Impedance Response of an<br />
<strong>Electrochemical</strong> System<br />
B. Hirschorn, I. Ibrahim, M. E. Orazem, H. Takenouti and B. Tribollet<br />
Impedance Data Masquerad<strong>in</strong>g as Unusual Circuit Elements: Instrumentation<br />
Artifacts *<br />
P. Vanýsek<br />
Characterization of Oxide Films by <strong>Electrochemical</strong> Impedance *<br />
I. Frateur<br />
Frontiers <strong>in</strong> Application of Impedance Diagnostics to H2-Fed Polymer Electrolyte<br />
Fuel Cells *<br />
M. Mathias, D. Baker, J. Zhang, Y. Liu and W. Gu<br />
iii<br />
1<br />
19<br />
43<br />
55<br />
67<br />
81<br />
101<br />
115<br />
129<br />
v
Guidel<strong>in</strong>es for Evaluation of Error Structure for Impedance Response of Polymer<br />
Electrolyte Membrane (PEM) Fuel Cells<br />
S. Roy and M. E. Orazem<br />
153<br />
Author Index 171<br />
* <strong>in</strong>vited paper<br />
vi
Guidel<strong>in</strong>es for Evaluation of Error Structure for Impedance Response of Polymer<br />
Electrolyte Membrane (PEM) Fuel Cells<br />
S. Roy and M. E. Orazem<br />
153<br />
Author Index 171<br />
* <strong>in</strong>vited paper<br />
vi