10.04.2014 Views

CATALYTIC REFORMING Process,Catalysts and Reactors

CATALYTIC REFORMING Process,Catalysts and Reactors

CATALYTIC REFORMING Process,Catalysts and Reactors

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Desirable reactions with hydrogen production<br />

• Naphthenes isomerization<br />

– Desirable reaction because of the subsequent dehydrogenation of the<br />

alkylcyclohexane into an aromatic<br />

– Difficulty of ring rearrangement <strong>and</strong> high risk of ring opening (paraffin(<br />

formation)<br />

– At the selected operating conditions, theoretically low rate but<br />

subsequent dehydrogenation shifts the reaction towards the desired<br />

ed<br />

direction<br />

– Slightly endothermic<br />

– Easier reaction for higher carbon number<br />

RON<br />

MON<br />

• Ethylcyclopentane = 67.2 61.2<br />

• Methylcyclohexane = 74.8 71.1<br />

• Toluene = 120 103.5<br />

Catalytic Reforming<br />

18

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!