06.04.2014 Views

Published or not - fyto

Published or not - fyto

Published or not - fyto

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

CHLOROTHALONIL<br />

Melting point 252 °C ( 99.6 / 99.8 %)<br />

- 2 -<br />

Boiling point > 350 °C<br />

APPENDIX I<br />

Identity, physical and chemical properties<br />

20 January 2005<br />

Appearance<br />

Pure: white crystalline solid <strong>or</strong> powder<br />

Techn.: white <strong>or</strong> tan powder<br />

Relative density D 20 4 = 1.735 (99.8%)<br />

Vapour pressure 7.62 x 10 –5 Pa at 25 °C<br />

Henry's law constant 2.5 x 10 –2 Pa m 3 mol –1 at 25 °C<br />

Solubility in water pH (neutral): 0.81 mg/l at 25 °C<br />

Solubility in <strong>or</strong>ganic In g/l at 20 °C: acetone 20.6;<br />

solvents<br />

dichl<strong>or</strong>oethane 22.4;<br />

ethyl acetate 13.8;<br />

n-heptane 0.20;<br />

xylene 74.4;<br />

methanol 1.36<br />

Partition co-efficient (log<br />

P ow )<br />

pH effectively neutral (ASTM type II<br />

water): Log Po/w = 2.94 at 25 °C<br />

Hydrolytic stability (DT 50 ) pH 5: stable<br />

pH 7 : stable<br />

pH 9 : DT 50 = 16.1 days at 20 °C<br />

Dissociation constant No dissociation<br />

Quantum yield of direct<br />

photo-transf<strong>or</strong>mation in<br />

water at λ >290 nm<br />

Flammability<br />

Explosive properties<br />

1.4 x 10 -3<br />

Not highly flammable<br />

No explosive properties<br />

UV/VIS abs<strong>or</strong>ption (max.) 232 nm, 312 nm and 324 nm (ε=<br />

62390, 1116 and 1507, resp.)<br />

Photostability in water<br />

(DT 50 )<br />

At pH 5 and 25 °C is DT 50 = 64.7<br />

days with 12 hours sunlight/day

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!