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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels 9.12. Use of Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 in Metal Working Fluids/Rolling Oils – Industrial 9.12.1. Exposure Scenario Section 1 Exposure Scenario Title Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 Title Use in Metal Working Fluids/Rolling Oils Use Descriptor Sector(s) of Use 3 Process Categories 1, 2, 3, 4, 5, 7, 8a, 8b, 9, 10, 13, 17 Further information on the mapping and allocation of PROC codes is contained in Table 9.1 Environmental Release Categories 4 Specific Environmental Release Category ESVOC SpERC 4.7a.v1 Processes, tasks, activities covered Covers the use in formulated MWFs/rolling oils including transfer operations, rolling and annealing activities, cutting/machining activities, automated and manual application of corrosion protections (including brushing, dipping and spraying), equipment maintenance, draining and disposal of waste oils. Assessment Method See Section 3. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid Vapour pressure (kPa) Liquid, vapour pressure
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels suits and face shields may be required during high dispersion activities which are likely to lead to substantial aerosol release, e.g. spraying. E4 General exposures (Closed Handle substance within a closed system E47 systems) CS15 General exposures (Open Provide extract ventilation to points where emissions occur E54 systems) CS16 Bulk transfers CS14 Handle substance within a closed system. E47 Wear gloves tested to EN374 PPE15 Filling preparation of Wear gloves tested to EN374 PPE15 equipment from drums or containers CS45 Process sampling CS2 No other specific measures identified EI20 Metal Machining Minimise exposure by partial enclosure of the operation or equipment and Operations CS79 provide extract ventilation at openings E60 Treatment of articles by Wear gloves tested to EN374 PPE15 dipping and pouring CS35 Spraying CS10 Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings E60 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) .E11 Wear gloves tested to EN374, coveralls and eye protection PPE23 Manual roller application or Wear suitable gloves tested to EN374 with specific employee training brushing CS13 PPE17 Automated metal Handle substance within a predominantly closed system provided with rolling/forming CS80 extract ventilation E49 Semi-automated metal Provide extract ventilation to points where emissions occur E54. rolling/forming CS83 Equipment cleaning and Drain down system prior to equipment break-in or maintenance E55 Wear maintenance CS39. chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Storage CS67 Store substance within a closed system. E84 Additional information on the basis for the allocation of the identified OCs and RMMs is contained in Appendices 2 to 3 Section 2.2 Control of environmental exposure Product characteristics Substance is complex UVCB [PrC3]. Predominantly hydrophobic [PrC4a]. Amounts used Fraction of <strong>EU</strong> tonnage used in region 0.1 Regional use tonnage (tonnes/year) 1.0e4 Fraction of Regional tonnage used locally 0.0097 Annual site tonnage (tonnes/year) 1.0e2 Maximum daily site tonnage (kg/day) 5.0e3 Frequency and duration of use Continuous release [FD2]. Emission days (days/year) 20 Environmental factors not influenced by risk management Local freshwater dilution factor 10 Local marine water dilution factor 100 Other given operational conditions affecting environmental exposure Release fraction to air from process (initial release prior to RMM) 0.02 Release fraction to wastewater from process (initial release prior to 3.0e-6 RMM) Release fraction to soil from process (initial release prior to RMM) 0 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used [TCS1]. 2010-07-30 CSR 150
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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This tool is provided for informati
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An Evaluation of the Persistence, B
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Table of Contents Executive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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100.0 Half-life predicted (days) 10
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2,3-dimethylheptane 9 7.7 6.2 7.4 2
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ioHCwin half-life (days) 10000.0 10
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criterion. It can be concluded that
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Hydrocarbon C nr BioHCwin Predicted
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ioHCwin half-life (days) 1000000.0
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Hydrocarbon C nr BioHCwin Predicted
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enzo[a]pyrene 20 421.6 16.5 Table 1
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(see Appendix 2). Since BCF predict
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10000 BCF (Arnot) 1000 100 10 1 n-P
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8- heptamethyl nonane 1
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Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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