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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels 9.10. Use of Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 in Lubricants – Professional: Low Environmental Release 9.10.1. Exposure Scenario Section 1 Exposure Scenario Title Gas Oils (vacuum, hydrocracked & distillate fuels) R20, R38, R40, R65, R51/53 Title Lubricants – Professional: Low Environmental Release Use Descriptor Sector(s) of Use 22 Process Categories 1, 2, 3, 4, 8a, 8b, 9, 13, 17, 20 Further information on the mapping and allocation of PROC codes is contained in Table 9.1 Environmental Release Categories 9a, 9b Specific Environmental Release Category ESVOC SpERC 9.6b.v1 Processes, tasks, activities covered Covers the use of formulated lubricants in closed and open systems including material transfers operations, operation of engines and similar articles, reworking on reject articles, equipment maintenance and disposal of waste oil. Assessment Method See Section 3. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product characteristics Physical form of product Liquid Vapour pressure (kPa) Liquid, vapour pressure
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels which are likely to lead to substantial aerosol release, e.g. spraying. E4 General exposures (Closed Handle substance within a closed system E47 PPE15 systems) CS15 Operation of equipment No other specific measures identified EI20 containing engine oils and similar CS26 General exposures (Open Provide a good standard of controlled ventilation (10 to 15 air changes systems) CS16 per hour) E40 Wear suitable gloves tested to EN374 PPE15 Bulk transfers CS14 Wear suitable gloves tested to EN374 PPE15 Avoid carrying out activities involving exposure for more than 4 hours OC28 Filling preparation of Use drum pumps or carefully pour from container E64 Wear suitable equipment from drums or gloves tested to EN374 PPE15 containers CS45; dedicated facility CS81 Filling preparation of equipment from drums or containers CS45; nondedicated facility CS82 Operation and lubrication of high energy open equipment CS17 Indoor OC8 Operation and lubrication of high energy open equipment CS17 Outdoor OC9 Maintenance (of larger plant items) and machine set up CS77 Maintenance of small items CS18 Engine lubricant service CS78 Manual roller application or brushing CS13 Spraying CS10 with local exhaust ventilation CS109 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training. PPE16 Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings E60 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) E11 Ensure operation is undertaken outdoors E69 Avoid carrying out activities involving exposure for more than 4 hours OC28 Limit the substance content in the product to 25 % OC18 Wear suitable gloves tested to EN374 PPE15 Ensure operatives are trained to minimise exposures EI19 Ensure material transfers are under containment or extract ventilation E66 Provide extract ventilation to emission points when contact with warm (>50oC) lubricant is likely E67 Wear suitable gloves tested to EN374 PPE15 Drain or remove substance from equipment prior to break-in or maintenance E81 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) E11 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. PPE17 Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings E60 Provide a good standard of general ventilation (not less than 3 to 5 air changes per hour) E11 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 Ensure operatives are trained to minimise exposures EI19 Spraying CS10 without local exhaust ventilation CS110 Wear a full face respirator conforming to EN140 with Type A/P2 filter or better. PPE32. Wear chemically resistant gloves (tested to EN374) in combination with intensive management supervision controls. PPE18 Limit the substance content in the product to 25 % OC18 Avoid carrying out activities involving exposure for more than 4 hours OC28 Treatment of articles by Wear suitable gloves tested to EN374 PPE15 dipping and pouring CS35 Storage CS67 Store substance within a closed system E84 Additional information on the basis for the allocation of the identified OCs and RMMs is contained in Appendices 2 to 3 Section 2.2 Control of environmental exposure 2010-07-30 CSR 142
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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This tool is provided for informati
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An Evaluation of the Persistence, B
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Table of Contents Executive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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100.0 Half-life predicted (days) 10
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2,3-dimethylheptane 9 7.7 6.2 7.4 2
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ioHCwin half-life (days) 10000.0 10
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criterion. It can be concluded that
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Hydrocarbon C nr BioHCwin Predicted
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ioHCwin half-life (days) 1000000.0
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Hydrocarbon C nr BioHCwin Predicted
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enzo[a]pyrene 20 421.6 16.5 Table 1
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(see Appendix 2). Since BCF predict
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10000 BCF (Arnot) 1000 100 10 1 n-P
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8- heptamethyl nonane 1
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Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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