EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Table 2 : PBT assessment of C11 – C19 monocyclic naphthenic metabolites when compared to the parent structures Name C# LogKow L(E)C50 Primary Bioacumulation half-life n-Heptylcyclopentane 12 6.05 Metabolite 1 1.87 +++ >>>> >> > > < Metabolite 3 2.36 + >>>> >>> < 1-cyclohexyl 4,8 dimethyl undecane 19 9.34 Metabolite 1 8.10 < Metabolite 2 8.10 < 120
1: The following structures were predicted to have no stable metabolites: n-hexylcyclopentane, isohexylcyclopentane, 1,2,3,4-tetraethylcyclohexane, iso-nonylcyclohexane, 1,5-dimethyl-1-(3,7- dimethyloctyl)cyclohexane, 1,5-dimethyl-1-(3,7-dimethylnonyl)cyclohexane 2: each symbol indicates the order of magnitude greater or less for the metabolite when compared to the parent molecule. 121
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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This tool is provided for informati
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An Evaluation of the Persistence, B
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Table of Contents Executive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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100.0 Half-life predicted (days) 10
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2,3-dimethylheptane 9 7.7 6.2 7.4 2
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ioHCwin half-life (days) 10000.0 10
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criterion. It can be concluded that
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Hydrocarbon C nr BioHCwin Predicted
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ioHCwin half-life (days) 1000000.0
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Hydrocarbon C nr BioHCwin Predicted
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enzo[a]pyrene 20 421.6 16.5 Table 1
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(see Appendix 2). Since BCF predict
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10000 BCF (Arnot) 1000 100 10 1 n-P
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8- heptamethyl nonane 1
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Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
Page 259 and 260: NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
Page 261 and 262: NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
Page 263 and 264: DAr 16 2-Hexylnaphthalene CCCCCCc1c
Page 265 and 266: NDAr 16 n-Butylacenaphthene c12cccc
Page 267 and 268: NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
Page 269 and 270: PAr 19 Ethylbenzo(a)fluorene C3c1cc
Page 271 and 272: PAr 22 n-Pentylbenzo(a)fluorene C3c
Page 273 and 274: PAr 28 Isohexyl-octadecahydro-picen
Page 275 and 276: Appendix 3. CONCAWE Position Paper
Page 277 and 278: probabilities are adjusted to best
Page 279 and 280: 1.2.2 OASIS LMC Models: Toxicologic
Page 281 and 282: environmental chemicals (database o
Page 283 and 284: dihydrodiol. These dihydroxylated i
Page 285: Table 1 : PBT assessment of C15 str
Page 289 and 290: Dimitrov SD, Dimitrova N, Mekenyan
Page 291 and 292: hydrocarbons and azaarenes original
Page 293 and 294: Verhaar HJM, van Leeuwen CJ, Hermen
Page 295 and 296: CONCAWE AQUATIC TOXICITY PREDICTION
Page 297 and 298: CONTENTS (Continued) Section Page 1
Page 299 and 300: 1-2 The model predictions include m
Page 301 and 302: 2-1 SECTION 2 2 SUMMARY OF COMPOSIT
Page 309 and 310: 10-1 SECTION 10 10 SUMMARY OF COMPO
Page 319: 20-1 SECTION 20 20 SUMMARY OF COMPO
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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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