EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
10000 Experimental BCF 1000 100 PAr Dietary BCF PAr Aqueous BCF B vB 5 10 15 20 25 Carbon Number Figure 59. Experimentally derived fish BCFs for poly-aromatic hydrocarbons (PAr) Experimental BMF 10 1 0.1 0.01 PAr Dietary BMF BMF = 1 0.001 10 11 12 13 14 15 16 17 18 19 20 Carbon Number Figure 60. Experimentally derived fish BMFs for poly-aromatic hydrocarbons (PAr) from dietary bioaccumulation studies 60
Acenaphthene Acenaphthylene Benz(a)anthracene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(e)pyrene Benzo(ghi)perylene Chrysene Dibenz(ah)anthracene Fluoranthene Fluorene Indeno(123cd)pyrene Naphthalene Phenanthrene Pyrene 1 10 -5 10 -4 10 -3 10 -2 10 -1 10 0 10 1 Fish Field BSAF Figure 61. Box plot of fish field biota-sediment accumulation factors (BSAFs) for several PAH. Box boundaries represent 25 th and 75 th percentile, the median is indicated by a line within each box, and whiskers denote the 10 th and 90 th percentiles of the data. Individual PAH data points ranged from n = 10 to n = 53. BSAFs for all of the compounds listed were extracted from a database compiled by the US Environmental Protection Agency (USEPA, 2008) Compound TMF (Wan et al. 2007) TMF (Nfon et al. 2008) TMF (Takeuchi et al. 2009) acenaphthylene 0.45 acenaphthene (1.02) benz[a]anthracene 0.2 0.75 (0.83) benzo[a]pyrene 0.24 (0.75) (0.80) benzo[e]pyrene 0.25 (0.86) (0.57) benzo[b]fluoranthene 0.60 benzo[b+k]fluoranthene 0.27 benzo[j+k]fluoranthene 0.69 benzo[k]fluoranthene (0.84) benzo[ghi]perylene (0.66) (0.75) (0.72) chrysene 0.26 0.66 0.65 fluoranthene 0.11 0.72 0.60 fluorene (1.15) indeno-123-cd]pyrene (0.81) (0.75) (0.80) dibenz[ah]anthracene (0.85) perylene 0.24 (0.67) (0.77) phenanthrene (0.43) 0.82 0.75 61
- Page 175 and 176: 100.0 Half-life predicted (days) 10
- Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
- Page 179 and 180: ioHCwin half-life (days) 10000.0 10
- Page 181 and 182: criterion. It can be concluded that
- Page 183 and 184: ioHCwin half-life (days) 100000.0 1
- Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
- Page 187 and 188: ioHCwin half-life (days) 1000000.0
- Page 189 and 190: ioHCwin half-life (days) 1000.0 100
- Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
- Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
- Page 195 and 196: (see Appendix 2). Since BCF predict
- Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
- Page 199 and 200: exhibit BMFs near unity (Figure 28)
- Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
- Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
- Page 205 and 206: BCF (regression) 100000 10000 1000
- Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
- Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
- Page 211 and 212: enzene n-octylbenzene 14 0.034 403
- Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
- Page 215 and 216: and appears to be an outlier. This
- Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
- Page 219 and 220: 100000 BCF (regression) 10000 1000
- Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
- Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
- Page 225: Hydrocarbon C BMF Arnot BCF Dietary
- Page 229 and 230: 5.0 Summary of Persistence and Bioa
- Page 231 and 232: lower water solubility, it is possi
- Page 233 and 234: properties of petroleum hydrocarbon
- Page 235 and 236: 8.0 References Anonymous (2004). Fi
- Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
- Page 239 and 240: Prince RC, Walters CC. (2007). Biod
- Page 241 and 242: Appendix 1. Hydrocarbon structures
- Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
- Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
- Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
- Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
- Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
- Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
- Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
- Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
- Page 259 and 260: NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
- Page 261 and 262: NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
- Page 263 and 264: DAr 16 2-Hexylnaphthalene CCCCCCc1c
- Page 265 and 266: NDAr 16 n-Butylacenaphthene c12cccc
- Page 267 and 268: NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
- Page 269 and 270: PAr 19 Ethylbenzo(a)fluorene C3c1cc
- Page 271 and 272: PAr 22 n-Pentylbenzo(a)fluorene C3c
- Page 273 and 274: PAr 28 Isohexyl-octadecahydro-picen
- Page 275 and 276: Appendix 3. CONCAWE Position Paper
Acenaphthene<br />
Acenaphthylene<br />
Benz(a)anthracene<br />
Benzo(a)pyrene<br />
Benzo(b)fluoranthene<br />
Benzo(k)fluoranthene<br />
Benzo(e)pyrene<br />
Benzo(ghi)perylene<br />
Chrysene<br />
Dibenz(ah)anthracene<br />
Fluoranthene<br />
Fluorene<br />
Indeno(123cd)pyrene<br />
Naphthalene<br />
Phenanthrene<br />
Pyrene<br />
1<br />
10 -5 10 -4 10 -3 10 -2 10 -1 10 0 10 1<br />
Fish Field BSAF<br />
Figure 61. Box plot of fish field biota-sediment accumulation factors (BSAFs) for several<br />
PAH. Box boundaries represent 25 th and 75 th percentile, the median is indicated by a line<br />
within each box, and whiskers denote the 10 th and 90 th percentiles of the data. Individual<br />
PAH data points ranged from n = 10 to n = 53. BSAFs for all of the compounds listed<br />
were extracted from a database compiled by the US Environmental Protection Agency<br />
(USEPA, 2008)<br />
Compound<br />
TMF (Wan<br />
et al. 2007)<br />
TMF<br />
(Nfon et al.<br />
2008)<br />
TMF<br />
(Takeuchi et<br />
al. 2009)<br />
acenaphthylene 0.45<br />
acenaphthene (1.02)<br />
benz[a]anthracene 0.2 0.75 (0.83)<br />
benzo[a]pyrene 0.24 (0.75) (0.80)<br />
benzo[e]pyrene 0.25 (0.86) (0.57)<br />
benzo[b]fluoranthene 0.60<br />
benzo[b+k]fluoranthene 0.27<br />
benzo[j+k]fluoranthene 0.69<br />
benzo[k]fluoranthene (0.84)<br />
benzo[ghi]perylene (0.66) (0.75) (0.72)<br />
chrysene 0.26 0.66 0.65<br />
fluoranthene 0.11 0.72 0.60<br />
fluorene (1.15)<br />
indeno-123-cd]pyrene (0.81) (0.75) (0.80)<br />
dibenz[ah]anthracene (0.85)<br />
perylene 0.24 (0.67) (0.77)<br />
phenanthrene (0.43) 0.82 0.75<br />
61