EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
100000 BCF (regression) 10000 1000 100 10 PAr B vB 1 10 15 20 25 30 35 Carbon Number Figure 57. Predicted fish BCFs for poly-aromatic hydrocarbons (PAr) using the regression-based approach in BCFBAF. B – 2000, vB - 5000 10000 BCF (Arnot) 1000 100 10 10 15 20 25 30 35 Carbon Number PAr B vB Figure 58. Predicted fish BCFs for poly-aromatic hydrocarbons (PAr) using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000 Hydrocarbon C BMF Arnot BCF Dietary BCF Aqueous BCF Species Reference acenaphthylene 12 0.005 269 67 RT Niimi and Dookhran 1989 12 269 579 C Yakata, 2006 12 269 596 C Yakata, 2006 56
Hydrocarbon C BMF Arnot BCF Dietary BCF Aqueous BCF Species Reference 12 269 507 C CITI, 1992 12 269 488 C CITI, 1992 fluorene 13 0.03 197 316 RT Niimi and Palazzo 1986 13 197 672 C CITI, 1992 13 197 780 C CITI, 1992 13 197 1875 FHM Carlson et al., 1979 13 197 1146 FHM Carlson et al., 1979 anthracene* 14 0.004 362 811 RT EMBSI, 2005a 14 0.027 362 217 RT EMBSI, 2008b 14 0.009 362 351 C EMBSI, 2008c 14 0.002 362 316 RT Niimi and Palazzo 1986 14 362 1807 C CITI, 1992 14 362 2240 C CITI, 1992 14 362 2354 FHM Hall and Oris, 1991 14 362 3725 FHM Hall and Oris, 1991 phenanthrene 14 0.076 365 2208 RT EMBSI, 2001a 14 0.01 365 407 RT Niimi and Palazzo 1986 14 1194 SHM Jonsson et al., 2004 14 417 SHM Jonsson et al.,2004 14 2329 FHM Carlson et al.,1979 14 3546 FHM Carlson et al.,1979 14 2927 FHM Carlson et al., 1979 9-methyl anthracene 15 0.004 344 959 RT EMBSI, 2005a 1-methyl phenanthrene 15 0.019 345 2282 RT EMBSI, 2001a 2-methyl anthracene 15 0.009 327 158 RT Niimi and Dookhran, 1989 9-methyl anthracene 15 0.001 344 315 RT Niimi and Dookhran, 1989 fluoranthene 16 0.032 451 213 435 RT EMBSI, 2007b, 2009b 16 0.046 451 967 RT EMBSI, 2008b 57
- Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
- Page 173 and 174: 3.0 Persistence Assessment of Petro
- Page 175 and 176: 100.0 Half-life predicted (days) 10
- Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
- Page 179 and 180: ioHCwin half-life (days) 10000.0 10
- Page 181 and 182: criterion. It can be concluded that
- Page 183 and 184: ioHCwin half-life (days) 100000.0 1
- Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
- Page 187 and 188: ioHCwin half-life (days) 1000000.0
- Page 189 and 190: ioHCwin half-life (days) 1000.0 100
- Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
- Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
- Page 195 and 196: (see Appendix 2). Since BCF predict
- Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
- Page 199 and 200: exhibit BMFs near unity (Figure 28)
- Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
- Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
- Page 205 and 206: BCF (regression) 100000 10000 1000
- Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
- Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
- Page 211 and 212: enzene n-octylbenzene 14 0.034 403
- Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
- Page 215 and 216: and appears to be an outlier. This
- Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
- Page 219 and 220: 100000 BCF (regression) 10000 1000
- Page 221: 10 Experimental BMF 1 0.1 NDiAr Die
- Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
- Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
- Page 229 and 230: 5.0 Summary of Persistence and Bioa
- Page 231 and 232: lower water solubility, it is possi
- Page 233 and 234: properties of petroleum hydrocarbon
- Page 235 and 236: 8.0 References Anonymous (2004). Fi
- Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
- Page 239 and 240: Prince RC, Walters CC. (2007). Biod
- Page 241 and 242: Appendix 1. Hydrocarbon structures
- Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
- Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
- Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
- Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
- Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
- Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
- Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
- Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
- Page 259 and 260: NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
- Page 261 and 262: NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
- Page 263 and 264: DAr 16 2-Hexylnaphthalene CCCCCCc1c
- Page 265 and 266: NDAr 16 n-Butylacenaphthene c12cccc
- Page 267 and 268: NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
- Page 269 and 270: PAr 19 Ethylbenzo(a)fluorene C3c1cc
- Page 271 and 272: PAr 22 n-Pentylbenzo(a)fluorene C3c
100000<br />
BCF (regression)<br />
10000<br />
1000<br />
100<br />
10<br />
PAr<br />
B<br />
vB<br />
1<br />
10 15 20 25 30 35<br />
Carbon Number<br />
Figure 57. Predicted fish BCFs for poly-aromatic hydrocarbons (PAr) using the<br />
regression-based approach in BCFBAF. B – 2000, vB - 5000<br />
10000<br />
BCF (Arnot)<br />
1000<br />
100<br />
10<br />
10 15 20 25 30 35<br />
Carbon Number<br />
PAr<br />
B<br />
vB<br />
Figure 58. Predicted fish BCFs for poly-aromatic hydrocarbons (PAr) using Arnot’s<br />
equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000<br />
Hydrocarbon C BMF<br />
Arnot<br />
BCF<br />
Dietary<br />
BCF<br />
Aqueous<br />
BCF<br />
Species<br />
Reference<br />
acenaphthylene 12 0.005 269 67 RT<br />
Niimi and<br />
Dookhran 1989<br />
12 269 579 C Yakata, 2006<br />
12 269 596 C Yakata, 2006<br />
56
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