EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Experimental BCF 100000 10000 1000 DAH Dietary BCF DAH Aqueous BCF B vB 100 5 10 15 20 25 Carbon Number Figure 51. Experimentally derived fish BCFs for di-aromatic hydrocarbons (DiAr) . B – 2000, vB - 5000 Experimental BMF 10 1 0.1 0.01 DAH Dietary BMF BMF = 1 0.001 5 10 15 20 Carbon Number Figure 52. Experimentally derived fish BMFs for di-aromatic hydrocarbons (DiAr) from dietary bioaccumulation studies 4.9 Naphthenic Di-Aromatics Regression method-based BCF predictions for naphthenic di-aromatic hydrocarbons (Figure 53) are above the B criterion of 2000 for structures ranging from C15 to C23. When biotransformation is incorporated to the model, none of the BCF predictions are above 2000 (Figure 54). In support of model predictions, no aqueous or dietary BCF that is available for naphthenic di-aromatics structures is above 2000. Furthermore, all experimental BMF values (Figure 55) are below 0.1. It can be concluded that based on the available data, naphthenic di-aromatic hydrocarbons, as a class, are not bioaccumulative or very bioaccumulative. 52
100000 BCF (regression) 10000 1000 100 10 NDiAr B vB 1 10 15 20 25 30 35 Carbon Number Figure 53. Predicted fish BCFs for naphthenic di-aromatic hydrocarbons (NDiAr) using the regression-based approach in BCFBAF. B – 2000, vB - 5000 10000.0 1000.0 BCF (Arnot) 100.0 10.0 1.0 NDiAr B vB 0.1 10 15 20 25 30 35 Carbon Number Figure 54. Predicted fish BCFs for naphthenic di-aromatic hydrocarbons (NDiAr) using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000 Hydrocarbon C BMF BCF Arnot Dietary BCF Aqueous BCF Species Reference acenaphthene 12 44 979 C CITI, 1992 12 44 1003 C CITI, 1992 1,2,3,10b-tetrahydro fluoranthene 16 0.023 132 506 RT EMBSI, 2008a 1,2,3,6,7,8- 16 0.056 176 1349 RT EMBSI, 2005e 53
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216: and appears to be an outlier. This
Page 217: 4-ethylbiphenyl 14 863 1039 C Yakat
Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
Page 259 and 260: NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
Page 261 and 262: NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
Page 263 and 264: DAr 16 2-Hexylnaphthalene CCCCCCc1c
Page 265 and 266: NDAr 16 n-Butylacenaphthene c12cccc
Page 267 and 268: NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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