EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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10000 1000 BCF (Arnot) 100 10 1 DiAr B vB 0 5 10 15 20 25 30 35 Carbon Number Figure 50. Predicted fish BCFs for di-aromatic hydrocarbons (DiAr) using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000 Hydrocarbon C BMF BCF Arnot Dietary BCF Aqueous BCF Species Reference naphthalene 10 0.005 229 814 RT EMBSI, 2005a 10 229 95 C CITI, 1992 10 229 91 C CITI, 1992 2-methylnaphthalene 11 389 1871 SHM Jonsson et al, 2004 2-methylnaphthalene 11 0.01 389 651 RT EMBSI, 2005a methylnaphthalenes 11 0.063 398 857 RT EMBSI, 2001b 1,3-dimethylnaphthalene 12 378 2051 SHM Jonsson et al, 2004 2,3-dimethylnaphthalene 12 0.012 378 973 RT EMBSI, 2005a di-me & et naphthalenes 12 0.108 863 1425 RT EMBSI, 2001b tri-me naphthalenes 13 0.092 2011 1702 RT EMBSI, 2001b 2-isopropylnapthalene 13 740 12298 SHM Jonsson et al, 2004 isopropylnaphthalene 13 740 1620 C CITI, 1992 13 740 600 C CITI, 1992 diphenylmethane 13 95 904 C CITI, 1992 4-ethyl-1,1'-biphenyl 14 0.031 863 216 RT EMBSI, 2008b 14 0.005 863 628 C EMBSI, 2008c 50
4-ethylbiphenyl 14 863 1039 C Yakata et al, 2006 1,4-dimethyl-2-(1- Yakata et 16 400 1106 C phenylethyl) benzene al, 2006 3,3',4,4'-tetramethyl 1,1'- EMBSI, 16 0.009 2068 536 RT biphenyl 2005e 2,7-diisopropyl EMBSI, 16 0.043 1570 229 RT naphthalene 2008b 2,7- EMBSI, 16 0.03 1570 2422 C diisopropylnaphthalene 2008c benzyl-p-xylene 16 426 1869 C CITI, 1992 426 1407 C CITI, 1992 6-n-butyl-2,3- EMBSI, 16 0.013 386 1695 RT dimethylnaphthalene 2006b 4-pentyl-1,1'-Biphenyl 17 0.067 746 526 RT EMBSI, 2005d benzene, 1,1'-(1,1,2,2- tetramethyl-1,2- ethanediyl)bis- 3,3',5,5'- tetramethyl bibenzyl 2,3-dimethy- 5(4methylpentyl) naphthalene 2,3-dimethy- 5(4methylpentyl) naphthalene 18 0.167 440 3097 RT 18 0.42 440 3501 RT 18 0.04 229 229 RT 18 0.046 389 191 RT EMBSI, 2005e EMBSI, 2005e EMBSI, 2005d EMBSI, 2006b Table 18. Experimentally derived dietary and aqueous bioaccumulation data for diaromatic hydrocarbons. BCF (Arnot) is the predicted BCF using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). RT: rainbow trout; C: carp; SHM: sheepshead minnow. Bold blue entries represent BCF values between the B criterion (2000) and the vB criterion (5000). Bold red entries represent BCF values above the vB criterion (5000). 51
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
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Page 215: and appears to be an outlier. This
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Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
Page 259 and 260: NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
Page 261 and 262: NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
Page 263 and 264: DAr 16 2-Hexylnaphthalene CCCCCCc1c
Page 265 and 266: NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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