EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
Hydrocarbon C BMF BCF Arnot Dietary BCF Aqueous BCF Species hexadecahydropyrene 16 1.02 4084 19451 4955 RT isopropyl hydrophenanthrene 1-methyl-7- (isopropyl)- hydrophenanthrene 17 0.448 3563 11595 RT 18 0.35 2872 7607 RT perhydrochrysene 18 0.376 4871 9691 RT 1,1':3', 1"- tercyclohexane hydrogenated terphenyl 18 0.44 95 282 RT Reference EMBSI, 2008a, 2009b EMBSI, 2006b EMBSI, 2008a EMBSI, 2008b EMBSI, 2008c 18 4650 C CITI, 1992 Table 15. Experimentally derived dietary and aqueous bioaccumulation data for polynaphthenic hydrocarbons. BCF (Arnot) is the predicted BCF using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). RT: rainbow trout; C: carp. Bold blue entries represent BCF values between the B criterion (2000) and the vB criterion (5000). Bold red entries represent BCF values above the vB criterion (5000). Experimental BCF 100000 10000 1000 Polynaphth. Dietary BCF Polynaphth. Aqueous BCF B vB 100 15 16 17 18 19 20 Carbon Number Figure 39. Experimentally derived fish BCFs for polynaphthenic hydrocarbons. B – 2000, vB - 5000 42
Experimental BMF 10 1 Polynaphth. Dietary BMF BMF = 1 0.1 15 16 17 18 19 20 Carbon Number Figure 40. Experimentally derived fish BMFs for polynaphthenic hydrocarbons from dietary bioaccumulation studies 4.6 Mono-Aromatics Regression method BCF predictions for mono-aromatics (Figure 41) are above the B criterion of 2000 for structures ranging from C12 to C17. When biotransformation is incorporated to the model, none of the BCF predictions are above 2000 (Figure 42). Dietary BCF values, which are typically more conservative than aqueous BCF values, are below the B criterion for all tested structures (C9 to C16) except 1,3,5-tris(1- methylethyl)-benzene (triisopropyl benzene, Table 16). However, this compound is not representative of petroleum hydrocarbon structures and is therefore not used for B assessment of this HCB. Aqueous BCFs for all other monoaromatics are below 2000. Experimental BMF factors derived from dietary data (Figure 44) are consistently well below 1. It can be concluded that based on the available data, mono-aromatic hydrocarbons, as a class, are neither bioaccumulative nor very bioaccumulative. BCF (regression) 100000 10000 1000 100 10 Monoaromatics B vB 1 5 10 15 20 25 30 35 Carbon Number Figure 41. Predicted fish BCFs for mono-aromatic hydrocarbons using the regressionbased approach in BCFBAF. B – 2000, vB - 5000 43
- Page 157 and 158: Professional - Treatment and dispos
- Page 159 and 160: Industrial - operation of open CS16
- Page 161 and 162: Vacuum Gas Oils, Hydrocracked Gas O
- Page 163 and 164: Vacuum Gas Oils, Hydrocracked Gas O
- Page 165 and 166: This tool is provided for informati
- Page 167 and 168: An Evaluation of the Persistence, B
- Page 169 and 170: Table of Contents Executive Summary
- Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
- Page 173 and 174: 3.0 Persistence Assessment of Petro
- Page 175 and 176: 100.0 Half-life predicted (days) 10
- Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
- Page 179 and 180: ioHCwin half-life (days) 10000.0 10
- Page 181 and 182: criterion. It can be concluded that
- Page 183 and 184: ioHCwin half-life (days) 100000.0 1
- Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
- Page 187 and 188: ioHCwin half-life (days) 1000000.0
- Page 189 and 190: ioHCwin half-life (days) 1000.0 100
- Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
- Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
- Page 195 and 196: (see Appendix 2). Since BCF predict
- Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
- Page 199 and 200: exhibit BMFs near unity (Figure 28)
- Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
- Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
- Page 205 and 206: BCF (regression) 100000 10000 1000
- Page 207: 4.5 Polynaphthenic hydrocarbons Reg
- Page 211 and 212: enzene n-octylbenzene 14 0.034 403
- Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
- Page 215 and 216: and appears to be an outlier. This
- Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
- Page 219 and 220: 100000 BCF (regression) 10000 1000
- Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
- Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
- Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
- Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
- Page 229 and 230: 5.0 Summary of Persistence and Bioa
- Page 231 and 232: lower water solubility, it is possi
- Page 233 and 234: properties of petroleum hydrocarbon
- Page 235 and 236: 8.0 References Anonymous (2004). Fi
- Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
- Page 239 and 240: Prince RC, Walters CC. (2007). Biod
- Page 241 and 242: Appendix 1. Hydrocarbon structures
- Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
- Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
- Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
- Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
- Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
- Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
- Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
- Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
Experimental BMF<br />
10<br />
1<br />
Polynaphth. Dietary BMF<br />
BMF = 1<br />
0.1<br />
15 16 17 18 19 20<br />
Carbon Number<br />
Figure 40. Experimentally derived fish BMFs for polynaphthenic hydrocarbons from<br />
dietary bioaccumulation studies<br />
4.6 Mono-Aromatics<br />
Regression method BCF predictions for mono-aromatics (Figure 41) are above the B<br />
criterion of 2000 for structures ranging from C12 to C17. When biotransformation is<br />
incorporated to the model, none of the BCF predictions are above 2000 (Figure 42).<br />
Dietary BCF values, which are typically more conservative than aqueous BCF values, are<br />
below the B criterion for all tested structures (C9 to C16) except 1,3,5-tris(1-<br />
methylethyl)-benzene (triisopropyl benzene, Table 16). However, this compound is not<br />
representative of petroleum hydrocarbon structures and is therefore not used for B<br />
assessment of this HCB. Aqueous BCFs for all other monoaromatics are below 2000.<br />
Experimental BMF factors derived from dietary data (Figure 44) are consistently well<br />
below 1. It can be concluded that based on the available data, mono-aromatic<br />
hydrocarbons, as a class, are neither bioaccumulative nor very bioaccumulative.<br />
BCF (regression)<br />
100000<br />
10000<br />
1000<br />
100<br />
10<br />
Monoaromatics<br />
B<br />
vB<br />
1<br />
5 10 15 20 25 30 35<br />
Carbon Number<br />
Figure 41. Predicted fish BCFs for mono-aromatic hydrocarbons using the regressionbased<br />
approach in BCFBAF. B – 2000, vB - 5000<br />
43