EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Hydrocarbon C BMF BCF Arnot Dietary BCF Aqueous BCF Species hexadecahydropyrene 16 1.02 4084 19451 4955 RT isopropyl hydrophenanthrene 1-methyl-7- (isopropyl)- hydrophenanthrene 17 0.448 3563 11595 RT 18 0.35 2872 7607 RT perhydrochrysene 18 0.376 4871 9691 RT 1,1':3', 1"- tercyclohexane hydrogenated terphenyl 18 0.44 95 282 RT Reference EMBSI, 2008a, 2009b EMBSI, 2006b EMBSI, 2008a EMBSI, 2008b EMBSI, 2008c 18 4650 C CITI, 1992 Table 15. Experimentally derived dietary and aqueous bioaccumulation data for polynaphthenic hydrocarbons. BCF (Arnot) is the predicted BCF using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). RT: rainbow trout; C: carp. Bold blue entries represent BCF values between the B criterion (2000) and the vB criterion (5000). Bold red entries represent BCF values above the vB criterion (5000). Experimental BCF 100000 10000 1000 Polynaphth. Dietary BCF Polynaphth. Aqueous BCF B vB 100 15 16 17 18 19 20 Carbon Number Figure 39. Experimentally derived fish BCFs for polynaphthenic hydrocarbons. B – 2000, vB - 5000 42
Experimental BMF 10 1 Polynaphth. Dietary BMF BMF = 1 0.1 15 16 17 18 19 20 Carbon Number Figure 40. Experimentally derived fish BMFs for polynaphthenic hydrocarbons from dietary bioaccumulation studies 4.6 Mono-Aromatics Regression method BCF predictions for mono-aromatics (Figure 41) are above the B criterion of 2000 for structures ranging from C12 to C17. When biotransformation is incorporated to the model, none of the BCF predictions are above 2000 (Figure 42). Dietary BCF values, which are typically more conservative than aqueous BCF values, are below the B criterion for all tested structures (C9 to C16) except 1,3,5-tris(1- methylethyl)-benzene (triisopropyl benzene, Table 16). However, this compound is not representative of petroleum hydrocarbon structures and is therefore not used for B assessment of this HCB. Aqueous BCFs for all other monoaromatics are below 2000. Experimental BMF factors derived from dietary data (Figure 44) are consistently well below 1. It can be concluded that based on the available data, mono-aromatic hydrocarbons, as a class, are neither bioaccumulative nor very bioaccumulative. BCF (regression) 100000 10000 1000 100 10 Monoaromatics B vB 1 5 10 15 20 25 30 35 Carbon Number Figure 41. Predicted fish BCFs for mono-aromatic hydrocarbons using the regressionbased approach in BCFBAF. B – 2000, vB - 5000 43
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Page 159 and 160: Industrial - operation of open CS16
Page 161 and 162: Vacuum Gas Oils, Hydrocracked Gas O
Page 163 and 164: Vacuum Gas Oils, Hydrocracked Gas O
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207: 4.5 Polynaphthenic hydrocarbons Reg
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
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Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
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Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256: MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258: NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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