EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Figure 31. Experimentally derived fish BCFs for mono-naphthenic hydrocarbons. B – 2000, vB - 5000 10 MN Dietary BMF BMF = 1 Experimental BMF 1 0.1 0.01 5 10 15 Carbon Number Figure 32. Experimentally derived fish BMFs for mono-naphthenic hydrocarbons from dietary bioaccumulation studies 4.4 Di-Naphthenic hydrocarbons Regression-based BCF predictions for di-naphthenic hydrocarbons (Figure 33) are above the B criterion of 2000 for structures ranging from C14 to C20. When biotransformation is incorporated to the model, BCF predictions for structures with carbon numbers ranging from C13 to C18 are above 2000 (Figure 34). Dietary BCF values are above the B criterion for many of the tested structures, which range from C9 to C16 (Table 14). One of the structures, trans-decalin, has a calculated dietary BCF value of more than 5000 but several aqueous BCF values for cis-decalin clearly show the true BCF is below 5000. Experimental BMF factors, derived from the dietary data (Figure 36), are always below 1 indicating these substances are not expected to biomagnify. It can be concluded that based on the available data, some C10 to C18 di-naphthenic hydrocarbons likely meet the bioaccumulative (B), but not very bioaccumulative (vB) criterion. 38
BCF (regression) 100000 10000 1000 100 10 Dinaphthenics B vB 1 0 5 10 15 20 25 30 35 40 Carbon number Figure 33. Predicted fish BCFs for di-naphthenic hydrocarbons using the regressionbased approach in BCFBAF. B – 2000, vB - 5000 10000 BCF (Arnot) 1000 100 10 Dinaphthenics B vB 1 0 0 5 10 15 20 25 30 35 40 Carbon number Figure 34. Predicted fish BCFs for di-naphthenic hydrocarbons using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000 Hydrocarbon C BMF BCF Arnot Dietary BCF Aqueous BCF Species Reference bicyclo[4.3.0] nonane 9 0.079 194 838 RT EMBSI, 2003 trans-decalin 10 0.856 486 5846 RT EMBSI, 2001a 10 486 1962 C CITI, 1992 10 486 2250 C CITI, 1992 cis-decalin 10 486 2573 C CITI, 1992 10 486 2323 C CITI, 1992 39
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
Page 153 and 154: Professional - Maintenance and CS77
Page 155 and 156: Note: differentiated Industrial -SU
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 161 and 162: Vacuum Gas Oils, Hydrocracked Gas O
Page 163 and 164: Vacuum Gas Oils, Hydrocracked Gas O
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216: and appears to be an outlier. This
Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
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Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252: hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254: PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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