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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Figure 31. Experimentally derived fish BCFs for mono-naphthenic hydrocarbons. B –<br />

2000, vB - 5000<br />

10<br />

MN Dietary BMF<br />

BMF = 1<br />

Experimental BMF<br />

1<br />

0.1<br />

0.01<br />

5 10 15<br />

Carbon Number<br />

Figure 32. Experimentally derived fish BMFs for mono-naphthenic hydrocarbons from<br />

dietary bioaccumulation studies<br />

4.4 Di-Naphthenic hydrocarbons<br />

Regression-based BCF predictions for di-naphthenic hydrocarbons (Figure 33) are above<br />

the B criterion of 2000 for structures ranging from C14 to C20. When biotransformation<br />

is incorporated to the model, BCF predictions for structures with carbon numbers ranging<br />

from C13 to C18 are above 2000 (Figure 34). Dietary BCF values are above the B<br />

criterion for many of the tested structures, which range from C9 to C16 (Table 14). One<br />

of the structures, trans-decalin, has a calculated dietary BCF value of more than 5000 but<br />

several aqueous BCF values for cis-decalin clearly show the true BCF is below 5000.<br />

Experimental BMF factors, derived from the dietary data (Figure 36), are always below 1<br />

indicating these substances are not expected to biomagnify. It can be concluded that<br />

based on the available data, some C10 to C18 di-naphthenic hydrocarbons likely meet the<br />

bioaccumulative (B), but not very bioaccumulative (vB) criterion.<br />

38

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