EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Hydrocarbon C BMF BCF (Arnot) Dietary BCF Aqueous BCF Species Reference 2,2,4- CITI, 1992 8 200 853 C trimethylpentane 8 200 821 C CITI, 1992 2,3-dimethylheptane 9 0.258 298 3726 RT EMBSI, 2001a 2,3-dimethylheptane 9 0.065 298 1957 RT EMBSI, 2006a 2,6-dimethyl octane 10 0.014 406 1735 RT EMBSI, 2006a 3-ethyl-nonane 11 0.036 602 2235 RT EMBSI, 2004a 3-methyl decane 11 0.02 602 1753 RT EMBSI, 2006a 2-methyl decane 11 0.036 602 663 RT EMBSI, 2006a 2,2,4,6,6- EMBSI, 12 0.187 1012 5899 RT pentamethylheptane 2001a 12 1012 4518 RT EMBSI 2004c 12 1012 1467 FHM Tolls and v Dijk, 2002 2,3 dimethyldecane 12 0.03 693 1049 RT EMBSI, 2005d 2,3 dimethyldecane 12 0.022 693 6004 RT EMBSI, 2006a 2,6-dimethyldecane 12 0.073 693 4380 RT EMBSI, 2001a 2,6-dimethyldecane 12 0.023 693 299 RT EMBSI, 2005e 2-methyl undecane 12 0.051 695 2983 RT EMBSI, 2006a 2,2,3-trimethyl EMBSI, 13 0.094 844 2499 RT decane 2004a 2,2,3-trimethyl EMBSI, 13 0.038 844 3623 RT decane 2006a 2,6-dimethyl EMBSI, 13 0.094 656 3467 RT undecane 2006a 4-methyl dodecane 13 0.077 631 2921 RT EMBSI, 2006a 2,6,10-trimethyl EMBSI, 15 1.27 251 2424 RT dodecane 2004a 2,6,10-trimethyl EMBSI, 15 0.72 251 3345 RT dodecane 2005b 15 291 RT EMBSI 2004b 15 817 RT EMBSI, 2005c 34
2,2,4,4,6,8,8- heptamethyl nonane 16 1.01 298 2620 RT 16 298 673 RT EMBSI, 2004a EMBSI, 2005c Table 12. Experimentally derived dietary and aqueous bioaccumulation data for isoparaffins. BCF (Arnot) is the predicted BCF using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). RT: rainbow trout; FHM: fathead minnow; C: carp. Bold blue entries represent BCF values between the B criterion (2000) and the vB criterion (5000). Bold red entries represent BCF values above the vB criterion (5000). 10000 Experimental BCF 1000 100 10 iP Dietary BCF iP Aqueous BCF B vB 1 5 10 15 20 Carbon Number Figure 27. Experimentally derived fish BCFs for iso-paraffins. B – 2000, vB - 5000 10 iP Dietary BMF BMF = 1 Experimental BMF 1 0.1 0.01 5 10 15 20 Carbon Number Figure 28. Experimentally derived fish BMFs for iso-paraffins from dietary bioaccumulation studies 35
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EU-SICHERHEITSDATENBLATT gemäß Ve
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
Page 149 and 150: Combined Professional - Manual spra
Page 151 and 152: Industrial - Bulk transfers CS14 Da
Page 153 and 154: Professional - Maintenance and CS77
Page 155 and 156: Note: differentiated Industrial -SU
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 161 and 162: Vacuum Gas Oils, Hydrocracked Gas O
Page 163 and 164: Vacuum Gas Oils, Hydrocracked Gas O
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199: exhibit BMFs near unity (Figure 28)
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216: and appears to be an outlier. This
Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
Page 219 and 220: 100000 BCF (regression) 10000 1000
Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250: MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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