EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
10000 Experimental BCF 1000 100 10 nP Dietary BCF nP Aqueous BCF B vB 1 5 10 15 20 25 30 Carbon Number Figure 23. Experimentally derived fish BCFs for n-paraffins. B – 2000, vB - 5000 Experimental BMF 10 1 0.1 nP Dietary BMF BMF = 1 0.01 5 10 15 20 Carbon Number Figure 24. Experimentally derived fish BMFs for n-paraffins from dietary bioaccumulation studies 4.2 Iso-paraffins Regression method BCF predictions for iso-paraffins (Figure 25) are above the B criterion of 2000 for structures ranging from C11 to C16. Above these carbon chain lengths, BCF values decrease below 2000. When biotransformation is incorporated into the model, none of the iso-paraffin BCF predictions are above 2000 (Figure 26). Experimental BCF values for iso-paraffins range from 673 (aqueous) to 6004 (dietary). Dietary BCF values, which are typically more conservative than aqueous BCF values, are above the B criterion for selected C9, C11 and C12 structures. Aqueous BCF data for 2,2,4,6,6-pentamethylheptane which is a highly branched, atypical structure indicates the B criterion maybe fulfilled (Figure 27). For all tested C13, C15 and C16 structures dietary calculated BCFs exceed 2000 (Table 12). However, reliable aqueous BCF data for C15 and C16 structures indicate these compounds do not fulfill the B criterion but do 32
exhibit BMFs near unity (Figure 28). It can be concluded that based on the available data, C12-C16 iso-paraffins may be bioaccumulative (B), but not very bioaccumulative (vB). BCF (regression) 100000 10000 1000 100 10 i-Paraffins B vB 1 0 5 10 15 20 25 30 35 Carbon Number Figure 25. Predicted fish BCFs for iso-paraffins using the regression-based approach in BCFBAF. B – 2000, vB - 5000 10000 BCF (Arnot) 1000 100 10 i-Paraffins B vB 1 0 0 5 10 15 20 25 30 35 Carbon Number Figure 26. Predicted fish BCFs for iso-paraffins using Arnot’s equations incorporating metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000 33
- Page 147 and 148: Industrial - Tabletting, CS100 Indo
- Page 149 and 150: Combined Professional - Manual spra
- Page 151 and 152: Industrial - Bulk transfers CS14 Da
- Page 153 and 154: Professional - Maintenance and CS77
- Page 155 and 156: Note: differentiated Industrial -SU
- Page 157 and 158: Professional - Treatment and dispos
- Page 159 and 160: Industrial - operation of open CS16
- Page 161 and 162: Vacuum Gas Oils, Hydrocracked Gas O
- Page 163 and 164: Vacuum Gas Oils, Hydrocracked Gas O
- Page 165 and 166: This tool is provided for informati
- Page 167 and 168: An Evaluation of the Persistence, B
- Page 169 and 170: Table of Contents Executive Summary
- Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
- Page 173 and 174: 3.0 Persistence Assessment of Petro
- Page 175 and 176: 100.0 Half-life predicted (days) 10
- Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
- Page 179 and 180: ioHCwin half-life (days) 10000.0 10
- Page 181 and 182: criterion. It can be concluded that
- Page 183 and 184: ioHCwin half-life (days) 100000.0 1
- Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
- Page 187 and 188: ioHCwin half-life (days) 1000000.0
- Page 189 and 190: ioHCwin half-life (days) 1000.0 100
- Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
- Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
- Page 195 and 196: (see Appendix 2). Since BCF predict
- Page 197: 10000 BCF (Arnot) 1000 100 10 1 n-P
- Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
- Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
- Page 205 and 206: BCF (regression) 100000 10000 1000
- Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
- Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
- Page 211 and 212: enzene n-octylbenzene 14 0.034 403
- Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
- Page 215 and 216: and appears to be an outlier. This
- Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
- Page 219 and 220: 100000 BCF (regression) 10000 1000
- Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
- Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
- Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
- Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
- Page 229 and 230: 5.0 Summary of Persistence and Bioa
- Page 231 and 232: lower water solubility, it is possi
- Page 233 and 234: properties of petroleum hydrocarbon
- Page 235 and 236: 8.0 References Anonymous (2004). Fi
- Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
- Page 239 and 240: Prince RC, Walters CC. (2007). Biod
- Page 241 and 242: Appendix 1. Hydrocarbon structures
- Page 243 and 244: iP 14 2,4,10-Trimethylundecane CC(C
- Page 245 and 246: MN 7 1,2-Dimethylcyclopentane CC1C(
- Page 247 and 248: MN 14 n-Nonylcyclopentane CCCCCCCCC
exhibit BMFs near unity (Figure 28). It can be concluded that based on the available<br />
data, C12-C16 iso-paraffins may be bioaccumulative (B), but not very bioaccumulative<br />
(vB).<br />
BCF (regression)<br />
100000<br />
10000<br />
1000<br />
100<br />
10<br />
i-Paraffins<br />
B<br />
vB<br />
1<br />
0 5 10 15 20 25 30 35<br />
Carbon Number<br />
Figure 25. Predicted fish BCFs for iso-paraffins using the regression-based approach in<br />
BCFBAF. B – 2000, vB - 5000<br />
10000<br />
BCF (Arnot)<br />
1000<br />
100<br />
10<br />
i-Paraffins<br />
B<br />
vB<br />
1<br />
0<br />
0 5 10 15 20 25 30 35<br />
Carbon Number<br />
Figure 26. Predicted fish BCFs for iso-paraffins using Arnot’s equations incorporating<br />
metabolism (Arnot and Gobas 2003). B – 2000, vB - 5000<br />
33
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