EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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ioHCwin half-life (days) 100000.0 10000.0 1000.0 100.0 10.0 1.0 0 5 10 15 20 25 30 35 40 Carbon number 60 d half-life Figure 19. Half-life predictions for poly-aromatic hydrocarbons using the US EPA model BioHCwin Hydrocarbon C nr BioHCwin Predicted Half-Life (days) Measured Seawater Half-Life (days) Measured Freshwater Half-Life (days) fluorene 13 15.1 2.5 methylfluorene 14 24.2 4.2 phenanthrene 14 15.0 5.0 2.6 1-methylphenanthrene 15 23.9 2.8 2-methylphenanthrene 15 23.9 4.2 3-methylphenanthrene 15 23.9 4.2 9-methylanthracene 15 196.7 6.0 9-methylphenanthrene 15 23.9 4.2 fluoranthene 16 191.4 9.2 pyrene 16 283.4 151 1-methylpyrene 17 108.8 64.0 benzo(b)fluorene 17 347.6 4.2 1-methyl-7-(1methylethyl)- phenanthrene 18 56.0 20 9-n butylphenanthrene 18 22.2 72.0 benzo[a]anthracene 18 343.8 > 182 chrysene 18 343.8 > 182 m-terphenyl 18 6.7 15 o-terphenyl 18 6.7 > 182 triphenylene 18 343.8 > 182 7-methylbenz(a)anthracene 19 131.9 4.7 benzo(k)fluoranthene 20 284.7 11.4 26
enzo[a]pyrene 20 421.6 16.5 Table 10. Predicted and experimental marine and freshwater half-life values for polyaromatic hydrocarbons (in bold, structure names for which BioHCwin predicts half-lives above 60 days; rows in orange show experimental values above 60 days) 1000.0 Half-life predicted (days) 100.0 10.0 Freshwater P criterion 1.0 Marine Water 1.0 10.0 100.0 Half-life observed (days) Figure 20. BioHCwin (Y-axis) vs. experimental half-lives (X-axis) for poly-aromatic hydrocarbons 27
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Vacuum Gas Oils, Hydrocracked Gas O
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Gas Oils (Vacuum) 4 DNEL (inhalatio
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Industrial - Tabletting, CS100 Indo
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Combined Professional - Manual spra
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Industrial - Bulk transfers CS14 Da
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Professional - Maintenance and CS77
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Note: differentiated Industrial -SU
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Professional - Treatment and dispos
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Industrial - operation of open CS16
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Page 141 and 142: Vacuum Gas Oils, Hydrocracked Gas O
Page 145 and 146: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 147 and 148: Industrial - Tabletting, CS100 Indo
Page 149 and 150: Combined Professional - Manual spra
Page 151 and 152: Industrial - Bulk transfers CS14 Da
Page 153 and 154: Professional - Maintenance and CS77
Page 155 and 156: Note: differentiated Industrial -SU
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191: Hydrocarbon C nr BioHCwin Predicted
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216: and appears to be an outlier. This
Page 217 and 218: 4-ethylbiphenyl 14 863 1039 C Yakat
Page 219 and 220: 100000 BCF (regression) 10000 1000
Page 221 and 222: 10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224: Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226: Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228: Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230: 5.0 Summary of Persistence and Bioa
Page 231 and 232: lower water solubility, it is possi
Page 233 and 234: properties of petroleum hydrocarbon
Page 235 and 236: 8.0 References Anonymous (2004). Fi
Page 237 and 238: EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240: Prince RC, Walters CC. (2007). Biod
Page 241 and 242: Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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