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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels APPENDIX 4: An Evaluation of the Persistence, Bioaccumulation and Toxicity of Petroleum Hydrocarbons 2010-07-30 CSR Appendix 4
An Evaluation of the Persistence, Bioaccumulation and Toxicity of Petroleum Hydrocarbons Report Prepared for CONCAWE Brussels, Belgium by Mark Lampi a , Miriam Léon Paumen b , Tom Parkerton a a ExxonMobil Biomedical Sciences, Inc., Annandale NJ, USA b ExxonMobil Petroleum and Chemical, Machelen, Belgium March 2010
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EU-SICHERHEITSDATENBLATT gemäß Ve
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Vacuum Gas Oils, Hydrocracked Gas O
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Page 115 and 116: Vacuum Gas Oils, Hydrocracked Gas O
Page 123 and 124: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 125 and 126: Industrial - Tabletting, CS100 Indo
Page 127 and 128: Combined Professional - Manual spra
Page 129 and 130: Industrial - Bulk transfers CS14 Da
Page 131 and 132: Professional - Maintenance and CS77
Page 133 and 134: Note: differentiated Industrial -SU
Page 135 and 136: Professional - Treatment and dispos
Page 137 and 138: Industrial - operation of open CS16
Page 145 and 146: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 147 and 148: Industrial - Tabletting, CS100 Indo
Page 149 and 150: Combined Professional - Manual spra
Page 151 and 152: Industrial - Bulk transfers CS14 Da
Page 153 and 154: Professional - Maintenance and CS77
Page 155 and 156: Note: differentiated Industrial -SU
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 165: This tool is provided for informati
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
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Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206: BCF (regression) 100000 10000 1000
Page 207 and 208: 4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210: Experimental BMF 10 1 Polynaphth. D
Page 211 and 212: enzene n-octylbenzene 14 0.034 403
Page 213 and 214: 10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216: and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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