EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

This tool is provided for informational purposes only and may be used at the user's
own risk. Consequently you should not act, or refrain from acting, based solely on
the information provided within this tool. This is intended to be a screening tool and
is not a substitute for and should not be relied upon in place of appropriate technical
advice, more refined knowledge of consumer exposure information, or common
sense.
Gasoils [vacuum] (VP>10Pa)
DNEL bands
Saturated
Substance
Molecular
Physical
Substance
Gasoils
Substance
TRA volatility
Vapour
Band1 (very
Name
Weight
5000.0 property liquid
300000.0
high
605474396.8
Properties:
(vacuum)
volatility (Pa):
range
Concentration
low)
(g/mole)
(mg/m3)
Common Thickness
Density
Life Cycle
Parameter Layer (cm) 0.01 (g/cm3) 1.0 Body Weight 60.0 Inhalation Rate 1.4 fraction released to
Stage / Sector
Consumer
Band2 (low)
Defaults:
(m3/hr)
of Use
(SU21)
References
dermal longterm
systemic
(mg/cm2)
dermal local
oral long-term
inhalation
inhalation long-term
inhalation local
Values
10.0
systemic
systemic
systemic (mg/m3)
61.20
(mg/m3)
Band3 (Medium)
(DNELs):
(mg/kg/day)
(mg/kg/day)
(mg/kg/24 hr day)
for 24 hr day
inhalation dermal/ oral
(mg/m3) (mg/kg/day)
[0.5, 5)
[0.1, 1)
[5, 25)
[1, 5)
[25, 100)
[5, 20)
Band4 (High)
>=100
>=20
Table 1: Mapping Consumer Uses in the Supply Chain Table 2b: Characterising the Risk - after refinement of exposure estimate
all all
dermal dermal dermal dermal oral inhalation inhalation inhalation inhalation inhalation inhalation inhalation
Relevant Use Sentinel Product sub Category
Generic Exposure Scenario TIER1 Predicted Exposure - ECETOC TRA based on defaults
Risk Characterization based on defaults
TIER1+ ECETOC TRA - exposure modifiers
Product
Sentinels
dermal oral
inhalation
TRA Tier 1+ Predicted Exposure - ECETOC TRA - refined estimates
Local Use
On Day of Use
TRA Tier1+ Risk Characterization - refined estimates
Chronic Considering Yearly Use
Frequency
Operation Conditions (OCs) Risk Management Measures (RMMs)
Risk Characterization - including RMMs
when needed (substance Specific)
TRA+ Predicted Exposure - including RMM
when needed (substance specific)
Chronic
Predicted Predicted Oral Predicted Predicted Predicted Total Predicted
Predicted Predicted Predicted Predicted Predicted Predicted Mean Inhalation Mean Inhalation Mean Inhalation Total RCR dermal RCR RCR systemic RCR systemic RCR systemic RCR systemic RCR systemic
RMMs for communication - Consolidate into Indicator RCR RCR RCR Predicted Predicted Oral Predicted
PCS Subcategories PEC PEC PEC DNEL Total RCR DNEL Total RCR DNEL Total RCR DNEL Total RCR
Dermal Exposure Inhalation Inhalation Inhalation Exposure
Dermal Dermal Dermal Oral Oral Inhalation Event Concentration Concentration Predicted local (based systemic (24hr TWA (all routes, (dermal, (inhalation, (all routes,
GES or e-SDS
for Basis of systemic systemic systemic (all Dermal Exposure Inhalation
(dermal) (oral) (inhalation) BAND1
BAND2
BAND3
BAND4
Exposure (mg/kg/d) Exposure Exposure Exposure - upper (mg/kg/d)
Dilution Factor
Exposure, Exposure, Exposure, Exposure, Exposure, Exposure, Concentration (24hr TWA) on Yearly (mg/m3) Exposure on mg/cm2) (dermal, inhalation daily) chronic, based yearly, based chronic)
REACH ADVISED: phrase [RMM code] Exposure (dermal, (inhalation routes) Exposure (mg/kg/d) Exposure
(mg/kg/d)
(mg/kg/d) (mg/m 3 ) bounded with SVC
RCR (all
Inhalation Factor (fraction Location
incorporating
RCR RCR (SVC-upper
Frequency (events per
Daily (mg/kg/d) Chronic Local daily Chronic daily (mg/m 3 ) Day of Exposure
(mg/kg/d) -
daily, based mg/m3)
on mg/kg/d)) on mg/m3)
Recommended: {phrase [RMM code].} Estimate based on based on
(mg/kg/d)
(mg/m3)
Area of
Short Title
(mg/m 3 RCR
routes - sum of Product ingredient (weight fraction)
Skin surface contact area
Glove
of total use (indoors,
Air Exchange
)
RCR (oral) (inhalation bounded
day): if < 1, only used for
Use Dilution Factor Dermal Factor
Amount Used per event (g)
Room Volume (m3) Exposure time (hours)
(mg/kg/d) (mg/cm2) (mg/kg/d) (mg/kg/d) (mg/kg/d)
(mg/m3)
day of use for
on mg/kg/d))
mg/kg/d)) mg/m3)
Application / UD
(dermal)
mg/kg/day
(g/g)
(cm 2 Amount Swallowed (g)
Air Exchange Rate (1/hr)
)
effiency
spilled/evaporated, i.e., outdoors,
Rate applied to
mg/kg/day) inhalation mg/m3)
chronic assessment
TRA
values)
amount lost) garage)
TRA for mg/kg
comparison
inhalation calc.
only
Value Comments Value Comments Value Comments Value Comments Value Comments Value Comments Value Comments Value Comments Value Comments Value Comment Value Comments dayofuse chronic event dayofuse chronic dayofuse event dayofuse chronic 1.3 61.2 1.3 61.2 d i t d o i c c c
Consumerl-SU21 PC13:Fuels
71.5 0 11416.7 125000.0 125000.0 11488 54.97 #DIV/0! #DIV/0! 2042.48 #DIV/0! 1 increased above 0.14 est. as 1 per 210.00 est. as palm of
TRA default
week
one hand
Liquid - Automotive
Refuelling
Consumerl-SU21 PC13:Fuels
71.5 0 11416.7 125000.0 125000.0 11488 54.97 #DIV/0! #DIV/0! 2042.48 #DIV/0! 1 increased above 0.33 daily use 210.00 est. as palm of
TRA default
assumed
one hand
over Winter
period (4
months)
Liquid - Home
heating oil
Consumerl-SU21 PC13:Fuels
71.5 0 11416.7 125000.0 125000.0 11488 54.97 #DIV/0! #DIV/0! 2042.48 #DIV/0! 1 increased above 0.07 est. as 1 per
TRA default
two weeks
Liquid - Garden
Equipment - Use
Consumerl-SU21 PC13:Fuels
71.5 0 11416.7 125000.0 125000.0 11488 54.97 #DIV/0! #DIV/0! 2042.48 #DIV/0! 1 increased above 0.07 est. as 1 per 420.00 Est. half of each
TRA default
two weeks
hand
Liquid - Garden
Equipment - Refueling
0.1000 Assumed value
37500 est. fuel tank size 50 0.0100 expect low % outdoor 0.60 est. 0.99 100 Stoffenma 0.050 3mins, 97th 3.50 0.50 1.00 0.00 0.00 4.22 3694.31 7.70 1.101 7.72 0.10 2.69 0.13 2.82 0.39 0.02 0.40 Unless otherwise stated, covers concentrations up to 100% [ConsOC1]; No specific RMMs developed beyong those Based upon 0.39 0.02 0.40 0.50 0.00 1.10 PC13:Fuels
0.50 0.00 1.10 0.00 0.00 0.00 0.00
of no >10%
L converted using
loss during
conservative
nager
percentile-
covers use up to 52 days/year[ConsOC3]; covers use up to 1 time/on OCs stated
infrequent
transfered from
gasoline density of
refueling due to
value for
volume
Vainiotalo et
day of use[ConsOC4]; covers skin contact area up to 210.00 cm2
use (10%
L converted using
loss during typical
general fact
default
as shorter
covers use up to 120 days/year[ConsOC3]; covers use up to 1 time/on OCs stated
infrequent
transfered from
gasoline density of
refueling due to
sheet
than vehicle
day of use[ConsOC4]; covers skin contact area up to 210.00 cm2
use (10%
based upon density
loss during
conservative
nager
per day
covers use up to 26 days/year[ConsOC3]; covers use up to 1 time/on OCs stated
daily use
transfered from
for mogas = 750
equipment use
value for
volume
day of use[ConsOC4]; for each use event, covers use amounts up to
contaminated
kg/m3.
outdoor
used for
750g [ConsOC2]; covers outdoor use [ConsOC12]; covers use in room
pump handle to
outdoors
size of 100m3[ConsOC11]; for each use event, covers exposure up to
2.00hr/event[ConsOC14];
Liquid - Garden
Equipment - Use
0.1000 Assumed value
750 1 L: Conv from L to g 0.0300 expect low % garage 1.50 RIVM 0.98 34 RIVM 0.030 Est. 2mins 7.00 0.49 1.00 0.00 0.00 0.44 647.10 0.81 0.057 7.44 0.10 5.38 0.01 5.40 0.38 0.00 0.38 Unless otherwise stated, covers concentrations up to 100% [ConsOC1]; No specific RMMs developed beyong those Based upon 0.38 0.00 0.38 0.49 0.00 0.06 PC13:Fuels
0.49 0.00 0.06 0.00 0.00 0.00 0.00
of no >10%
based upon density loss but may be
general fact
general
covers use up to 26 days/year[ConsOC3]; covers use up to 1 time/on OCs stated
infrequent
transfered from
for mogas = 750
more from pouring
sheet
fact sheet
day of use[ConsOC4]; covers skin contact area up to 420.00 cm2
use (