EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Industrial - General exposures CS16 Daily; Indoor; 15 - 1 Enclosed transfers, clear PROC4 Batch >4 hours, ambient SU3/ SU10 open batch process, hour; product temp. lines prior to decoupling process with temp. including open EDM exposure processes Industrial -SU3 Bulk transfers CS14 Indoor, Daily; 15 mins - Enclosed transfers, clear PROC8b daily; ambient 1 hour; product temp lines prior to decoupling Dedicated temp. (ambient) discharging to/from vessels Combine in Industrial -SU3 Filling preparation of CS45 Indoor, Daily; 15 mins - Pumped transfer or use PROC8b 4 hours; ambient equipment from drums 1 hour; product temp of dedicated container. blending in batch temp. or containers (CS45) - (ambient) Eye protection, Gloves, process (ATIEL identified 3 Apron PROCs for this activity) Industrial -SU3 Filling preparation of CS45 Indoor, Daily; 15 mins - Pumped transfer or use PROC9 Dedicated >4 hours, ambient equipment from drums 1 hour; product temp of dedicated container. filling line temp. or containers (ATIEL (ambient) Eye protection, Gloves, identified 3 PROCs for Apron this activity) Industrial -SU3 Process sampling. CS2 Indoor, Daily; 15 mins - Dedicated pipette. No PROC3 Closed >4 hours, ambient Drawing sample into a 1 hour; product temp hand immersion. PPE batch process (with temp. pipette for testing (ambient) sampling) Industrial -SU3 Metal Machining CS79 Indoor, Daily; 8 hours; Restrict area of PROC 17 >4 hours, ambient Operations product temp (ambient) openings; extract Lubrication at high temp. ventilation to emission energy conditions points; PPE Industrial -SU3 Treatment of articles by CS35 Indoor, Daily; 8 hours, Cabinet to allow the PROC 13 Dipping >4 hours, ambient dipping and pouring product temp (ambient), dipping and the dripping and pouring temp. automatic dipping in a of the pieces. PPE bath Combine in narrative Industrial -SU3 Spraying CS10 Indoor, Daily; 8 hours, LEV, Spraying cabinet PROC 7 >4 hours, ambient product temp (ambient), with capture of the temp. automated spraying aerosols, PPE Vapour phase Industrial -SU3 >4 hours, ambient temp. Industrial -SU3 Manual roller CS13 Indoor, Daily; 8 hours, PPE PROC 10 Roller or >4 hours, ambient application or brushing product temp (ambient), brush application temp. Automated replenishment of roller or brush Elevated Industrial -SU3 Automated metal CS80 Indoor. Continuous; Enclosed vented cabinet PROC2 >4 hours, ambient temperature rolling/forming daily; 8hour; elevated with blow off system to temp. therefore applied temperature (120 deg contain mist/vapour; value for medium C) from rolling product recovery and volatility operation; Remote recirculation; Gloves, operation eye protection, overalls. Elevated Industrial -SU3 Semi-automated metal CS83 Indoor. Continuous; LEV canopy; product PROC 17 - >4 hours, ambient temperature rolling/forming daily; 8hour; elevated recovery and lubrication at high temp. therefore applied temperature (120 deg recirculation; Gloves, energy conditions value for medium C) from rolling eye protection, overalls. and in partly open volatility operation; manual process intervention Vapour phase. Industrial -SU3 >4 hours, ambient temp. Industrial -SU3 Oil/water-based PROC4 Open >4 hours, ambient batch process (with temp. sampling) With LEV 5 90 0.5 0.69 0 0.69 0.01 0.00 0.01 Ensure material transfers are under containment or extract ventilation. E66 Provide extract ventilation to points where emissions occur E54 Wear suitable gloves tested to EN374 PPE15 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed system. E47 Operate activity from way from sources of substance emission or release E77 Ensure material transfers are under containment or extract ventilation. E56. Wear chemically resistant gloves (tested to EN374) PPE15 Avoid splashing C&H15 No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Transfer via enclosed lines E52 Use drum pumps or carefully pour from container E64 Wear gloves tested to EN374 PPE15 No LEV 5 0 5 13.71 90 1.371 0.07 0.47 0.55 Transfer via enclosed lines E52 Use drum pumps or carefully pour from container E64 Provide good GV E11 Wear gloves tested to EN374 with basic training PPE16 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Ensure material transfers are under containment or extract ventilation. E66 Wear suitable gloves tested to EN374 PPE15 No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 No special precuations EI18 Ensure samples are obtained under containment or extract ventilation E76 Wear suitable gloves tested to EN374 PPE15 Avoid dip sampling E42 With LEV 50 90 5 90% ventilation 1.37 0 1.37 0.07 0.47 0.55 Minimise exposure by partial enclosure reflceted in E60 of the operation or equipment and phrase; provide extract ventilation at openings E60 Provide a good standard of general ventilation (3 to 5 air changes per hour) .E11 Wear suitable gloves tested to EN374 PPE15 No LEV 1 0 1 6.86 80 1.372 0.01 0.47 0.49 Provide extract ventilation to points where emissions occur E54. Allow time for product to drain from work pieces EI21 Automate activity where possible AP16 Wear chemically resistant gloves (tested to EN374) PPE15 Avoid manual contact with wet work pieces With LEV 20 95 1 2.14 80 0.43 0.01 0.15 0.16 Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings E60 provide GV E11 Automate activity where possible AP16 Wear a respirator conforming to EN140 with Type A/P2 filter or better PPE29. Wear gloves tested to EN374, coveralls and eye protection PPE23 With LEV 100 95 5 2.14 80 0.43 0.71 0.15 0.86 Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings E60 provide enhanced GV E48 Automate activity where possible AP16 Wear a respirator conforming to EN140 with Type A/P2 filter or better PPE29. Wear gloves tested to EN374, coveralls and eye protection PPE23 No LEV 5 0 5 27.43 95 1.37 0.07 0.47 0.55 Wear suitable gloves tested to EN374 with specific employee training PPE17 Provide a good standard of general ventilation E11 Use long handled brushes and rollers where possible.E58 With LEV 1 90 0.1 0.14 0 0.14 0.00 0.05 0.05 Handle substance within a closed system E47 Provide extract ventilation to points where emissions occur E54 With LEV 50 95 2.5 1.37 0 1.37 0.04 0.00 0.04 Provide extract ventilation to points where emissions occur E54. Restrict area of openings to equipment E68 Wear chemically resistant gloves (tested to EN374) PPE15 Segregate the activity away from other operations E63 With LEV 50 95 2.5 1.37 0 1.37 0.36 0.47 0.83 Provide extract ventilation to points where emissions occur E54. Restrict area of openings to equipment E68 Wear chemically resistant gloves (tested to EN374) PPE15 Segregate the activity away from other operations E63 With LEV 5 90 0.5 0.69 0 0.69 0.01 0.00 0.01 Ensure material transfers are under containment or extract ventilation. E66 Provide extract ventilation to points where emissions occur E54 Wear suitable gloves tested to EN374 PPE15
Note: differentiated Industrial -SU3 Equipment cleaning CS39 Indoor, Daily; 1 - 4 Enclosed transfer, clear PROC8b dedicated and nondedicated facility for Dedicated facility CS81 retain drainings in sealed discharging to/from and maintenance - hours; ambient temp. lines prior to decoupling; Dedicated equipment cleaning - storage pending vessels both identified by disposal. PPE ATIEL - combined in narrative as CS39 Industrial -SU3 Equipment cleaning Indoor, Daily; 1 - 4 Collect waste and retain PROC8a and maintenance -Nondedicated facility storage pending to/from vessels hours; ambient temp. drainings in sealed Discharging (CS82) disposal. PPE Industrial -SU3 Material Storage CS67 Continuous; daily; 8hour Enclosed process; PROC1/2 Closed closed/semi-closed continuous process sampling point (sometimes with sampling) Use as binders and Industrial -SU3 Bulk transfers from CS3 Daily; 1 - 4 hours; Enclosed transfers, clear PROCs 1-3 release agents storage to mixing ambient temp. lines prior to decoupling contained vessels processes Industrial -SU3 Transfers to mixing CS8 Daily; 15 mins - 1 hour; Pumped transfer from PROC8b vessels from drums ambient temp drum to holding tanks. Discharging to/from vessels Industrial -SU3 Mixing / blending of CS29 Daily; >4 hours Enclosed or ventilated PROC3 Closed foundry sands with mixing vessel batch process (with binder sampling) Industrial -SU3 Mixing / blending of CS30 Daily; >4 hours Enhanced general PROC4 Open foundry sands with ventilation batch process (with binder sampling) Industrial -SU3 Forming moulds from CS31 Daily; >4 hours, ambient PPE PROC14 foundary sand temp Production by tabletting, compression, Combine in narrative Industrial -SU3 Emissions from casting CS32, CS108 Daily; 1 - 4 hours; Enhanced general PROC6 Open into moulds elevated temp.sufficient ventilation, PPE processing at to create fume elevated temperature Industrial -SU3 Emissions from casting CS32, CS108 Daily; 1 - 4 hours; Enhanced general PROC6 Open into moulds (vapour elevated temp.sufficient ventilation, PPE processing at phase) to create fume elevated temperature Combine in narrative Industrial -SU3 Applying release agent CS10, CS33 Daily; 1 - 4 hours; Enclosed or ventilated PROC7 to moulds and ambient temp. production line. Application by shuttering Automation. spraying Industrial -SU3 Applying release agent CS10, CS33 Daily; 1 - 4 hours; Enclosed or ventilated PROC7 to moulds and ambient temp. production line. Application by shuttering (vapour Automation. spraying phase) Industrial -SU3 Applying release agent CS13 Daily; 1 - 4 hours; PPE PROC10 Roller to moulds and ambient temp. application and shuttering brushing Combine in narrative Industrial -SU3 Applying release agent CS10, CS34 Daily; 1 - 4 hours; PPE, face mask PROC7 to moulds and ambient temp. Application by shuttering spraying Industrial -SU3 Applying release agent CS10, CS34 Daily; 1 - 4 hours; PPE, face mask PROC7 to moulds and ambient temp. Application by shuttering (vapours) spraying Industrial - maintenance of CS5 Daily; 1-4 hours, work methods, drain prior PROC8a SU10 equipment ambient to work, retain spills, Discharging gloves to/from vessels (non-dedicated) Industrial -SU3 Storage CS67 Daily; 8 hrs; ambient samples collected at PROC1/2 Closed temp; dedicated sample point continuous process (sometimes with li ) Oil and gas field Industrial - SU3 Bulk transfers from tote CS14 Daily; 15 - 1 hour; Enclosed transfers, clear PROCs 1-3 chemicals tanks and supply product temp (ambient). lines prior to decoupling contained vessels processes Industrial - SU3 Charge from drums CS45 Daily; 15 mins - 1 hour; Pumped transfer from PROC8b product temp (ambient) drum to holding tanks. Discharging to/from vessels (dedicated) Industrial - SU3 Drilling mud (re-) CS512 Daily; 1-4 hour; product Closed equipment, PROC3 Closed formulation temp (ambient); indoor enclosed or vented batch process with sampling points sampling Industrial - SU3 Drill floor operations CS513 Daily; 1-4 hour per PPE PROC4 Batch operator; product temp process with (ambient), outdoors exposure Combine Industrial - SU3 Operation of solids CS514 Daily; >4 hours; indoor; Local exhaust ventilation PROC4 Batch filtering equipment product temperature process with elevated temperature approx. 60 dC exposure > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours; daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. 1-4 hours, ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours daily; ambient temp. > 4 hours; daily; elevated product temperature No LEV 5 80 1 SOPs assumed 13.71 90 1.37 0.01 0.47 0.49 Drain down system prior to equipment to offer break-in or maintenance E55 Good GV equivalent LEV E40 Transfer via enclosed lines E52 effic shown Wear chemically resistant gloves (tested to EN374) PPE16 Retain drain downs in sealed storage pending disposal or for subsequent recycle. ENVT4 Drain down system prior to equipment No LEV 5 80 1 SOPs assumed 13.71 90 1.37 0.01 0.47 0.49 to offer break-in or maintenance E55 Good GV equivalent LEV E40 Transfer via enclosed lines E52 effic shown Wear chemically resistant gloves (tested to EN374) PPE16 Retain drain downs in sealed storage pending disposal or for subsequent recycle. ENVT4 outdoor activity 0.5 0 0.5 0.14 0 0.14 0.01 0.05 0.06 Store substance within a closed system. E84 Transfer via enclosed lines. E52 Avoid dip sampling E42 No LEV 3 0 3 1.37 0 1.37 0.04 0.47 0.52 Handle within contained systems E47 Ensure material transfers are under containment or extract ventilation E66 wear gloves PPE15 clear lines prior to decoupling E39 remote vent vapours ENVT17 With LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Use drum pumps E53 Wear gloves (80%) PPE15 Avoid spillage on withdrawal C&H16 GV E40 No LEV 3 0 3 1.37 0 1.37 0.04 0.47 0.52 No psecial measures EI18 Use GV E11 wear gloves PPE15 Provide extract ventilation to points where emissions occur E54 No LEV 5 0 5 13.71 90 1.37 0.07 0.47 0.55 Provide GV E11 Wear gloves (90%) PPE16 Provide extract ventilation to points where emissions occur E54 No LEV 5 0 5 3.43 80 0.69 0.07 0.24 0.31 Provide GV E11 Wear gloves (90%) PPE16 Provide extract ventilation to points where emissions occur E54 With LEV 25 90 2.5 1.37 80 0.27 0.04 0.09 0.13 Wear gloves (80%) PPE15. Apply extract ventilation to emissions E60 apply GV E11 With LEV 5 90 0.5 1.37 0 1.37 0.07 0.47 0.54 Apply extract ventilation to emissions. E60 apply GV E11 With LEV 20 90 2 Use of E57 2.14 80 0.43 0.03 0.15 0.18 Carry out in a vented booth or equates to 90% extracted enclosure. E57 wear gloves PPE15 automate AP16 Segregate the activity away from other operations E63 Apply ventilation or undertake in With LEV 100 90 10 Use of E57 2.14 80 0.43 0.15 0.15 0.29 equates to 90% ventilated enclosure. E61 wear gloves PPE15 automate AP16 With LEV 5 0 5 27.43 95 1.37 0.07 0.47 0.55 Apply extract ventilation to emissions. E54 Wear gloves (95%). PPE17 good GV E11 No LEV 100 95 5 42.86 95 2.14 0.07 0.74 0.81 Good GV E11 Wear RPE (APF=20) APF=20 defines LEV value; and gloves (95%) PPE24, PPE23 specific activity Segregate E63 Ensure operatives are training (0.85x) trained to minimise exposures EI19 No LEV 100 95 5 APF=20 defines 42.86 95 2.14 0.07 0.74 0.81 Good GV E11 Wear RPE (APF=20) LEV value; and gloves (95%) PPE24, PPE23 specific activity Segregate E63 Ensure operatives are training (0.85x) trained to minimise exposures EI19 No LEV 5 0 5 13.71 90 1.37 0.07 0.47 0.55 SOP re drain downs.E65 Enclosed transfers E52 Wear gloves (90%) PPE16 outdoor activity 0.5 0 0.5 0.14 0 0.14 0.01 0.05 0.06 Store substance within a closed system. E84 Avoid dip samples E42 No LEV 3 0 3 1.37 0 1.37 0.04 0.47 0.52 Handle within contained systems E47 Ensure material transfers are under containment or extract ventilation E66 wear gloves PPE15 clear lines prior to decoupling E39 remote vent vapours ENVT17 With LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Use drum pumps E53 Wear gloves (80%) PPE15 Avoid spillage on withdrawal C&H16 GV E40 No LEV 3 0 3 1.37 0 1.37 0.04 0.47 0.52 No psecial measures EI18 Use GV E11 wear gloves PPE15 Handle substance within a predominantly closed system provided with extract ventilation E49 No LEV 5 0 5 13.71 90 1.37 0.07 0.47 0.55 Use outdoors E69 Wear gloves (90%) PPE16 Wear suitable coveralls capable of preventing penetration of the substance PPE27 Wear rubber boots PPE28 With LEV. 25 90 2.5 0.69 0 0.69 0.04 0.24 0.27 Provide the operation with a properly sited receiving hood E71. Recirculation of exhaust air is not recommended E80 Ensure the ventilation system is regularly maintained and tested (E74). Wear suitable gloves tested to EN374 PPE15 0
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EU-SICHERHEITSDATENBLATT gemäß Ve
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Vacuum Gas Oils, Hydrocracked Gas O
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Page 103 and 104: Vacuum Gas Oils, Hydrocracked Gas O
Page 123 and 124: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 125 and 126: Industrial - Tabletting, CS100 Indo
Page 127 and 128: Combined Professional - Manual spra
Page 129 and 130: Industrial - Bulk transfers CS14 Da
Page 131 and 132: Professional - Maintenance and CS77
Page 133 and 134: Note: differentiated Industrial -SU
Page 135 and 136: Professional - Treatment and dispos
Page 137 and 138: Industrial - operation of open CS16
Page 145 and 146: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 147 and 148: Industrial - Tabletting, CS100 Indo
Page 149 and 150: Combined Professional - Manual spra
Page 151 and 152: Industrial - Bulk transfers CS14 Da
Page 153: Professional - Maintenance and CS77
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198: 10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200: exhibit BMFs near unity (Figure 28)
Page 201 and 202: 2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204: Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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