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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Industrial - Tabletting,<br />

CS100 Indoor; daily; 8 hours; LEV, PPE PROC14<br />

SU3/ SU10 compression, extrusion<br />

product temp.<br />

Production of<br />

or pelletisation<br />

preparation by<br />

tabletting,<br />

compression,<br />

Industrial - Drum and small CS6 Indoor, Continuous; Enclosed transfers, PROC9 Transfer<br />

SU3/ SU10 package filling<br />

daily; 8 hour; product vented transfer points of<br />

temp.<br />

substance/mixture<br />

into small<br />

containers<br />

Industrial - Clean down and CS39 Indoor, Daily; 1 - 4 Enclosed lines; retain PROC8a Nondedicated<br />

SU3/ SU10 Maintenance<br />

hours; product temp; wash down in sealed<br />

collection of line waste storage pending disposal discharging to/from<br />

in container<br />

or use as recycled vessels<br />

material for subsequent<br />

formulation. PPE.<br />

Industrial - Storage CS67 Daily; 8 hrs; product samples collected at PROC1/2 Closed<br />

SU3/ SU10<br />

temp;<br />

dedicated sample point continuous process<br />

(sometimes with<br />

sampling)<br />

Uses in Coatings Industrial -SU3 General exposures CS15 ] Continuous; daily; 8hour Enclosed process; 1/2 -Use in closed,<br />

(closed systems) CS15 [CS56]<br />

closed/semi-closed continuous<br />

] with sample collection<br />

sampling point<br />

process with occasional<br />

controlled<br />

[CS56].<br />

exposure (e.g.<br />

sampling)<br />

Industrial - Bulk transfers CS14 Daily; 15 min - 1 hour; Enclosed transfers, PROC8b<br />

SU3/ SU10<br />

product temp; collection vented transfer points; Dedicated<br />

of line waste in container clear lines prior to discharging to/from<br />

decoupling<br />

vessels<br />

Industrial -SU3 Film formation - force [CS 94] enclosed in situ in 2 -Use in closed,<br />

drying (50 - 100°C).<br />

workplace<br />

continuous<br />

Stoving (>100°C).<br />

process with occasional<br />

controlled<br />

UV/EB radiation curing.<br />

[CS 94]<br />

exposure (e.g.<br />

sampling)<br />

Industrial -SU3 Film formation - air [CS95] 4 - Use in batch<br />

drying. [CS95]<br />

and other process<br />

(synthesis) where<br />

opportunity for<br />

exposure arises<br />

Industrial -SU3 Preparation of material [CS 96]<br />

liquid/ powder products) - 5 - Mixing or<br />

for application. [CS 96] [CS30]<br />

batch, indoor/ outdoor. blending in batch<br />

Mixing operations (open<br />

processes for<br />

systems) [CS30]<br />

formulation of<br />

preparations and<br />

combine Industrial -SU3 Spraying<br />

[CS97] Daily; >4 hours, product Enclosed. Vented spray 7 -Industrial<br />

(automatic/robotic).<br />

temp (ambient) booth; specific workforce spraying<br />

[CS97]<br />

education, PPE<br />

Industrial -SU3 Spraying<br />

[CS97] Daily; >4 hours, product Enclosed. Vented spray 7 -Industrial<br />

(automatic/robotic).<br />

temp (ambient) booth; specific workforce spraying<br />

[CS97] vapours<br />

education, PPE<br />

combine Industrial -SU3 Manual spraying. [CS24] Open , Air supplied 7 -Industrial<br />

[CS24]<br />

masks, respirator. spraying<br />

Industrial -SU3 Manual spraying. [CS24] Open , Air supplied 7 -Industrial<br />

[CS24] vapours<br />

masks, respirator. spraying<br />

Industrial -SU3 Material transfers. CS3 Daily; 15 min - 1 hour; Enclosed transfers, 8b -Transfer of<br />

[CS3].<br />

product temp (ambient); vented transfer points; chemicals from/to<br />

collection of line waste clear lines prior to vessels/ large<br />

in container. outdoor/ decoupling<br />

containers at<br />

indoor.<br />

dedicated facilities.<br />

Industrial -SU3 Roller, spreader, flow [CS69] Daily; >4 hours, product Local exhaust ventilation 10 - Roller<br />

application. [CS69]<br />

temp. (ambient); Range at rollers; remove spills application or<br />

from 2-3% upto 40-50% as they occur, PPE. brushing<br />

Large scale (open<br />

equipment)<br />

daily; ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

>4 hours, ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

>4 hours, ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

>4 hours, ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

daily; ambient<br />

temp.<br />

> 4 hours; daily;<br />

ambient temp.<br />

> 4 hours; daily;<br />

ambient temp.<br />

daily; ambient<br />

temp.<br />

> 4 hours; daily;<br />

ambient temp.<br />

No LEV 5 0 5 3.43 80 0.69 0.07 0.24 0.31 Provide extract ventilation to points<br />

where emissions occur E54 Wear<br />

suitable gloves tested to EN374<br />

PPE15<br />

No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Fill containers/cans at dedicated fill<br />

points supplied with local extract<br />

ventilation E51 Clear spills<br />

immediately C&H13 Wear suitable<br />

gloves tested to EN374 PPE15 Put lids<br />

on containers immediately after use E9<br />

No LEV 10 80 2 LEV<br />

13.71 90 1.371 0.03 0.47 0.50 Apply vessel entry procedures<br />

effectiveness<br />

including use of forced supplied air.<br />

assumed to<br />

AP15 Drain down system prior to<br />

equate to SOP<br />

equipment break-in or maintenance<br />

relating to<br />

E65 Transfer via enclosed lines E52<br />

draining etc<br />

Wear suitable gloves tested to EN374<br />

prior to<br />

PPE16 Wear suitable coveralls to<br />

maintence<br />

prevent exposure to the skin PPE27<br />

Retain drain downs in sealed storage<br />

pending disposal or for subsequent<br />

recycle. ENVT4<br />

outdoor activity 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Store substance within a closed<br />

system. E84 Transfer via enclosed<br />

lines. E52 Avoid dip sampling E42<br />

No LEV 1 0 1.0 0.03 0 0.03 0.01 0.01 0.02 Handle substance within a closed<br />

system E47 Ensure material transfers<br />

are under containment or extract<br />

ventilation E66 Wear suitable gloves<br />

tested to EN374 PPE15<br />

No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed<br />

system. E47 Operate activity from<br />

way from sources of substance<br />

emission or release E77 Ensure<br />

material transfers are under<br />

containment or extract ventilation.<br />

E56. Wear chemically resistant gloves<br />

(tested to EN374) PPE15 Avoid<br />

splashing C&H15<br />

No LEV 10 30 7.0 1.37 0 1.37 Handle substance within a closed<br />

Good GV 0.10 0.47 0.57 system E47 Provide a good standard<br />

of general ventilation (3 to 5 air<br />

changes per hour) E11 Provide extract<br />

ventilation to point where emissions<br />

occur E54 Wear suitable gloves tested<br />

to EN374 PPE15<br />

No LEV 5 0 5.0 6.86 80 1.37 0.07 0.47 0.55 Provide a good standard of general<br />

ventilation (3 to 5 air changes per<br />

hour) E11. Avoid manual contact with<br />

wet work pieces EI17. Wear suitable<br />

gloves tested to EN374 PPE15.<br />

No LEV 5 0 5.0 13.71 90 1.371 0.07 0.47 0.55 Provide extract ventilation to points<br />

where emissions occur E54. Wear<br />

chemically resistant gloves (tested to<br />

EN374) in combination with ‘basic’<br />

employee training PPE16<br />

With LEV. 20 95 1.0 E60 = 95% 2.14 0 2.14 0.01 0.74 0.75 Minimise exposure by partial enclosure<br />

of the operation or equipment and<br />

provide extract ventilation at openings<br />

E60 Wear suitable gloves tested to<br />

EN374 PPE15. Provide GV E11<br />

With LEV. 100 95 5.0 E60 = 95% 2.14 80 0.43 0.71 0.15 0.86 Minimise exposure by partial enclosure<br />

of the operation or equipment and<br />

provide extract ventilation at openings<br />

[E60]. {Wear suitable gloves tested to<br />

EN374 [PPE15]}. Provide GV E11<br />

No LEV 20 90 2.0 RPE (APF=10)) 21.85 95 1.09 0.03 0.38 0.41 Provide enhanced GV E48 Wear a<br />

respirator conforming to EN140 with<br />

Type A filter or better. PPE22 Wear<br />

chemically resistant gloves (tested to<br />

type EN374) in combination with<br />

specific activity training PPE17 Ensure<br />

operatives are trained to minimise<br />

exposures EI19 Segregate the activity<br />

away from other operations E63<br />

No LEV 100 90 4.2 RPE (APF=10)) 21.85 95 1.09 0.60 0.38 0.98 Provide good GV E11 Wear a<br />

operator training<br />

respirator conforming to EN140 with<br />

(reduces<br />

Type A filter or better. PPE22 Wear<br />

exposure by<br />

chemically resistant gloves (tested to<br />

15%) : good GV<br />

type EN374) in combination with<br />

(0.7x)<br />

specific activity training PPE17 Ensure<br />

operatives are trained to minimise<br />

exposures EI19 Segregate the activity<br />

away from other operations E63<br />

No LEV 5 0 5.0 6.86 80 1.37 0.07 0.47 0.55 Provide general ventilation E11 Wear<br />

suitable gloves tested to EN374<br />

PPE15 Ensure material transfers are<br />

under containment or extract<br />

ventilation E66 Clear lines prior to<br />

decoupling E39 Use drum pumps or<br />

carefully pour from container E64<br />

With LEV. 5 0 5.0 27.43 95 1.37 0.07 0.47 0.55 Wear chemically resistant gloves<br />

(tested to EN374) in combination with<br />

specific activity training. PPE17<br />

Provide GV E11 Avoid splashing<br />

C&H15 Avoid manual contact with wet<br />

work pieces EI17.

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