EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

More documents

Recommendations

Info

Industrial - SU8/9/3 Combine in narrative Industrial - as Bulk Transfer SU3 CS14 unless differentiation required in practice Industrial - SU3 Industrial - SU3 Industrial - SU3 Industrial - SU3 Formulation & Industrial - (re)packing of SU3/SU10 substances and mixtures Combine in with Industrial - above row in SU3/ SU10 narrative Industrial - SU3/ SU10 Industrial - SU3/ SU10 Industrial - SU3/ SU10 Industrial - SU3/ SU3 Industrial - SU3/ SU10 Combine in narrative Industrial - SU3/ SU10 Industrial - SU3/ SU10 Combine in narrative Industrial - SU3/ SU10 Industrial - SU3/ SU10 Bulk transfers (closed CS501 Daily; 15 - 1 hour; systems) e.g bottom product temp.; loading Indoor/Outdoor Bulk closed loading and CS503 Outdoor; Daily; 15 - 1 unloading NEW CS hour; product temp.; (e.g. road/rail car exposure potential bottom during breaking of hose loading/unloading; connection marine vessel/barge loading/unloading;) Bulk open loading NEW CS503 Outdoor; Daily; 1 - 4 CS (e.g. road/rail car hours; product temp; top loading, may exposure potential from involve LEV) vapour emissions from tank opening Drum and small CS6 Indoor; Continuous; package filling daily; 8 hour; product temp. Clean down and CS39 Daily; 15 min - 1 hour; Maintenance product temp; collection of line waste in container Storage CS67 Daily; 8 hrs; product temp; Outdoors General process CS15 Continuous; daily; 15 - 1 exposures (no hour; product temp. sampling) (e.g. In-line additive dosing equipment, in-line filter cleaning) General process CS15 Continuous; daily; 15 exposures and sample mins - 1 hour collection General process exposures (e.g. In-line additive dosing equipment, in-line filter cleaning) CS15 Batch process; daily; 15 - 1 hour; product temp. General exposures CS16 Daily; Indoor; 15 - 1 open batch process hour; product temp. Sample collection CS2 Daily; 4 hours, ambient temp. >4 hours, ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. >4 hours, ambient temp. >4 hours, ambient temp. >4 hours, ambient temp. >4 hours, ambient temp. >4 hours, ambient temp. >4 hours, ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed system. E47 Operate activity from way from sources of substance emission or release E77 Ensure material transfers are under containment or extract ventilation. E56. Wear chemically resistant gloves (tested to EN374) PPE15 Avoid splashing C&H15 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Ensure material transfers are under containment or extract ventilation E66 Clear transfer lines prior to decoupling E38 Ensure operation is undertaken outdoors E69 Wear suitable gloves tested to EN374. PPE15. No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Ensure material transfers are under containment or extract ventilation E66 Clear transfer lines prior to decoupling E38 Ensure operation is undertaken outdoors E69 Wear suitable gloves tested to EN374. PPE15. No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Fill containers/cans at dedicated fill points supplied with local extract ventilation E51 Clear spills immediately C&H13 Wear suitable gloves tested to EN374 PPE15 Put lids on containers immediately after use E9 No LEV 10 80 2 LEV 13.71 90 1.37 0.03 0.47 0.50 Apply vessel entry procedures effectiveness including use of forced supplied air. assumed to AP15 Drain down system prior to equate to SOP equipment break-in or maintenance relating to E65 Transfer via enclosed lines E52 draining etc Wear suitable gloves tested to EN374 prior to PPE16 Wear suitable coveralls to maintence prevent exposure to the skin PPE27 Retain drain downs in sealed storage pending disposal or for subsequent recycle. ENVT4 outdoor activity 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Store substance within a closed system. E84 Transfer via enclosed lines. E52 Avoid dip sampling E42 Closed process. 0.01 0 0.01 0.03 0 0.03 0.00 0.01 0.01 No special measures EI18 Handle substance within a closed system. E47 No LEV 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Handle substance within a closed system. E47 Ensure material transfers are under containment or extract ventilation E66 No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 Handle substance within a closed system. E47 Ensure material transfers are under containment or extract ventilation E66 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Ensure material transfers are under containment or extract ventilation [E66] Clear transfer lines prior to decoupling E39 Wear gloves tested to EN374 PPE15 No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 No special precuations EI18 Ensure samples are obtained under containment or extract ventilation E76 Wear suitable gloves tested to EN374 PPE15 Avoid dip sampling E42 No LEV 5 0 5 0.34 0 0.34 0.07 0.12 0.19 No special precuations EI18 Handle in a fume cupboard or under extract ventilation E83 Wear suitable gloves tested to EN374. PPE15. No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed system. E47 Operate activity from way from sources of substance emission or release E77 Ensure material transfers are under containment or extract ventilation. E56. Wear chemically resistant gloves (tested to EN374) PPE15 Avoid splashing C&H15 No LEV 5 0 5 13.71 90 1.37 0.07 0.47 0.55 Provide extract ventilation to points where emissions occur E54 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training. PPE16 With LEV 25 90 2.5 0.07 0 0.07 0.36 0.02 0.38 Provide extract ventilation to points where emissions occur E54 Wear suitable gloves tested to EN374 PPE15 No LEV 10 80 2 13.71 90 1.37 0.03 0.47 0.50 Use drum pumps or carefully pour from Use drum pumps container E64 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training. PPE16 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Provide extract ventilation to points where emissions occur E54 Use drum pumps or carefully pour from container. E64 Avoid spillage when withdrawing pump. C&H16 Wear suitable gloves tested to EN374 PPE15
Industrial - Tabletting, CS100 Indoor; daily; 8 hours; LEV, PPE PROC14 SU3/ SU10 compression, extrusion product temp. Production of or pelletisation preparation by tabletting, compression, Industrial - Drum and small CS6 Indoor, Continuous; Enclosed transfers, PROC9 Transfer SU3/ SU10 package filling daily; 8 hour; product vented transfer points of temp. substance/mixture into small containers Industrial - Clean down and CS39 Indoor, Daily; 1 - 4 Enclosed lines; retain PROC8a Nondedicated SU3/ SU10 Maintenance hours; product temp; wash down in sealed collection of line waste storage pending disposal discharging to/from in container or use as recycled vessels material for subsequent formulation. PPE. Industrial - Storage CS67 Daily; 8 hrs; product samples collected at PROC1/2 Closed SU3/ SU10 temp; dedicated sample point continuous process (sometimes with sampling) Uses in Coatings Industrial -SU3 General exposures CS15 ] Continuous; daily; 8hour Enclosed process; 1/2 -Use in closed, (closed systems) CS15 [CS56] closed/semi-closed continuous ] with sample collection sampling point process with occasional controlled [CS56]. exposure (e.g. sampling) Industrial - Bulk transfers CS14 Daily; 15 min - 1 hour; Enclosed transfers, PROC8b SU3/ SU10 product temp; collection vented transfer points; Dedicated of line waste in container clear lines prior to discharging to/from decoupling vessels Industrial -SU3 Film formation - force [CS 94] enclosed in situ in 2 -Use in closed, drying (50 - 100°C). workplace continuous Stoving (>100°C). process with occasional controlled UV/EB radiation curing. [CS 94] exposure (e.g. sampling) Industrial -SU3 Film formation - air [CS95] 4 - Use in batch drying. [CS95] and other process (synthesis) where opportunity for exposure arises Industrial -SU3 Preparation of material [CS 96] liquid/ powder products) - 5 - Mixing or for application. [CS 96] [CS30] batch, indoor/ outdoor. blending in batch Mixing operations (open processes for systems) [CS30] formulation of preparations and combine Industrial -SU3 Spraying [CS97] Daily; >4 hours, product Enclosed. Vented spray 7 -Industrial (automatic/robotic). temp (ambient) booth; specific workforce spraying [CS97] education, PPE Industrial -SU3 Spraying [CS97] Daily; >4 hours, product Enclosed. Vented spray 7 -Industrial (automatic/robotic). temp (ambient) booth; specific workforce spraying [CS97] vapours education, PPE combine Industrial -SU3 Manual spraying. [CS24] Open , Air supplied 7 -Industrial [CS24] masks, respirator. spraying Industrial -SU3 Manual spraying. [CS24] Open , Air supplied 7 -Industrial [CS24] vapours masks, respirator. spraying Industrial -SU3 Material transfers. CS3 Daily; 15 min - 1 hour; Enclosed transfers, 8b -Transfer of [CS3]. product temp (ambient); vented transfer points; chemicals from/to collection of line waste clear lines prior to vessels/ large in container. outdoor/ decoupling containers at indoor. dedicated facilities. Industrial -SU3 Roller, spreader, flow [CS69] Daily; >4 hours, product Local exhaust ventilation 10 - Roller application. [CS69] temp. (ambient); Range at rollers; remove spills application or from 2-3% upto 40-50% as they occur, PPE. brushing Large scale (open equipment) daily; ambient temp. daily; ambient temp. daily; ambient temp. daily; ambient temp. >4 hours, ambient temp. daily; ambient temp. >4 hours, ambient temp. daily; ambient temp. >4 hours, ambient temp. daily; ambient temp. daily; ambient temp. > 4 hours; daily; ambient temp. > 4 hours; daily; ambient temp. daily; ambient temp. > 4 hours; daily; ambient temp. No LEV 5 0 5 3.43 80 0.69 0.07 0.24 0.31 Provide extract ventilation to points where emissions occur E54 Wear suitable gloves tested to EN374 PPE15 No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Fill containers/cans at dedicated fill points supplied with local extract ventilation E51 Clear spills immediately C&H13 Wear suitable gloves tested to EN374 PPE15 Put lids on containers immediately after use E9 No LEV 10 80 2 LEV 13.71 90 1.371 0.03 0.47 0.50 Apply vessel entry procedures effectiveness including use of forced supplied air. assumed to AP15 Drain down system prior to equate to SOP equipment break-in or maintenance relating to E65 Transfer via enclosed lines E52 draining etc Wear suitable gloves tested to EN374 prior to PPE16 Wear suitable coveralls to maintence prevent exposure to the skin PPE27 Retain drain downs in sealed storage pending disposal or for subsequent recycle. ENVT4 outdoor activity 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Store substance within a closed system. E84 Transfer via enclosed lines. E52 Avoid dip sampling E42 No LEV 1 0 1.0 0.03 0 0.03 0.01 0.01 0.02 Handle substance within a closed system E47 Ensure material transfers are under containment or extract ventilation E66 Wear suitable gloves tested to EN374 PPE15 No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed system. E47 Operate activity from way from sources of substance emission or release E77 Ensure material transfers are under containment or extract ventilation. E56. Wear chemically resistant gloves (tested to EN374) PPE15 Avoid splashing C&H15 No LEV 10 30 7.0 1.37 0 1.37 Handle substance within a closed Good GV 0.10 0.47 0.57 system E47 Provide a good standard of general ventilation (3 to 5 air changes per hour) E11 Provide extract ventilation to point where emissions occur E54 Wear suitable gloves tested to EN374 PPE15 No LEV 5 0 5.0 6.86 80 1.37 0.07 0.47 0.55 Provide a good standard of general ventilation (3 to 5 air changes per hour) E11. Avoid manual contact with wet work pieces EI17. Wear suitable gloves tested to EN374 PPE15. No LEV 5 0 5.0 13.71 90 1.371 0.07 0.47 0.55 Provide extract ventilation to points where emissions occur E54. Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training PPE16 With LEV. 20 95 1.0 E60 = 95% 2.14 0 2.14 0.01 0.74 0.75 Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings E60 Wear suitable gloves tested to EN374 PPE15. Provide GV E11 With LEV. 100 95 5.0 E60 = 95% 2.14 80 0.43 0.71 0.15 0.86 Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings [E60]. {Wear suitable gloves tested to EN374 [PPE15]}. Provide GV E11 No LEV 20 90 2.0 RPE (APF=10)) 21.85 95 1.09 0.03 0.38 0.41 Provide enhanced GV E48 Wear a respirator conforming to EN140 with Type A filter or better. PPE22 Wear chemically resistant gloves (tested to type EN374) in combination with specific activity training PPE17 Ensure operatives are trained to minimise exposures EI19 Segregate the activity away from other operations E63 No LEV 100 90 4.2 RPE (APF=10)) 21.85 95 1.09 0.60 0.38 0.98 Provide good GV E11 Wear a operator training respirator conforming to EN140 with (reduces Type A filter or better. PPE22 Wear exposure by chemically resistant gloves (tested to 15%) : good GV type EN374) in combination with (0.7x) specific activity training PPE17 Ensure operatives are trained to minimise exposures EI19 Segregate the activity away from other operations E63 No LEV 5 0 5.0 6.86 80 1.37 0.07 0.47 0.55 Provide general ventilation E11 Wear suitable gloves tested to EN374 PPE15 Ensure material transfers are under containment or extract ventilation E66 Clear lines prior to decoupling E39 Use drum pumps or carefully pour from container E64 With LEV. 5 0 5.0 27.43 95 1.37 0.07 0.47 0.55 Wear chemically resistant gloves (tested to EN374) in combination with specific activity training. PPE17 Provide GV E11 Avoid splashing C&H15 Avoid manual contact with wet work pieces EI17.
Page 1 and 2:
EU-SICHERHEITSDATENBLATT gemäß Ve
Page 3 and 4:
Page 5 and 6:
Page 7 and 8:
Page 9 and 10:
Page 11 and 12:
Page 13 and 14:
Page 15 and 16:
Vacuum Gas Oils, Hydrocracked Gas O
Page 17 and 18:
Page 19 and 20:
Page 21 and 22:
Page 23 and 24:
Page 25 and 26:
Page 27 and 28:
Page 29 and 30:
Page 31 and 32:
Page 33 and 34:
Page 35 and 36:
Page 37 and 38:
Page 39 and 40:
Page 41 and 42:
Page 43 and 44:
Page 45 and 46:
Page 47 and 48:
Page 49 and 50:
Page 51 and 52:
Page 53 and 54:
Page 55 and 56:
Page 57 and 58:
Page 59 and 60:
Page 61 and 62:
Page 63 and 64:
Page 65 and 66:
Page 67 and 68:
Page 69 and 70:
Page 71 and 72:
Page 73 and 74:
Page 75 and 76:
Page 77 and 78:
Page 79 and 80:
Page 81 and 82:
Page 83 and 84:
Page 85 and 86:
Page 87 and 88:
Page 89 and 90:
Page 91 and 92:
Page 93 and 94:
Page 95 and 96: Vacuum Gas Oils, Hydrocracked Gas O
Page 123 and 124: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 125 and 126: Industrial - Tabletting, CS100 Indo
Page 127 and 128: Combined Professional - Manual spra
Page 129 and 130: Industrial - Bulk transfers CS14 Da
Page 131 and 132: Professional - Maintenance and CS77
Page 133 and 134: Note: differentiated Industrial -SU
Page 135 and 136: Professional - Treatment and dispos
Page 137 and 138: Industrial - operation of open CS16
Page 145: Gas Oils (Vacuum) 4 DNEL (inhalatio
Page 149 and 150: Combined Professional - Manual spra
Page 151 and 152: Industrial - Bulk transfers CS14 Da
Page 153 and 154: Professional - Maintenance and CS77
Page 155 and 156: Note: differentiated Industrial -SU
Page 157 and 158: Professional - Treatment and dispos
Page 159 and 160: Industrial - operation of open CS16
Page 165 and 166: This tool is provided for informati
Page 167 and 168: An Evaluation of the Persistence, B
Page 169 and 170: Table of Contents Executive Summary
Page 171 and 172: 2.0 Outline of PBT/vPvB Assessment
Page 173 and 174: 3.0 Persistence Assessment of Petro
Page 175 and 176: 100.0 Half-life predicted (days) 10
Page 177 and 178: 2,3-dimethylheptane 9 7.7 6.2 7.4 2
Page 179 and 180: ioHCwin half-life (days) 10000.0 10
Page 181 and 182: criterion. It can be concluded that
Page 185 and 186: Hydrocarbon C nr BioHCwin Predicted
Page 187 and 188: ioHCwin half-life (days) 1000000.0
Page 191 and 192: Hydrocarbon C nr BioHCwin Predicted
Page 193 and 194: enzo[a]pyrene 20 421.6 16.5 Table 1
Page 195 and 196: (see Appendix 2). Since BCF predict
Page 197 and 198:
10000 BCF (Arnot) 1000 100 10 1 n-P
Page 199 and 200:
exhibit BMFs near unity (Figure 28)
Page 201 and 202:
2,2,4,4,6,8,8- heptamethyl nonane 1
Page 203 and 204:
Hydrocarbon C BMF BCF (Arnot) Dieta
Page 205 and 206:
BCF (regression) 100000 10000 1000
Page 207 and 208:
4.5 Polynaphthenic hydrocarbons Reg
Page 209 and 210:
Experimental BMF 10 1 Polynaphth. D
Page 211 and 212:
enzene n-octylbenzene 14 0.034 403
Page 213 and 214:
10000 1000 BCF (Arnot) 100 10 1 NMA
Page 215 and 216:
and appears to be an outlier. This
Page 217 and 218:
4-ethylbiphenyl 14 863 1039 C Yakat
Page 219 and 220:
100000 BCF (regression) 10000 1000
Page 221 and 222:
10 Experimental BMF 1 0.1 NDiAr Die
Page 223 and 224:
Hydrocarbon C BMF Arnot BCF Dietary
Page 225 and 226:
Hydrocarbon C BMF Arnot BCF Dietary
Page 227 and 228:
Acenaphthene Acenaphthylene Benz(a)
Page 229 and 230:
5.0 Summary of Persistence and Bioa
Page 231 and 232:
lower water solubility, it is possi
Page 233 and 234:
properties of petroleum hydrocarbon
Page 235 and 236:
8.0 References Anonymous (2004). Fi
Page 237 and 238:
EMBSI (2007c). Fish, dietary bioacc
Page 239 and 240:
Prince RC, Walters CC. (2007). Biod
Page 241 and 242:
Appendix 1. Hydrocarbon structures
Page 243 and 244:
iP 14 2,4,10-Trimethylundecane CC(C
Page 245 and 246:
MN 7 1,2-Dimethylcyclopentane CC1C(
Page 247 and 248:
MN 14 n-Nonylcyclopentane CCCCCCCCC
Page 249 and 250:
MN 29 MN 29 MN 30 n-Tetracosylcyclo
Page 251 and 252:
hexahydroindane DN 20 2,4-dimethylo
Page 253 and 254:
PN 27 Phenanthrene 2,6-dimethylhept
Page 255 and 256:
MAr 13 1-Methyl-3-hexylbenzene Cc1c
Page 257 and 258:
NMAr 12 n-Propylindan c1ccc2CC(CCC)
Page 259 and 260:
NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
Page 261 and 262:
NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
Page 263 and 264:
DAr 16 2-Hexylnaphthalene CCCCCCc1c
Page 265 and 266:
NDAr 16 n-Butylacenaphthene c12cccc
Page 267 and 268:
NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
Page 269 and 270:
PAr 19 Ethylbenzo(a)fluorene C3c1cc
Page 271 and 272:
PAr 22 n-Pentylbenzo(a)fluorene C3c
Page 273 and 274:
PAr 28 Isohexyl-octadecahydro-picen
Page 275 and 276:
Appendix 3. CONCAWE Position Paper
Page 277 and 278:
probabilities are adjusted to best
Page 279 and 280:
1.2.2 OASIS LMC Models: Toxicologic
Page 281 and 282:
environmental chemicals (database o
Page 283 and 284:
dihydrodiol. These dihydroxylated i
Page 285 and 286:
Table 1 : PBT assessment of C15 str
Page 287 and 288:
1: The following structures were pr
Page 289 and 290:
Dimitrov SD, Dimitrova N, Mekenyan
Page 291 and 292:
hydrocarbons and azaarenes original
Page 293 and 294:
Verhaar HJM, van Leeuwen CJ, Hermen
Page 295 and 296:
CONCAWE AQUATIC TOXICITY PREDICTION
Page 297 and 298:
CONTENTS (Continued) Section Page 1
Page 299 and 300:
1-2 The model predictions include m
Page 301 and 302:
2-1 SECTION 2 2 SUMMARY OF COMPOSIT
Page 303 and 304:
Page 305 and 306:
Page 307 and 308:
Page 309 and 310:
10-1 SECTION 10 10 SUMMARY OF COMPO
Page 311 and 312:
Page 313 and 314:
Page 315 and 316:
Page 317 and 318:
Page 319:
show all

EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?