EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
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Gas Oils (Vacuum)<br />
4 DNEL (inhalation,<br />
aerosol, mg/m3) =<br />
68.3 DNELs (dermal)<br />
= mg/kg/d<br />
Table 1: Mapping Uses in the Supply Chain 7<br />
2.9 Reference<br />
Value<br />
(vapour<br />
phase<br />
portion of<br />
mixed<br />
aerosol<br />
7 Basis for ES<br />
User Group Contributing Scenarios<br />
CS Ref<br />
Use Descriptor<br />
Typical Mapped Typical Mapped RMMs Process<br />
Operating Conditions<br />
Categoryequivalen<br />
Tier 1 assumptions and adjustments<br />
Predicted Exposure - ECETOC TRA estimate<br />
RMMs for communication -<br />
where required<br />
Consolidate into GES or e-SDS (Black<br />
OCs (red text Tier RMMs (red text Moderate LEV Predicted Relvant Predicted Dermal Dermal Protection Predicted Actual<br />
text REACH advised; Blue text<br />
1 adjustments) additional Tier 1 dustiness Efficiency % Exposure Exposure (mg/kg/d) Reduction Efficiency Dermal Exposure<br />
recommended)<br />
adjustments) (mg/3) no (XX if not (mg/m3) modifiers<br />
(mg/kg/d) Substance Specific Substance Specific Substance Specific<br />
LEV TRA)<br />
RCR (inhalation) RCR (dermal) RCR (all routes)<br />
Manufacture of Industrial - General process CS15 Continuous; daily; 15 - 1 Closed processes PROC1 Closed >4 hours, ambient Closed process. 0.01 0 0.01 0.34 10 0.306 0.00 0.11 0.11 No special precautions identified' EI18<br />
substance SU8/9/3 exposures (no<br />
hour; product temp.<br />
process (no temp.<br />
No exposure.<br />
Wear gloves PPE15<br />
sampling)<br />
Outdoor<br />
sampling)<br />
Combine in narrative Industrial - General process CS15 Continuous; daily; 15 Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Handle substance within a closed<br />
with row above SU8/9/3 exposures and sample<br />
mins - 1 hour; product Outdoor location; continuous process temp.<br />
system E49 Ensure samples are<br />
collection<br />
temp. Outdoor closed/semi-closed (with sampling)<br />
collected under containment or extract<br />
sampling point<br />
ventilation. E76 Wear gloves PPE15<br />
Industrial - General process CS15 Batch process; daily; 15 - Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 Handle substance within a closed<br />
SU8/9/3 exposures<br />
1 hour; product temp.; enclosed or vented batch process (with temp.<br />
system E47 Ensure samples are<br />
Indoor/Outdoor sampling points sampling)<br />
collected under containment or extract<br />
ventilation.E76<br />
Industrial - General exposures CS16 Daily; 15 - 1 hour; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Wear gloves PPE15 Provide extract<br />
SU8/9/3 open batch process<br />
product temp.; lines prior to decoupling process with temp.<br />
ventn to transfer points E54. Clear<br />
Indoor/Outdoor<br />
exposure<br />
lines prior to decoupling. E39 Provide<br />
good GV E40<br />
Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0 2.1 0.34 0 0.34 0.03 0.12 0.15 Ensure samples are collected under<br />
SU8/9/3<br />
temp.; Indoor/Outdoor sampling points batch process (with temp.<br />
containment or extract ventilation.E76<br />
sampling)<br />
Wear gloves PPE16 Avoid splashing<br />
C&H15 Undertake outdoors E69<br />
Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0 5 0.34 0 0.34 0.07 0.12 0.19 Use in fume cupboard E83 Wear<br />
SU8/9/3<br />
product temp.; Indoor<br />
laboratory temp.<br />
suitable gloves tested to EN374<br />
PPE15<br />
Industrial - Bulk transfers (closed CS501 Daily; 15 - 1 hour; Enclosed transfers, clear PROC8b >4 hours, ambient No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed<br />
SU8/9/3 systems) e.g bottom<br />
product temp.; lines prior to decoupling Dedicated temp.<br />
system E47 Wear chemically resistant<br />
loading<br />
Indoor/Outdoor<br />
discharging to/from<br />
gloves (tested to EN374) PPE15<br />
vessels<br />
Ensure material transfers are under<br />
containment or extract ventilation. E56<br />
Avoid splashing C&H15 Operate<br />
activity from way from sources of<br />
substance emission or release E77<br />
Industrial - Bulk transfers (open CS503 Daily; 1-4 hrs hour; Enclosed transfers, PROC8b<br />
daily; ambient No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Wear gloves PPE15 Provide extract<br />
SU8/9/3 systems)<br />
product temp.; vented transfer points; Dedicated temp.<br />
ventn to transfer points E66. Clear<br />
Indoor/Outdoor clear lines prior to discharging to/from<br />
lines prior to decoupling. E39 Operate<br />
decoupling<br />
vessels<br />
activity from way from sources of<br />
substance emission or release E77<br />
Industrial - Clean down and CS39 Daily; 15 mins -1 hour; Enclosed lines; retain PROC8a Nondedicated<br />
temp.<br />
effectiveness<br />
break-in or maintenance. E65. Retain<br />
>4 hours; ambient No LEV 10 80 2 LEV<br />
13.71 90 1.371 0.03 0.47 0.50 Drain down system prior to equipment<br />
SU8/9/3 Maintenance<br />
product temp; collection wash down in sealed<br />
of line waste in storage pending disposal discharging to/from<br />
assumed to<br />
drain down in sealed storage pending<br />
container;<br />
or use as recycled vessels<br />
equate to SOP<br />
disposal or for subsequent recycle<br />
Indoor/Outdoor material for subsequent<br />
relating to<br />
ENVT4. Deal with spills immediately.<br />
formulation. PPE.<br />
draining etc<br />
C&H13. Wear chemically resistant<br />
prior to<br />
gloves (tested to EN374) . PPE16<br />
maintence<br />
Wear suitable coveralls to prevent<br />
exposure to the skin PPE27<br />
Industrial - Bulk Storage CS85 Daily; 8 hrs; product samples collected at PROC1/2 Closed daily; ambient outdoor activity 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Store substance within a closed<br />
SU3/ SU10<br />
temp;<br />
dedicated sample point continuous process temp.<br />
system. E84 Avoid dip samples E42<br />
(sometimes with<br />
sampling)<br />
Distribution of Industrial - General process CS15 Continuous; Outdoor; Closed process. No PROC1 Closed >4 hours, ambient Closed product. 0.01 0 0.01 0.34 0 0.34 0.00 0.12 0.12 No special measures EI18 Handle<br />
substance SU3<br />
exposures - closed<br />
daily; 15 - 1 hour; exposure.<br />
process (no temp.<br />
No exposure.<br />
substance within a closed system. E47<br />
process (e.g. In-line<br />
product temp.<br />
sampling)<br />
additive dosing<br />
equipment, in-line filter<br />
cleaning)<br />
Combine in narrative Industrial - General process CS15 Continuous; Outdoor; Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Handle substance within a closed<br />
SU3<br />
exposures (occasional<br />
daily; 15 mins - 1 hour; closed/semi-closed continuous process temp.<br />
system. E47 Ensure material transfers<br />
controlled exposure)<br />
product temp.<br />
sampling point<br />
(with sampling)<br />
are under containment or extract<br />
ventilation E66<br />
Industrial - General process CS15 Batch process; Outdoor; Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 Handle substance within a closed<br />
SU3<br />
exposures - closed<br />
daily; 15 - 1 hour; enclosed or vented batch process (with temp.<br />
system. E47 Ensure material transfers<br />
batch process<br />
product temp.<br />
sampling points sampling)<br />
are under containment or extract<br />
ventilation E66<br />
Industrial -SU3 General exposures CS16 Daily; Indoor/Outdoor; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Ensure material transfers are under<br />
open batch process<br />
15 - 1 hour; product lines prior to decoupling process with temp.<br />
containment or extract ventilation<br />
temp.<br />
exposure<br />
[E66] Clear transfer lines prior to decoupling<br />
E39 Wear gloves tested to<br />
EN374 PPE15<br />
Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 No special precuations EI18 Ensure<br />
SU3<br />
temp.; Outdoor; sampling points batch process (with temp.<br />
samples are obtained under<br />
sampling)<br />
containment or extract ventilation E76<br />
Wear suitable gloves tested to EN374<br />
PPE15 Avoid dip sampling E42<br />
Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0 5 0.34 0 0.34 0.07 0.12 0.19 No special precuations EI18 Handle in<br />
SU3<br />
product temp.; Indoor<br />
laboratory temp.<br />
a fume cupboard or under extract<br />
ventilation E83 Wear suitable gloves<br />
tested to EN374. PPE15.<br />
t