EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

Gas Oils (Vacuum)
4 DNEL (inhalation,
aerosol, mg/m3) =
68.3 DNELs (dermal)
= mg/kg/d
Table 1: Mapping Uses in the Supply Chain 7
2.9 Reference
Value
(vapour
phase
portion of
mixed
aerosol
7 Basis for ES
User Group Contributing Scenarios
CS Ref
Use Descriptor
Typical Mapped Typical Mapped RMMs Process
Operating Conditions
Categoryequivalen
Tier 1 assumptions and adjustments
Predicted Exposure - ECETOC TRA estimate
RMMs for communication -
where required
Consolidate into GES or e-SDS (Black
OCs (red text Tier RMMs (red text Moderate LEV Predicted Relvant Predicted Dermal Dermal Protection Predicted Actual
text REACH advised; Blue text
1 adjustments) additional Tier 1 dustiness Efficiency % Exposure Exposure (mg/kg/d) Reduction Efficiency Dermal Exposure
recommended)
adjustments) (mg/3) no (XX if not (mg/m3) modifiers
(mg/kg/d) Substance Specific Substance Specific Substance Specific
LEV TRA)
RCR (inhalation) RCR (dermal) RCR (all routes)
Manufacture of Industrial - General process CS15 Continuous; daily; 15 - 1 Closed processes PROC1 Closed >4 hours, ambient Closed process. 0.01 0 0.01 0.34 10 0.306 0.00 0.11 0.11 No special precautions identified' EI18
substance SU8/9/3 exposures (no
hour; product temp.
process (no temp.
No exposure.
Wear gloves PPE15
sampling)
Outdoor
sampling)
Combine in narrative Industrial - General process CS15 Continuous; daily; 15 Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Handle substance within a closed
with row above SU8/9/3 exposures and sample
mins - 1 hour; product Outdoor location; continuous process temp.
system E49 Ensure samples are
collection
temp. Outdoor closed/semi-closed (with sampling)
collected under containment or extract
sampling point
ventilation. E76 Wear gloves PPE15
Industrial - General process CS15 Batch process; daily; 15 - Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 Handle substance within a closed
SU8/9/3 exposures
1 hour; product temp.; enclosed or vented batch process (with temp.
system E47 Ensure samples are
Indoor/Outdoor sampling points sampling)
collected under containment or extract
ventilation.E76
Industrial - General exposures CS16 Daily; 15 - 1 hour; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Wear gloves PPE15 Provide extract
SU8/9/3 open batch process
product temp.; lines prior to decoupling process with temp.
ventn to transfer points E54. Clear
Indoor/Outdoor
exposure
lines prior to decoupling. E39 Provide
good GV E40
Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0 2.1 0.34 0 0.34 0.03 0.12 0.15 Ensure samples are collected under
SU8/9/3
temp.; Indoor/Outdoor sampling points batch process (with temp.
containment or extract ventilation.E76
sampling)
Wear gloves PPE16 Avoid splashing
C&H15 Undertake outdoors E69
Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0 5 0.34 0 0.34 0.07 0.12 0.19 Use in fume cupboard E83 Wear
SU8/9/3
product temp.; Indoor
laboratory temp.
suitable gloves tested to EN374
PPE15
Industrial - Bulk transfers (closed CS501 Daily; 15 - 1 hour; Enclosed transfers, clear PROC8b >4 hours, ambient No LEV 5 0 5 6.86 80 1.37 0.07 0.47 0.55 Handle substance within a closed
SU8/9/3 systems) e.g bottom
product temp.; lines prior to decoupling Dedicated temp.
system E47 Wear chemically resistant
loading
Indoor/Outdoor
discharging to/from
gloves (tested to EN374) PPE15
vessels
Ensure material transfers are under
containment or extract ventilation. E56
Avoid splashing C&H15 Operate
activity from way from sources of
substance emission or release E77
Industrial - Bulk transfers (open CS503 Daily; 1-4 hrs hour; Enclosed transfers, PROC8b
daily; ambient No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Wear gloves PPE15 Provide extract
SU8/9/3 systems)
product temp.; vented transfer points; Dedicated temp.
ventn to transfer points E66. Clear
Indoor/Outdoor clear lines prior to discharging to/from
lines prior to decoupling. E39 Operate
decoupling
vessels
activity from way from sources of
substance emission or release E77
Industrial - Clean down and CS39 Daily; 15 mins -1 hour; Enclosed lines; retain PROC8a Nondedicated
temp.
effectiveness
break-in or maintenance. E65. Retain
>4 hours; ambient No LEV 10 80 2 LEV
13.71 90 1.371 0.03 0.47 0.50 Drain down system prior to equipment
SU8/9/3 Maintenance
product temp; collection wash down in sealed
of line waste in storage pending disposal discharging to/from
assumed to
drain down in sealed storage pending
container;
or use as recycled vessels
equate to SOP
disposal or for subsequent recycle
Indoor/Outdoor material for subsequent
relating to
ENVT4. Deal with spills immediately.
formulation. PPE.
draining etc
C&H13. Wear chemically resistant
prior to
gloves (tested to EN374) . PPE16
maintence
Wear suitable coveralls to prevent
exposure to the skin PPE27
Industrial - Bulk Storage CS85 Daily; 8 hrs; product samples collected at PROC1/2 Closed daily; ambient outdoor activity 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Store substance within a closed
SU3/ SU10
temp;
dedicated sample point continuous process temp.
system. E84 Avoid dip samples E42
(sometimes with
sampling)
Distribution of Industrial - General process CS15 Continuous; Outdoor; Closed process. No PROC1 Closed >4 hours, ambient Closed product. 0.01 0 0.01 0.34 0 0.34 0.00 0.12 0.12 No special measures EI18 Handle
substance SU3
exposures - closed
daily; 15 - 1 hour; exposure.
process (no temp.
No exposure.
substance within a closed system. E47
process (e.g. In-line
product temp.
sampling)
additive dosing
equipment, in-line filter
cleaning)
Combine in narrative Industrial - General process CS15 Continuous; Outdoor; Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 0 1 1.37 0 1.37 0.01 0.47 0.49 Handle substance within a closed
SU3
exposures (occasional
daily; 15 mins - 1 hour; closed/semi-closed continuous process temp.
system. E47 Ensure material transfers
controlled exposure)
product temp.
sampling point
(with sampling)
are under containment or extract
ventilation E66
Industrial - General process CS15 Batch process; Outdoor; Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 Handle substance within a closed
SU3
exposures - closed
daily; 15 - 1 hour; enclosed or vented batch process (with temp.
system. E47 Ensure material transfers
batch process
product temp.
sampling points sampling)
are under containment or extract
ventilation E66
Industrial -SU3 General exposures CS16 Daily; Indoor/Outdoor; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 0 5 6.86 80 1.372 0.07 0.47 0.55 Ensure material transfers are under
open batch process
15 - 1 hour; product lines prior to decoupling process with temp.
containment or extract ventilation
temp.
exposure
[E66] Clear transfer lines prior to decoupling
E39 Wear gloves tested to
EN374 PPE15
Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0 3 0.34 0 0.34 0.04 0.12 0.16 No special precuations EI18 Ensure
SU3
temp.; Outdoor; sampling points batch process (with temp.
samples are obtained under
sampling)
containment or extract ventilation E76
Wear suitable gloves tested to EN374
PPE15 Avoid dip sampling E42
Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0 5 0.34 0 0.34 0.07 0.12 0.19 No special precuations EI18 Handle in
SU3
product temp.; Indoor
laboratory temp.
a fume cupboard or under extract
ventilation E83 Wear suitable gloves
tested to EN374. PPE15.
t