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EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Gas Oils (Vacuum)<br />

4 DNEL (inhalation,<br />

aerosol, mg/m3) =<br />

68.3 DNELs (dermal)<br />

= mg/kg/d<br />

2.9<br />

Table 1: Mapping Uses in the Supply Chain 7<br />

Use Descriptor Tier 1 assumptions and adjustments Predicted Exposure - ECETOC<br />

where required<br />

TRA estimate<br />

User Group Contributing Scenarios<br />

Typical Mapped<br />

Operating Conditions<br />

CS Ref<br />

Typical Mapped RMMs Process OCs (red text Tier RMMs (red text<br />

Categoryequivalen 1 adjustments) additional Tier 1<br />

adjustments)<br />

Moderate Predicted Dermal<br />

dustiness (mg/kg/d)<br />

(mg/3) no<br />

LEV<br />

Manufacture of Industrial - General process CS15 Continuous; daily; 15 - 1 Closed processes PROC1 Closed >4 hours, ambient Closed process. 0.01 0.34<br />

substance SU8/9/3 exposures (no<br />

hour; product temp.<br />

process (no temp.<br />

No exposure.<br />

sampling)<br />

Outdoor<br />

sampling)<br />

Combine in narrative Industrial - General process CS15 Continuous; daily; 15 Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 1.37<br />

with row above SU8/9/3 exposures and sample<br />

mins - 1 hour; product Outdoor location; continuous process temp.<br />

collection<br />

temp. Outdoor closed/semi-closed (with sampling)<br />

sampling point<br />

Industrial - General process CS15 Batch process; daily; 15 - Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0.34<br />

SU8/9/3 exposures<br />

1 hour; product temp.; enclosed or vented batch process (with temp.<br />

Indoor/Outdoor sampling points sampling)<br />

Industrial - General exposures CS16 Daily; 15 - 1 hour; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 6.86<br />

SU8/9/3 open batch process<br />

product temp.; lines prior to decoupling process with temp.<br />

Indoor/Outdoor<br />

exposure<br />

Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0.34<br />

SU8/9/3<br />

temp.; Indoor/Outdoor sampling points batch process (with temp.<br />

sampling)<br />

Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0.34<br />

SU8/9/3<br />

product temp.; Indoor<br />

laboratory temp.<br />

Industrial - Bulk transfers (closed CS501 Daily; 15 - 1 hour; Enclosed transfers, clear PROC8b >4 hours, ambient No LEV 5 6.86<br />

SU8/9/3 systems) e.g bottom<br />

product temp.; lines prior to decoupling Dedicated temp.<br />

loading<br />

Indoor/Outdoor<br />

discharging to/from<br />

vessels<br />

Industrial - Bulk transfers (open CS503 Daily; 1-4 hrs hour; Enclosed transfers, PROC8b<br />

daily; ambient No LEV 5 6.86<br />

SU8/9/3 systems)<br />

product temp.; vented transfer points; Dedicated temp.<br />

Indoor/Outdoor clear lines prior to discharging to/from<br />

decoupling<br />

vessels<br />

Industrial - Clean down and CS39 Daily; 15 mins -1 hour; Enclosed lines; retain PROC8a Nondedicated<br />

temp.<br />

>4 hours; ambient No LEV 10 13.71<br />

SU8/9/3 Maintenance<br />

product temp; collection wash down in sealed<br />

of line waste in storage pending disposal discharging to/from<br />

container;<br />

or use as recycled vessels<br />

Indoor/Outdoor material for subsequent<br />

formulation. PPE.<br />

Industrial - Bulk Storage CS85 Daily; 8 hrs; product samples collected at PROC1/2 Closed daily; ambient outdoor activity 1 1.37<br />

SU3/ SU10<br />

temp;<br />

dedicated sample point continuous process temp.<br />

(sometimes with<br />

sampling)<br />

Distribution of Industrial - General process CS15 Continuous; Outdoor; Closed process. No PROC1 Closed >4 hours, ambient Closed product. 0.01 0.34<br />

substance SU3<br />

exposures - closed<br />

daily; 15 - 1 hour; exposure.<br />

process (no temp.<br />

No exposure.<br />

process (e.g. In-line<br />

product temp.<br />

sampling)<br />

additive dosing<br />

equipment, in-line filter<br />

cleaning)<br />

Combine in narrative Industrial - General process CS15 Continuous; Outdoor; Enclosed process; PROC2 Closed >4 hours, ambient No LEV 1 1.37<br />

SU3<br />

exposures (occasional<br />

daily; 15 mins - 1 hour; closed/semi-closed continuous process temp.<br />

controlled exposure)<br />

product temp.<br />

sampling point<br />

(with sampling)<br />

Industrial - General process CS15 Batch process; Outdoor; Closed equipment, PROC3 Closed >4 hours, ambient No LEV 3 0.34<br />

SU3<br />

exposures - closed<br />

daily; 15 - 1 hour; enclosed or vented batch process (with temp.<br />

batch process<br />

product temp.<br />

sampling points sampling)<br />

Industrial -SU3 General exposures CS16 Daily; Indoor/Outdoor; Enclosed transfers, clear PROC4 batch >4 hours, ambient No LEV 5 6.86<br />

open batch process<br />

15 - 1 hour; product lines prior to decoupling process with temp.<br />

temp.<br />

exposure<br />

Industrial - Sample collection CS2 Daily; 4 hours, ambient No LEV 3 0.34<br />

SU3<br />

temp.; Outdoor; sampling points batch process (with temp.<br />

sampling)<br />

Industrial - Laboratory activities CS36 Daily; 15 mins - 1 hour; Fume cupboard. PPE. PROC15 Use in >4 hours, ambient No LEV 5 0.34<br />

SU3<br />

product temp.; Indoor<br />

laboratory temp.<br />

t

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