EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels Endpoint 9.4.3 Short-term toxicity to Plants 9.4.4 Long-term toxicity testing on invertebrates 9.4.6 (should be 9.4.5) Long-term toxicity testing on plants 9.5.1 Long-term toxicity to Sediment organisms 9.6.1 Long-term or reproductive toxicity to birds Relevance to Category Derived Category Value No Not applicable – see comments No Not applicable – see comments No Not applicable – see comments No Not applicable – see comments No Not applicable – see comments Comment complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. 4. Conclusions per end point for C&L, PBT/vPvB and dose descriptor Physicochemical Properties (Section 7 of REACH Annexes VII-X) The hazard classification of category members with respect to physical-chemical properties is as follows: o ‘Harmful’ if: may cause lung damage if swallowed’ (R65) Toxicological Information (Section 8 of REACH Annexes VII-X) The hazard classification of category members with respect to toxicological properties is as follows: ‘Harmful by inhalation’ (R20) ‘Irritating to skin’ (R38) ‘Limited evidence of a carcinogenic effect’ – Category 3 (R40) Eco-toxicological Information (Section 9 of REACH Annexes VII-X) The hazard classification of category members with respect to ecotoxicological properties is as follows: 2010-07-30 CSR Appendix 1
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels ‘Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment’ (R51/53) PBT/vPvB Assessment (Note: numbered in accordance with relevant CSR section) 8.1. Assessment of PBT/vPvB Properties - Comparison with the Criteria of Annex XIII 8.1.1. Persistence Assessment An evaluation of representative hydrocarbon structures indicate some structures meet the Persistent (P) or very Persistent (vP) criteria (see CONCAWE, 2010b). 8.1.2. Bioaccumulation Assessment An evaluation of representative hydrocarbon structures indicates no structures meet the very Bioaccumulative (vB) criterion but some structures meet the Bioaccumulative (B) criterion (see CONCAWE, 2010b). 8.1.3. Toxicity Assessment For representative hydrocarbons structures that were found to meet the P and B criteria, a toxicity evaluation was performed (see CONCAWE, 2010b). No structures relevant to petroleum substances were found to meet the toxicity criterion except anthracene which has been confirmed as a PBT substance. 8.1.4. Summary and overall Conclusions on PBT or vPvB Properties Anthracene is not present in this substance at greater than 0.1% (CONCAWE, 2010b). No other representative hydrocarbon structures were found to meet the PBT / vPvB criteria. 8.2. Emission Characterisation Emission Characterisation is not required because the substance does not fulfil the PBT / vPvB criteria (see CONCAWE, 2010b). Dose Desriptors (Health and Environment) Toxicity o Acute oral LD 50 > 7600 mg/kg o Acute Inhalation LC 50 > 4.1 mg/l o Acute dermal LD 50 > 4300 mg/kg o Short-term repeat dose dermal NOAEL 0.5 ml/kg o Sub-chronic repeat dose inhalation NOAEC >1710 mg/m 3 o Sub-chronic repeat dose dermal NOAEL 30 mg/kg o Reproductive toxicity dermal NOAEL 125 mg/kg o Reproductive toxicity inhalation NOAEC > 401 ppm Ecotoxicity o Acute aquatic invertebrate EL 50 68 mg/l o Acute aquatic algae IL 50 22 mg/l o Acute aquatic fish LL 50 21 mg/l o Long-term invertebrate NOEL 0.21 mg/l o Long-term fish NOEL 0.083 mg/l 2010-07-30 CSR Appendix 1
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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels<br />
Endpoint<br />
9.4.3 Short-term toxicity to<br />
Plants<br />
9.4.4 Long-term toxicity<br />
testing on invertebrates<br />
9.4.6 (should be 9.4.5)<br />
Long-term toxicity testing on<br />
plants<br />
9.5.1 Long-term toxicity to<br />
Sediment organisms<br />
9.6.1 Long-term or<br />
reproductive toxicity to birds<br />
Relevance to<br />
Category<br />
Derived Category<br />
Value<br />
No Not applicable –<br />
see comments<br />
No Not applicable –<br />
see comments<br />
No Not applicable –<br />
see comments<br />
No Not applicable –<br />
see comments<br />
No Not applicable –<br />
see comments<br />
Comment<br />
complex substance.<br />
Substance is a<br />
hydrocarbon UVCB.<br />
Standard tests for this<br />
endpoint are intended for<br />
single substances and are<br />
not appropriate for this<br />
complex substance.<br />
Substance is a<br />
hydrocarbon UVCB.<br />
Standard tests for this<br />
endpoint are intended for<br />
single substances and are<br />
not appropriate for this<br />
complex substance.<br />
Substance is a<br />
hydrocarbon UVCB.<br />
Standard tests for this<br />
endpoint are intended for<br />
single substances and are<br />
not appropriate for this<br />
complex substance.<br />
Substance is a<br />
hydrocarbon UVCB.<br />
Standard tests for this<br />
endpoint are intended for<br />
single substances and are<br />
not appropriate for this<br />
complex substance.<br />
Substance is a<br />
hydrocarbon UVCB.<br />
Standard tests for this<br />
endpoint are intended for<br />
single substances and are<br />
not appropriate for this<br />
complex substance.<br />
4. Conclusions per end point for C&L, PBT/vPvB and<br />
dose descriptor<br />
Physicochemical Properties (Section 7 of REACH Annexes VII-X)<br />
The hazard classification of category members with respect to physical-chemical properties is as<br />
follows:<br />
o ‘Harmful’ if: may cause lung damage if swallowed’ (R65)<br />
Toxicological Information (Section 8 of REACH Annexes VII-X)<br />
The hazard classification of category members with respect to toxicological properties is as follows:<br />
‘Harmful by inhalation’ (R20)<br />
<br />
<br />
‘Irritating to skin’ (R38)<br />
‘Limited evidence of a carcinogenic effect’ – Category 3 (R40)<br />
Eco-toxicological Information (Section 9 of REACH Annexes VII-X)<br />
The hazard classification of category members with respect to ecotoxicological properties is as<br />
follows:<br />
2010-07-30 CSR Appendix 1