EU-SICHERHEITSDATENBLATT Dieselkraftstoff ... - Schmierstoffe

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Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels testing on fish Endpoint Relevance to Category Derived Category Value 21 mg/l (96 h) (Oncorhynchus mykiss) Comment 9.1.4 Activated sludge respiration inhibition testing 9.1.5 Long-term toxicity testing on invertebrates (preferred species Daphnia) 9.1.6 Long-term toxicity testing on fish 9.1.6.1 Fish early-life stage (FELS) toxicity test 9.1.6.2 Fish short-term toxicity test on embryo and sac-fry stages No Not applicable – see comments Yes Yes NOEL 0.21 mg/l (21 d) (Daphnia magna) NOEL 0.083 mg/l (14 d) (o. mykiss) Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Based on key study. Based on QSAR (PETROTOX) prediction 9.1.6.3 Fish, juvenile growth test 9.2 Degradation 9.2.1 Biotic 9.2.1.1 Ready biodegradability Yes Readily biodegradable Based on key study. 9.2.1.2 Simulation testing on ultimate degradation in surface water 9.2.1.3 Soil simulation testing (for substances with a high potential for adsorption to soil) 9.2.1.4 Sediment simulation testing (for substances with a high potential for adsorption to sediment) 9.2.2 Abiotic 9.2.2.1 Abiotic Hydrolysis as a function of pH 9.2.2.2 Identification of degradation products 60 % in a 28 day test Yes Not applicable – see comments No Not applicable – see comments No Not applicable – see comments No Not applicable – see comments No Not applicable – see comments Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Hydrocarbons are not susceptible to abiotic hydrolysis. For all the major classes of hydrocarbons, the major metabolites are in most cases less toxic, and 2010-07-30 CSR Appendix 1
Vacuum Gas Oils, Hydrocracked Gas Oils, and Distillate Fuels Endpoint 9.3 Fate and behaviour in the environment 9.3.1 Adsorption/desorption Screening 9.3.2 Bioaccumulation in aquatic species, preferably fish 9.3.3 Further information on adsorption/desorption 9.3.4 Further information on the environmental fate and behaviour of the substance and/or degradation products 9.4 Effects on terrestrial Organisms Relevance to Category Derived Category Value No Not applicable – see comments Yes Not applicable – see comments No Not applicable – see comments No Not applicable – see comments Comment always less bioaccumulative than the parent molecule. Consequently, it is concluded that for PBT and risk assessment purposes, the metabolites of hydrocarbons do not require any further assessment. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. For all the major classes of hydrocarbons, the major metabolites are in most cases less toxic, and always less bioaccumulative than the parent molecule. Consequently, it is concluded that for PBT and risk assessment purposes, the metabolites of hydrocarbons do not require any further assessment. 9.4.1 Short-term toxicity to invertebrates 9.4.2 Effects on soil micro- Organisms No Not applicable – see comments No Not applicable – see comments Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this complex substance. Substance is a hydrocarbon UVCB. Standard tests for this endpoint are intended for single substances and are not appropriate for this 2010-07-30 CSR Appendix 1
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EU-SICHERHEITSDATENBLATT gemäß Ve
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Vacuum Gas Oils, Hydrocracked Gas O
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Page 61 and 62: Vacuum Gas Oils, Hydrocracked Gas O
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Page 137 and 138: Industrial - operation of open CS16
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This tool is provided for informati
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An Evaluation of the Persistence, B
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Table of Contents Executive Summary
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2.0 Outline of PBT/vPvB Assessment
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3.0 Persistence Assessment of Petro
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100.0 Half-life predicted (days) 10
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2,3-dimethylheptane 9 7.7 6.2 7.4 2
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ioHCwin half-life (days) 10000.0 10
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criterion. It can be concluded that
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Hydrocarbon C nr BioHCwin Predicted
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ioHCwin half-life (days) 1000000.0
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Hydrocarbon C nr BioHCwin Predicted
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enzo[a]pyrene 20 421.6 16.5 Table 1
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(see Appendix 2). Since BCF predict
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10000 BCF (Arnot) 1000 100 10 1 n-P
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exhibit BMFs near unity (Figure 28)
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2,2,4,4,6,8,8- heptamethyl nonane 1
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Hydrocarbon C BMF BCF (Arnot) Dieta
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BCF (regression) 100000 10000 1000
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4.5 Polynaphthenic hydrocarbons Reg
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Experimental BMF 10 1 Polynaphth. D
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enzene n-octylbenzene 14 0.034 403
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10000 1000 BCF (Arnot) 100 10 1 NMA
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and appears to be an outlier. This
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4-ethylbiphenyl 14 863 1039 C Yakat
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100000 BCF (regression) 10000 1000
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10 Experimental BMF 1 0.1 NDiAr Die
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Hydrocarbon C BMF Arnot BCF Dietary
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Hydrocarbon C BMF Arnot BCF Dietary
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Acenaphthene Acenaphthylene Benz(a)
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5.0 Summary of Persistence and Bioa
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lower water solubility, it is possi
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properties of petroleum hydrocarbon
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8.0 References Anonymous (2004). Fi
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EMBSI (2007c). Fish, dietary bioacc
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Prince RC, Walters CC. (2007). Biod
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Appendix 1. Hydrocarbon structures
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iP 14 2,4,10-Trimethylundecane CC(C
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MN 7 1,2-Dimethylcyclopentane CC1C(
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MN 14 n-Nonylcyclopentane CCCCCCCCC
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MN 29 MN 29 MN 30 n-Tetracosylcyclo
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hexahydroindane DN 20 2,4-dimethylo
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PN 27 Phenanthrene 2,6-dimethylhept
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MAr 13 1-Methyl-3-hexylbenzene Cc1c
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NMAr 12 n-Propylindan c1ccc2CC(CCC)
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NMAr 24 c1cc(CC(C)CCCC(C)CCCCC)c2CC
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NMAr 29 NMAr 29 NMAr 29 NMAr 29 NMA
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DAr 16 2-Hexylnaphthalene CCCCCCc1c
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NDAr 16 n-Butylacenaphthene c12cccc
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NDAr 26 Dimethyloctyl-1,2,3,6,7,8-
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PAr 19 Ethylbenzo(a)fluorene C3c1cc
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PAr 22 n-Pentylbenzo(a)fluorene C3c
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PAr 28 Isohexyl-octadecahydro-picen
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Appendix 3. CONCAWE Position Paper
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probabilities are adjusted to best
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1.2.2 OASIS LMC Models: Toxicologic
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environmental chemicals (database o
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dihydrodiol. These dihydroxylated i
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Table 1 : PBT assessment of C15 str
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1: The following structures were pr
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Dimitrov SD, Dimitrova N, Mekenyan
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hydrocarbons and azaarenes original
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Verhaar HJM, van Leeuwen CJ, Hermen
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CONCAWE AQUATIC TOXICITY PREDICTION
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CONTENTS (Continued) Section Page 1
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1-2 The model predictions include m
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2-1 SECTION 2 2 SUMMARY OF COMPOSIT
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10-1 SECTION 10 10 SUMMARY OF COMPO
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